Optimization of active layers for efficient binary organic solar cells.

The photovoltaic performance of organic solar cells (OSCs) is closely related to the active layer and its microstructure. Therefore, it is essential to coordinately control the preparation process parameters from multiple perspectives to optimize the morphology and improve the device's photovoltaic performance. Based on the classical and efficient PM6:L8-BO active system, this paper systematically studies the effects of annealing temperature, film thickness, solvent additives, and other factors on the film microstructure, exciton generation and dissociation, charge transport, phase separation, and light absorption.

Dual-Donor-Induced Crystallinity Modulation Enables 19.23% Efficiency Organic Solar Cells.

Trap-assisted charge recombination is one of the primary limitations of restricting the performance of organic solar cells. However, effectively reducing the presence of traps in the photoactive layer remains challenging. Herein, wide bandgap polymer donor PTzBI-dF is demonstrated as an effective modulator for enhancing the crystallinity of the bulk heterojunction active layers composed of D18 derivatives blended with Y6, leading to dense and ordered molecular packings, and thus, improves photoluminescence quenching properties.

Neural correlates of empathy in donation decisions: Insights from EEG and machine learning.

Empathy is central to individual and societal well-being. Numerous studies have examined how trait of empathy affects prosocial behavior. However, little studies explored the psychological and neural mechanisms by which different dimensions of trait empathy influence prosocial behavior.

Bionic cell wall models: Utilizing TEMPO-oxidized cellulose nanofibers for fucoxanthin delivery systems.

Fucoxanthin (FX) has various excellent biological properties but suffers from poor bioavailability. In this work, we build a bionic cell wall model using TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy)-oxidized cellulose. The bionic cell wall enhances the environmental stability of the liposomes and serves as a pH-responsive mechanism.

Mechanochemically facilitated silver-catalyzed direct H/D exchange on heteroarenes.

Despite recent advances in H/D exchange, the effective deuteration of polyarenes remains challenging, due to their insolubility and hydrophobicity. This study presents a concept proofing of a mechanochemically facilitated direct H/D exchange. The silver-catalyzed deuteration of heteroarenes was promoted smoothly within 99 minutes of grinding, with heavy water as the deuterium source.

The impact of IT change on corporate environmental violations: Toward information asymmetry and stakeholder theory.

As an essential market player, corporations play a crucial role in achieving green and sustainable economic development, while information technology is vital in influencing corporate environmental decision-making. Therefore, using a sample of A-share listed companies in China from 2009 to 2021, we developed a measurement for IT change through computer-aided text analysis to investigate the impacts of IT change on corporate environmental violations. The key findings are as follows: (1) a 1% increase in external or internal IT change can reduce corporate environmental violations by approximately 0.

Enhancing the Efficiency and Stability of Inverted Perovskite Solar Cells and Modules through Top Interface Modification with N-type Semiconductors.

The interface modification between perovskite and electron transport layer (ETL) plays a crucial role in achieving high performance inverted perovskite photovoltaics (i-PPVs). Herein, non-fullerene acceptors (NFAs), known as Y6-BO and Y7-BO, were utilized to modify the perovskite/ETL interface in i-PPVs. Non-polar solvent-soluble NFAs can effectively passivate surface defects without structural damage of the underlying perovskite films.

Air pollution and defensive behavior: Evidence from transaction data in China.

This study presents empirical research about the defensive behavior of air pollution, that is, health insurance purchases. Using transaction-level data from a large insurance company, covering more than half a million insurance contracts from nineteen cities in China from 2014 to 2018, we empirically imply that an increase of 10% in AQI leads to a 0.37% uptick in the number of daily sales of health insurance contracts by the company within the city.

Warm growing season activates microbial nutrient cycling to promote fertilizer nitrogen uptake by maize.

The influence of nitrogen (N) inputs on soil microbial communities and N uptake by plants is well-documented. Seasonal variations further impact these microbial communities and their nutrient-cycling functions, particularly within multiple cropping systems. Nevertheless, the combined effects of N fertilization and growing seasons on soil microbial communities and plant N uptake remain ambiguous, thereby constraining our comprehension of the optimal growing season for maximizing crop production.

The Synergistic Effect of Limestone Powder and Rice Husk Ash on the Mechanical Properties of Cement-Based Materials.

Fully utilizing solid waste as supplementary cementitious materials (SCMs) while ensuring the mechanical properties of cement-based materials is one of the pathways for carbon reduction in the cement industry. Understanding the effects of the two solid wastes-limestone powder (LP) and rice husk ash (RHA) on the mechanical properties of cement-based materials is of great significance for their application in concrete. This study investigates the impact of LP and RHA on the strength of cement mortar at various ages and the microhardness of hardened cement paste.

Enhancing Drug Solubility, Bioavailability, and Targeted Therapeutic Applications through Magnetic Nanoparticles.

Biological variability poses significant challenges in the development of effective therapeutics, particularly when it comes to drug solubility and bioavailability. Poor solubility across varying physiological conditions often leads to reduced absorption and inconsistent therapeutic outcomes. This review examines how nanotechnology, especially through the use of nanomaterials and magnetic nanoparticles, offers innovative solutions to enhance drug solubility and bioavailability.

Formability and Failure Mechanisms of Continuous Glass Fiber-Reinforced Polypropylene Composite Laminates in Thermoforming Below the Melting Temperature.

In this study, the thermoforming formability of continuous glass fiber-reinforced polypropylene (CGFRPP) laminates below the melting temperature were investigated. The forming limits of CGFRPP laminates were explored using flexural tests, Erichsen tests and deep drawing tests. The failure mechanism of CGFRPP in thermoforming was investigated by observing typical failure specimens using a microscope.

Preparing a Phytosome for Promoting Delivery Efficiency and Biological Activities of Methyl Jasmonate-Treated Adventitious Root Extract (DMARE).

(1) Background: Methyl jasmonate-treated adventitious root extract (MeJA-DMARE), enriched with phenolics, has enhanced bioactivities. However, phenolics possess low stability and bioavailability. Substantial evidence indicates that plant extract-phospholipid complex assemblies, known as phytosomes, represent an innovative drug delivery system.

Drying-Wetting Correlation Analysis of Chloride Transport Behavior and Mechanism in Calcium Sulphoaluminate Cement Concrete.

In response to rising CO emissions in the cement industry and the growing demand for durable offshore engineering materials, calcium sulphoaluminate (CSA) cement concrete, known for its lower carbon footprint and enhanced corrosion resistance compared to Ordinary Portland Cement (OPC), is increasingly important. However, the chloride transport behavior of CSA concrete in both laboratory and marine environments remains underexplored and controversial. Accordingly, the chloride ion transport behaviors and mechanisms of CSA concrete in laboratory-accelerated drying-wetting cyclic environments using NaCl solution and seawater, as well as in marine tidal environments, were characterized using the rapid chloride test (RCT), X-ray diffraction (XRD), mercury infiltration porosimetry (MIP), and thermogravimetric analysis (TGA).

Preparation of cellulose-based nanoparticles via electrostatic self-assembly for the pH-responsive delivery of astaxanthin.

Oral administration of astaxanthin (AST), a potent antioxidant, is limited owing to its low solubility, physicochemical stability, and bioavailability. This study developed pH-responsive nanocarriers by the electrostatic self-assembly of 2,2,6,6-tetramethylpiperidine-1-oxyradical (TEMPO)-oxidized cellulose nanofibers (TCNFs) and chitosan (CS) to enhance the intestinal delivery of AST. The TCNF/CS@AST nanoparticles were optimized through single-factor experiments and Box-Behnken design, subsequently overcoming the hydrophobicity of AST and demonstrating improved stability against environmental stressors and controlled release in the intestinal environment.