4 results match your criteria: "Nikolaev Institute of Inorganic Chemistry (NIIC)[Affiliation]"
Exploring the Frontiers of Heterometallic Systems: the {FeW} Octahedral Cluster Complex.
Inorg Chem
September 2024
Nikolaev Institute of Inorganic Chemistry (NIIC), Siberian Branch of the Russian Academy of Sciences (SB RAS), 3 Acad. Lavrentiev Avenue, Novosibirsk 630090, Russia.
Article Synopsis
- This research introduces the first heterometallic octahedral cluster complexes made from both 5d (tungsten) and 3d (iron) metals.
- The main focus is on a compound called (TBA)[FeWBr], which shows selective reactions at the iron site when different solvents are applied.
- The study also reveals various anions related to {FeW}, characterizes them through X-ray diffraction, examines their redox properties, and contrasts the bonding between Fe and W with bonds in other metal clusters using theoretical calculations.
One-Dimensional Diiodine-Iodobismuthate(III) Hybrids Cat{[BiI](I)}: Syntheses, Stability, and Optical Properties.
Inorg Chem
December 2020
Nikolaev Institute of Inorganic Chemistry (NIIC), Siberian Branch of the Russian Academy of Sciences (SB RAS), Lavrentieva Street, Novosibirsk 630090, Russia.
One-dimensional iodine-rich iodobismuthates(III), Cat{[BiI](I)} [Cat = 1,4-MePy () and 1-EtBMAP ()], feature the highest amount of "trapped" diiodine units in polyhalogen-halometalates of p-block elements. Both complexes have narrow optical band gaps (1.55 and 1.
View Article and Find Full Text PDFEnhancement of CO Uptake and Selectivity in a Metal-Organic Framework by the Incorporation of Thiophene Functionality.
Inorg Chem
May 2018
Nikolaev Institute of Inorganic Chemistry (NIIC), Siberian Branch of the Russian Academy of Sciences , 3 Ac. Lavrentiev Avenue , Novosibirsk 630090 , Russian Federation.
The complex [Zn(tdc)dabco] (Htdc = thiophene-2,5-dicarboxylic acid; dabco = 1,4-diazabicyclooctane) shows a remarkable increase in carbon dioxide (CO) uptake and CO/dinitrogen (N) selectivity compared to the nonthiophene analogue [Zn(bdc)dabco] (Hbdc = benzene-1,4-dicarboxylic acid; terephthalic acid). CO adsorption at 1 bar for [Zn(tdc)dabco] is 67.4 cm·g (13.
View Article and Find Full Text PDFElastic and photo-elastic characteristics of laser crystals potassium rare-earth tungstates KRE(WO₄)₂, where RE=Y, Yb, Gd and Lu.
Ultrasonics
July 2014
Scientific and Technological Centre of Unique Instrumentation (STC UI RAS), 15 Butlerova str., Moscow 117342, Russia.
The elastic and photo-elastic characteristics of four laser crystals KY(WO₄)₂, KGd(WO₄)₂, KYb(WO₄)₂, and KLu(WO₄)₂ are presented. The first pair was reported early, and the last two materials have been investigated for the first time. The full matrix of elastic constants of these monoclinic crystals has been determined.
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