Preparation and Physicochemical Characterization of a Diclofenac Sodium-Dual Layer Polyvinyl Alcohol Patch.

The aim of this study is to prepare a dual layer polyvinyl (PVA) patch using a combination of electrospinning techniques and cryogelation (freeze-thaw process) then subsequently to investigate the effect of freeze-thaw cycles, nanofiber thickness, and diclofenac sodium (DS) loading on the physicochemical and mechanical properties and formulation of dual layer PVA patches composed of electrospun PVA nanofibers and PVA cryogel. After the successful preparation of the dual layer PVA patch, the prepared patch was subjected to investigation to assess the effect of freeze-thaw cycles, nanofiber thickness and percentages of DS loading on the morphology, physiochemical and mechanical properties. Various spectroscopic techniques such as scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared (FTIR), water contact angle, and tensile tests were used to evaluate the physicochemical and mechanical properties of prepared dual layer PVA patches.

A Review on Current Trends of Polymers in Orthodontics: BPA-Free and Smart Materials.

Polymeric materials have always established an edge over other classes of materials due to their potential applications in various fields of biomedical engineering. Orthodontics is an emerging field in which polymers have attracted the enormous attention of researchers. In particular, thermoplastic materials have a great future utility in orthodontics, both as aligners and as retainer appliances.

GPU based parallel framework for receiver coil sensitivity estimation in SENSE reconstruction.

Magnetic Resonance Imaging (MRI) uses non-ionizing radiations and is safer as compared to CT and X-ray imaging. MRI is broadly used around the globe for medical diagnostics. One main limitation of MRI is its long data acquisition time.

Evaluation of Antioxidant Activity and Histopathological Changes Occurred by the Oral Ingestion of CuO Nanoparticles in Monosodium Urate Crystal-Induced Hyperuricemic BALB/c Mice.

Nanotechnology is an intensive branch of science due to the unique features of nano range particles (1-100 nm). Their nano size results in a high surface area of absorption when orally administered. Monosodium urate crystal excessive deposition causes a commonly known inflammatory disease called gout into the synovial joints.

Synthesis and Characterization of Fe-TiO Nanomaterial: Performance Evaluation for RB5 Decolorization and In Vitro Antibacterial Studies.

A photocatalytic system for decolorization of double azo reactive black 5 (RB5) dye and water disinfection of was developed. Sol gel method was employed for the synthesis of Fe-TiO photocatalysts and were characterized using thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM) coupled with energy dispersive X-ray analysis (EDX), transmission electron microscopy (TEM), diffuse reflectance spectroscopy (DRS) and Brunauer-Emmett-Teller (BET) analysis. Results showed that photocatalytic efficiency was greatly influenced by 0.

Quantification of biochemical compounds in Linn flower extract and its hepatoprotective effect.

Liver disorders may occur as a result of exposure to chemical compounds capable of inducing the oxidative stress and hepatic injuries. The aim of present study was to investigate the effects of flower extracts of for the treatment of liver injury induced by the CCl. About 1 ml/kg body weight (b.

Defect-mediated photoluminescence enhancement in ZnO/ITO via MeV Cu ion irradiation.

Zinc oxide (ZnO) nanowires play a pivotal role in the nanoworld due to their broad range of characteristics and applications. In this work, structural and optical properties of ZnO nanowires grown on indium doped tin oxide (ITO) coated glass have been modified by copper (Cu) ions irradiation at constant energy of 0.7 MeV.

Corrosion and Heat Treatment Study of Electroless NiP-Ti Nanocomposite Coatings Deposited on HSLA Steel.

Corrosion and heat treatment studies are essential to predict the performance and sustainability of the coatings in harsh environments, such as the oil and gas industries. In this study, nickel phosphorus (NiP)-titanium (Ti) nanocomposite coatings (NiP-Ti nanoparticles (TNPs)), containing various concentrations of Ti nanoparticles (TNPs) were deposited on high strength low alloy (HSLA) steel through electroless deposition processing. The concentrations of 0.

Insight into monsoon for shaping the air quality of Islamabad, Pakistan: Comparing the magnitude of health risk associated with PM and PM exposure.

Monsoon plays a determinant role in defining the air quality of many Asian countries. Filter-based 24 h ambient PM and PM sampling was performed by using two paralleled medium volume air samplers during pre-and post-monsoon periods. A negligible change in PM mass concentration from 45.

Topotactic, pressure-driven, diffusion-less phase transition of layered CsCoO to a stuffed cristobalite-type configuration.

CsCoO, featuring a two-dimensional layered architecture of edge- and vertex-linked CoO tetrahedra, is subjected to a temperature-driven reversible second-order phase transformation (α → β) at 100 K, which corresponds to a structural relaxation with concurrent tilting and breathing modes of edge-sharing CoO tetrahedra. In the present investigation, it was found that pressure induces a phase transition, which encompasses a dramatic change in the connectivity of the tetrahedra. At 923 K and 2 GPa, β-CsCoO undergoes a first-order phase transition to a new quenchable high-pressure polymorph, γ-CsCoO.

Ambient PM and PM bound PAHs in Islamabad, Pakistan: Concentration, source and health risk assessment.

Polycyclic aromatic hydrocarbons (PAHs) in ambient particulate matter contribute considerably to human health risk. Simultaneous sampling of ambient PM/PM was done to analyze the Ʃ16PAH across the four seasons of 2017 in Islamabad, Pakistan. The average Ʃ16PAH concentrations in PM and PM were 25.

An Improved Rosin Transfer Process for the Reduction of Residue Particles for Graphene.

In this work, an improved rosin transfer process is initiated. An anisole coating is introduced based on the rosin transfer process to reduce the residue particles on the surface of transferred graphene. Rosin/graphene and anisole/rosin/graphene samples are handled without baking and with baking at different temperatures, i.

Effects of Different Ion Irradiation on the Contact Resistance of Pd/Graphene Contacts.

The effect of ion-induced defects on graphene was studied to investigate the contact resistance of 40 nm palladium (Pd) contacting on graphene. The defect development was considered and analyzed by irradiating boron (B), carbon (C), nitrogen (N), and argon (Ar) ions on as-transferred graphene before metallization. The bombardment energy was set at 1.

Experimental and theoretical insights into the corrosion inhibition activity of novel Schiff bases for aluminum alloy in acidic medium.

Three novel Schiff bases, namely -(4-((4-((phenylimino)methyl)phenoxy)methoxy)benzylidene)benzenamine (UA), -(3-methoxy-4-((2-methoxy-4-((phenylimino)methyl)phenoxy)methoxy)benzylidene)benzenamine (UB), and -(3-ethyl-4-((2-ethyl-4-((phenylimino)methyl)phenoxy)methoxy)benzylidene)benzenamine (UC), were synthesized and their structures were elucidated through diverse spectroscopic techniques such as FT-IR, GC-MS, H NMR and C NMR. The corrosion inhibition effect of these Schiff bases on aluminum alloy AA2219-T6 in acidic medium was explored using weight loss, Tafel polarization, and electrochemical impedance spectroscopy. Theoretical quantum chemical calculations using density functional theory were employed to determine the adsorption site.

Antioxidant and anti-gout effects of orally administered zinc oxide nanoparticles in gouty mice.

Background: Zinc is an essential trace element which is involved in controlling oxidative stress, growth and immune system by regulating inflammatory cytokines. Gouty arthritis is the inflammation of joints and tissues caused by the accumulation of monosodium urate crystals.

Method And Objective: This study involved the oral administration of zinc oxide nanoparticles at a various concentration (5 ppm, 10 ppm, and 20 ppm) and study their antioxidant and anti-gout effects on Balb/C mice.

Mechanistic Insights into a Sustainable Mechanochemical Synthesis of Ettringite.

Mechanochemistry offers an environmentally benign and facile synthesis method for a variety of cement paste constituents. In addition, these methods can be used to selectively tune the properties of cement components. The mineral ettringite is an important component of cementitious materials and has additional technological potential due to its ion exchange properties.

Inhibition of Hyperuricemia and Gouty Arthritis in BALB/c Mice Using Copper Oxide Nanoparticles.

Nanoparticles are known for their unique properties and are being utilized in various disciplines of sciences. Their nanosize enables them to higher exposure and higher availability when given orally. Gout is an inflammatory disease caused by deposition of monosodium urate (MSU) crystal deposition into the joints.

Butterfly cluster like lamellar BiOBr/TiO nanocomposite for enhanced sunlight photocatalytic mineralization of aqueous ciprofloxacin.

The present study for the first time reports facile in-situ room temperature synthesis of butterfly cluster like lamellar BiOBr deposited over TiO nanoparticles for photocatalytic breakdown of ciprofloxacin (CIP). The butterfly cluster arrangement of BiOBr resulted in an increase in surface area from 124.6 to 160.

Information generating, sharing, and manipulating Source-Reservoir-Sink model of self-organizing dissipative structures.

The evolution of self-organizing ensembles of fullerenes and the emergence of the Buckyball are described by information generating, sharing, and manipulating Source-Reservoir-Sink model. Shannon's information-theoretic model of signal transmitter, channel, and receiver that preserves and retains the original signal is extended to our model that maps the transformations of chemical and physical components of the self-organizing dissipative structures into Source, Reservoir, and Sink. The information generated by Source is manipulated by controlling the flow of information to Reservoir before being transmitted to Sink.

Carbonic Anhydrase Inhibitory Potential of 1,2,4-triazole-3-thione Derivatives of Flurbiprofen, Ibuprofen and 4-tert-butylbenzoic Hydrazide: Design, Synthesis, Characterization, Biochemical Evaluation, Molecular Docking and Dynamic Simulation Studies.

Background: The over-expression of the carbonic anhydrases results in some specific carcinomas including pancreatic, gastric and brain tumor. Tumors are distinguished under hypoxic conditions and various investigations are being carried out to target the known hypoxic areas of the tumors to increase the sensitivity towards standard therapeutic treatment.

Objective: Herein, we have designed and synthesized some biologically important esters, hydrazides, thiocarbamates, 1,2,4-triazole-3-thiones and Schiff bases.

Photocatalytic Dehydrogenation of Formic Acid on CdS Nanorods through Ni and Co Redox Mediation under Mild Conditions.

Selective release of hydrogen from formic acid (FA) is deemed feasible to solve issues associated with the production and storage of hydrogen. Here, we present a new efficient photocatalytic system consisting of CdS nanorods (NRs), Ni, and Co to liberate hydrogen from FA. The optimized noble-metal-free catalytic system employs Ni/Co as a redox mediator to relay electrons and holes from CdS NRs to the Ni and Co, respectively, which also deters the oxidation of CdS NRs.

Optimised synthesis of ZnO-nano-fertiliser through green chemistry: boosted growth dynamics of economically important .

Mounting-up economic losses to annual crops yield due to micronutrient deficiency, fertiliser inefficiency and increasing microbial invasions (e.g. attack on tomatoes) are needed to be solved via nano-biotechnology.

Doxorubicin-loaded photosensitive magnetic liposomes for multi-modal cancer therapy.

Multifunctional magnetic nanosystems have attracted an enormous attention of researchers for their potential applications in cancer diagnostics and therapy. The localized nanotherapies triggered by the external stimuli, like magnetic fields and visible light, are significant in clinical applications. We report a liposomal system that aims to treat cancer by magnetic hyperthermia, photodynamic therapy and chemotherapy simultaneously.