2 results match your criteria: "National University of Science and Tehnology "MISiS"[Affiliation]"

We synthesized single crystals of NaNi(OH)(HPO) () and polycrystals of (Na, Ni)Ni(OH)(HPO) () with ellenbergerite-like structures using the hydrothermal method. The phases crystallize in the hexagonal space group 6 with the following unit cell parameters: = 12.5342(1) Å, = 4.

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Crystal chemistry and physical properties of the AM(HO)[BPO(OH)] (A = Cs, Rb; M = Ni, Cu, (Ni, Fe)) borophosphate family.

Dalton Trans

June 2019

M.V. Lomonosov Moscow State University, Leninskiy Gory, GSP-1, Moscow, 119991, Russian Federation. and National University of Science and Tehnology "MISiS", Leninskiy Prospekt, 4, Moscow, 119049, Russian Federation and National Research South Ural State University, Chelyabinsk 454080, Russian Federation.

Three new transition metal borophosphates, CsCu(HO)[BPO(OH)] (denoted (I)), CsNi(HO)[BPO(OH)] (II) and mixed RbNiFe(HO)[BPO(OH)] (III), were synthesized by a boric acid flux method at 473-493 K. X-ray single-crystal diffraction study confirms their isotipy with (Cs/Rb)Co(HO)[BPO(OH)] borophosphates crystallizing in the orthorhombic space group Pbca. The crystal structures of all compounds are based on 3D frameworks made from corrugating borophosphate layers [BPO(OH)] and trimers of MO(HO) and two MO edge-sharing octahedra.

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