Study of Plugging Compositions Based on Synthetic Resins for Repair and Insulation Work in Wells.

This research is aimed at analyzing existing plugging compositions and developing a new plugging composition based on phenol-formaldehyde resin. This paper presents the results of studies of a hardening composition based on phenol-formaldehyde resin for repair and insulation work in wells. The plugging composition consists of two parts: Component "A" (resin and additives) and Component "B" (hardener).

Long-Term Biodegradation of Polyacrylamide Gel Residues in Mammary Glands: Physico-Chemical Analysis, Chromatographic Detection, and Implications for Chronic Inflammation.

In the past, polyacrylamide hydrogel was a popular choice for breast augmentation filler, and many women underwent mammoplasty with this gel. However, due to frequent complications, the use of polyacrylamide hydrogel in mammoplasty has been banned. Despite this ban, patients experiencing complications still seek medical treatment.

New Fire-Retardant Open-Cell Composite Polyurethane Foams Based on Triphenyl Phosphate and Natural Nanoscale Additives.

Despite the mechanical and physical properties of polyurethane foams (PUF), their application is still hindered by high inflammability. The elaboration of effective, low-cost, and environmentally friendly fire retardants remains a pressing issue that must be addressed. This work aims to show the feasibility of the successful application of natural nanomaterials, such as halloysite nanotubes and nanocellulose, as promising additives to the commercial halogen-free, fire-retardant triphenyl phosphate (TPP) to enhance the flame retardance of open-cell polyurethane foams.

Time-Delayed Anticancer Effect of an Extremely Low Frequency Alternating Magnetic Field and Multimodal Protein-Tannin-Mitoxantrone Carriers with Brillouin Microspectroscopy Visualization In Vitro.

The effect of an extremely low frequency alternating magnetic field (ELF AMF) at frequencies of 17, 48, and 95 Hz at 100 mT on free and internalized 4T1 breast cancer cell submicron magnetic mineral carriers with an anticancer drug, mitoxantrone, was shown. The alternating magnetic field (100 mT; 17, 48, 95 Hz; time of treatment-10.5 min with a 30 s delay) does not lead to the significant destruction of carrier shells and release of mitoxantrone or bovine serum albumin from them according to the data of spectrophotometry, or the heating of carriers in the process of exposure to magnetic fields.

Surfactant-Polymer Composition for Selective Water Shut-Off in Production Wells.

Today, a significant part of production wells' stock has a high water cut percentage of 90% and above. Obviously, for this reason, the need to develop new and improved existing technologies for water shut-off in wells increases every year. Physico-chemical methods of water shut-off are based on the application of special reagents and compositions that plug the pathways of water inflow to the well.

Experimental Investigation of Hydraulic Fracturing Fluid Based on Pseudo Gemini Surfactant with Polysaccharide Addition.

In the last decade, hydrogels for hydraulic fracturing based on viscoelastic surfactants have been actively studied. Interest in these systems is justified by their unique qualities: good viscoelasticity and the ability to form stable suspensions of proppant or sand, destruction without the formation of bridging agents, hydrophobization of the rock surface and metal of technological equipment, as well as oil-cleaning properties. These qualities are most often provided by a minimum set of components-a surfactant and an electrolyte.

Natural Fibrous Materials Based on Fungal Mycelium Hyphae as Porous Supports for Shape-Stable Phase-Change Composites.

Adsorption of organic phase-change materials (PCMs) by the porous matrix of microfibrillar cellulose (MFC) is a simple and versatile way to prepare shape-stable phase-change composites, which are promising as sustainable thermoregulating additives to construction materials. However, due to MFC inherent morphology, the resulting composites have relatively low poured density that complicates their introduction in sufficient amounts, for instance, into mortar mixes. Unlike MFC, fungal mycelium has, by an order, less fibrils thickness and, thus, possesses significantly higher poured density.

A Facile One-Step Synthesis of Polystyrene/Cellulose (PS@MFC) Biocomposites for the Preparation of Hybrid Water-Absorbing Sponge Materials.

The elaboration of a low-cost and effective approach to synthesize hybrid composite materials based on the conventional thermoplastics and natural biopolymers is a sustainable alternative to the production of "traditional" plastics. Cellulose is one of the most abundant biopolymers. Its fibrils possess outstanding mechanical characteristics and, hence, attract considerable interest of researchers during recent decades.

Fe-Co Alloy Nanoparticles Dispersed in Polymer-Derived Carbon Support: Effect of Initial Polymer Nature on the Size, Structure and Magnetic Properties.

Fe-Co alloy nanoparticles with different sizes, supported by carbon derived from several polymers, namely polyacrylonitrile, polyvinyl alcohol and chitosan, have been synthesized by a one-pot method involving simultaneous metal nanoparticle formation and polymer carbonization. The method involves the joint dissolution of metal salts and a polymer, followed by annealing of the resulting dried film. Detailed XRD analysis confirmed the formation of Fe-Co alloy nanoparticles in each sample, regardless of the initial polymer used.

Polyurethane/-Octadecane Phase-Change Microcapsules via Emulsion Interfacial Polymerization: The Effect of Paraffin Loading on Capsule Shell Formation and Latent Heat Storage Properties.

Organic phase-change materials (PCMs) hold promise in developing advanced thermoregulation and responsive energy systems owing to their high latent heat capacity and thermal reliability. However, organic PCMs are prone to leakages in the liquid state and, thus, are hardly applicable in their pristine form. Herein, we encapsulated organic PCM -Octadecane into polyurethane capsules via polymerization of commercially available polymethylene polyphenylene isocyanate and polyethylene glycol at the interface oil-in-water emulsion and studied how various -Octadecane feeding affected the shell formation, capsule structure, and latent heat storage properties.

Composite Bone Cements with Enhanced Drug Elution.

Antibiotic-loaded bone cement (ALBC) has become an indispensable material in orthopedic surgery in recent decades, owing to the possibility of drugs delivery to the surgical site. It is applied for both infection prophylaxis (e.g.

Application of Hydrogels and Hydrocarbon-Based Gels in Oil Production Processes and Well Drilling.

The use of gels in oil production processes has become a regular practice in oilfield operations and is constantly developing in all oil-producing countries of the world, as evidenced by the growth of publications and patent activity on this topic. Many oil production processes, such as hydraulic fracturing, conformance control, water, and gas shutoff, cannot be imagined without the use of gel technologies. Inorganic, organic, and hybrid gels are used, as well as foams, gel-forming, and gel-dispersed systems.

Synthesis and properties of thiol-modified CNC via surface tosylation.

SH-containing polymers and nanoparticles are a significant direction in the creation of novel materials. The aim of this work is the synthesis of cellulose nanocrystals (CNC) with a surface modified by tosyl functions (CNC-Ts) and their further modification into SH-containing nanocrystals (CNC-SH). CNC-Ts were synthesized in an aqueous-organic emulsion from never-dried particles, while maintaining the size and supramolecular structure of CNC; the content of Ts-functions is up to 2.

Fireproof Nanocomposite Polyurethane Foams: A Review.

First introduced in 1954, polyurethane foams rapidly became popular because of light weight, high chemical stability, and outstanding sound and thermal insulation properties. Currently, polyurethane foam is widely applied in industrial and household products. Despite tremendous progress in the development of various formulations of versatile foams, their use is hindered due to high flammability.

Peroxidase-like Activity of CeO Nanozymes: Particle Size and Chemical Environment Matter.

The enzyme-like activity of metal oxide nanoparticles is governed by a number of factors, including their size, shape, surface chemistry and substrate affinity. For CeO nanoparticles, one of the most prominent inorganic nanozymes that have diverse enzymatic activities, the size effect remains poorly understood. The low-temperature hydrothermal treatment of ceric ammonium nitrate aqueous solutions made it possible to obtain CeO aqueous sols with different particle sizes (2.

Laser Derived Electron Transport Layers with Embedded p-n Heterointerfaces Enabling Planar Perovskite Solar Cells with Efficiency over 25.

Electron transport layers (ETLs) with pronounced electron conducting capability are essential for high performance planar perovskite photovoltaics, with the great challenge being that the most widely used metal oxide ETLs unfortunately have intrinsically low carrier mobility. Herein is demonstrated that by simply addressing the carrier loss at particle boundaries of TiO ETLs, through embedding in ETL p-n heterointerfaces, the electron mobility of the ETLs can be boosted by three orders of magnitude. Such embedding is encouragingly favorable for both inhibiting the formation of rutile phase TiO in ETL, and initiating the growth of high-quality perovskite films with less defect states.

Phase-Change Microcapsules with a Stable Polyurethane Shell through the Direct Crosslinking of Cellulose Nanocrystals with Polyisocyanate at the Oil/Water Interface of Pickering Emulsion.

Phase-change materials (PCMs) attract much attention with regard to their capability of mitigating fossil fuel-based heating in in-building applications, due to the responsive accumulation and release of thermal energy as a latent heat of reversible phase transitions. Organic PCMs possess high latent heat storage capacity and thermal reliability. However, bare PCMs suffer from leakages in the liquid form.

Supercritical fluid-assisted modification combined with the resynthesis of SmCoO as an effective tool to enhance the long-term performance of SmCoO-derived catalysts for the dry reforming of methane to syngas.

The dry reforming of methane to syngas (DRM) is of increasing significance concerning, first, the production of raw materials for commercial organic/petrochemical syntheses and for hydrogen energetic, and, second, the utilization of two most harmful greenhouse gases. Herein, new SmCoO-based DRM catalysts derived from heterometallic precursors and operated without preliminary reduction are reported. For the first time, the effect of supercritical fluids-assisted modification of the SmCoO-derived catalysts combined with the re-oxidation of spent catalysts to SmCoO onto its long-term performance was studied.

Improving the accuracy of estimates of the pulse sequence period using the methodology of complete sufficient statistics.

This paper is devoted to the synthesis of new signal processing algorithms based on the methodology of complete sufficient statistics and the possibility of using the Lehmann-Scheffe theorem. Using the example of a sequence of quasi-rectangular pulses, an approach to estimating their period was illustrated, taking into account the duty-off factor and the pulse squareness coefficient. A mathematical model was developed, on the basis of which, estimates of the potential accuracy of the methods were carried out.

Theoretical and Experimental Study of Joint Osmotic and Electroosmotic Water Transfer through a Cation-Exchange Membrane.

Using the previously developed cell model of a charged membrane and the principles of linear thermodynamics of irreversible processes (the Onsager approach), exact and approximate (in the case of an ideally selective membrane) analytical formulae for calculating the osmotic and electroosmotic permeability of the membrane in aqueous solutions of 1:1 electrolyte at constant electric current density and concentration gradient were suggested. The formulae have been successfully verified by our own experimental data for the extrusion cation-exchange membrane MF-4SC p.29 in NaCl solution up to concentrations of 3 M.

A rapid synthesis of nanofibrillar cellulose/polystyrene composite via ultrasonic treatment.

A new method of the synthesis of nanofibrillar cellulose/polystyrene composite based on ultrasonic treatment of styrene emulsion in cellulose-water solution was elaborated. A new approach does not require additional heating and proposes a significantly faster synthesis (15 min, 45 °C) of the target composite compared to the methods described previously. A comprehensive analysis did not reveal any significant differences between mechanical, physical and biodegradable properties of the composite obtained by ultrasonic method and that one obtained by conventional thermal method, which requires much higher temperature (above 75 °C) and reaction duration (from 3 h).

Degradation of Hybrid Drug Delivery Carriers with a Mineral Core and a Protein-Tannin Shell under Proteolytic Hydrolases.

Hybrid carriers with the mineral CaCO/FeO core and the protein-tannin shell are attractive for drug delivery applications due to reliable coupling of anticancer drugs with protein-tannin complex and the possibility of remote control over drug localization and delivery by the external magnetic field. This study aims to elucidate the mechanisms of drug release via enzymatic degradation of a protein-tannin carrier shell triggered by proteolytic hydrolases trypsin and pepsin under physiological conditions. To do this, the carriers were incubated with the enzyme solutions in special buffers to maintain the enzyme activity.

Hydrophobic Ag-Containing Polyoctylmethylsiloxane-Based Membranes for Ethylene/Ethane Separation in Gas-Liquid Membrane Contactor.

The application of gas-liquid membrane contactors for ethane-ethylene separation seems to offer a good alternative to conventional energy-intensive processes. This work aims to develop new hydrophobic composite membranes with active ethylene carriers and to demonstrate their potential for ethylene/ethane separation in gas-liquid membrane contactors. For the first time, hybrid membrane materials based on polyoctylmethylsiloxane (POMS) and silver tetrafluoroborate, with a Si:Ag ratio of 10:0.

Activating a Semiconductor-Liquid Junction via Laser-Derived Dual Interfacial Layers for Boosted Photoelectrochemical Water Splitting.

The semiconductor-liquid junction (SCLJ), the dominant place in photoelectrochemical (PEC) catalysis, determines the interfacial activity and stability of photoelectrodes, whcih directly affects the viability of PEC hydrogen generation. Though efforts dedicated in past decades, a challenge remains regarding creating a synchronously active and stable SCLJ, owing to the technical hurdles of simultaneously overlaying the two advantages. The present work demonstrates that creating an SCLJ with a unique configuration of the dual interfacial layers can yield BiVO photoanodes with synchronously boosted photoelectrochemical activity and operational stability, with values located at the top in the records of such photoelectrodes.