Anhydrous proton conductivity of electrospun phosphoric acid-doped PVP-PVDF nanofibers and composite membranes containing MOF fillers.

A high-temperature proton exchange membrane was fabricated based on polyvinylidene fluoride (PVDF) and polyvinylpyrrolidone (PVP) blend polymer nanofibers. Using electrospinning method, abundant small ionic clusters can be formed and agglomerated on membrane surface, which would facilitate the proton conductivity. To further enhance the conductivity, phosphoric acid (PA) retention as well as mechanical strength, sulfamic acid (SA)-doped metal-organic framework MIL-101 was incorporated into PVP-PVDF blend nanofiber membranes.