The Kinetics of Sorption-Desorption Phenomena: Local and Non-Local Kinetic Equations.

The kinetics of adsorption phenomena are investigated in terms of local and non-local kinetic equations of the Langmuir type. The sample is assumed in the shape of a slab, limited by two homogeneous planar-parallel surfaces, in such a manner that the problem can be considered one-dimensional. The local kinetic equations in time are analyzed when both saturation and non-saturation regimes are considered.

Percolation Effects in Mixed Matrix Membranes with Embedded Carbon Nanotubes.

Polymeric membranes with embedded nanoparticles, e.g., nanotubes, show a significant increase in permeability of the target component while maintaining selectivity.

Sars-Cov2 world pandemic recurrent waves controlled by variants evolution and vaccination campaign.

While understanding the time evolution of Covid-19 pandemic is needed to plan economics and tune sanitary policies, a quantitative information of the recurrent epidemic waves is elusive. This work describes a statistical physics study of the subsequent waves in the epidemic spreading of Covid-19 and disclose the frequency components of the epidemic waves pattern over two years in United States, United Kingdom and Japan. These countries have been taken as representative cases of different containment policies such as "Mitigation" (USA and UK) and "Zero Covid" (Japan) policies.

The Nature of Ferromagnetism in a System of Self-Ordered α-FeSi Nanorods on a Si(111)-4° Vicinal Surface: Experiment and Theory.

In this study, the appearance of magnetic moments and ferromagnetism in nanostructures of non-magnetic materials based on silicon and transition metals (such as iron) was considered experimentally and theoretically. An analysis of the related literature shows that for a monolayer iron coating on a vicinal silicon surface with (111) orientation after solid-phase annealing at 450-550 °C, self-ordered two-dimensional islands of α-FeSi displaying superparamagnetic properties are formed. We studied the transition to ferromagnetic properties in a system of α-FeSi nanorods (NRs) in the temperature range of 2-300 K with an increase in the iron coverage to 5.

Differentiation of glioblastoma tissues using spontaneous Raman scattering with dimensionality reduction and data classification.

The neurosurgery of intracranial tumors is often complicated by the difficulty of distinguishing tumor center, infiltration area, and normal tissue. The current standard for intraoperative navigation is fluorescent diagnostics with a fluorescent agent. This approach can be further enhanced by measuring the Raman spectrum of the tissue, which would provide additional information on its composition even in the absence of fluorescence.

New Technological Approaches to the Organization of the Work of Medical Personnel Performing Auscultation of Patients with COVID-19.

Due to the COVID-19 epidemic, the challenge of introducing methods for investigating patients reducing or eliminating the probability of infection of medical staff is currently relevant. This article provides an analytical review of new technological approaches to organizing the work of medical personnel in carrying out auscultation of patients with COVID-19. The development and approval of such technologies is shown to have started around the world.

Albumin microbubbles conjugated with zinc and aluminum phthalocyanine dyes for enhanced photodynamic activity.

Gas-liquid interfaces are reaching a particular interest in biomedicine. Microbubbles, ultrasound contrast agents of clinical routine, gained increasing attention as theranostic platforms due to the preserved acoustic response, drug conjugation capabilities, and applicability in biological barrier opening. A combination of microbubbles and photodynamic therapy agents can enhance the photodynamic effect, yet the evaluation of agent conjugation on microbubble stabilization and photodynamic effect is needed.

Interaction of Shock Waves with Water Saturated by Nonreacting or Reacting Gas Bubbles.

A compressible medium represented by pure water saturated by small nonreactive or reactive gas bubbles can be used for generating a propulsive force in large-, medium-, and small-scale thrusters referred to as a pulsed detonation hydroramjet (PDH), which is a novel device for underwater propulsion. The PDH thrust is produced due to the acceleration of bubbly water (BW) in a water guide by periodic shock waves (SWs) and product gas jets generated by pulsed detonations of a fuel-oxidizer mixture. Theoretically, the PDH thrust is proportional to the operation frequency, which depends on both the SW velocity in BW and pulsed detonation frequency.

Correlation analysis of vibration modes in physical vapour deposited BiSe thin films probed by the Raman mapping technique.

In this work, the Raman spectroscopy mapping technique is used for the analysis of mechanical strain in BiSe thin films of various (3-400 nm) thicknesses synthesized by physical vapour deposition on amorphous quartz and single-layer graphene substrates. The evaluation of strain effects is based on the correlation analysis of in-plane (E ) and out-of-plane (A ) Raman mode positions. For BiSe films deposited on quartz, experimental datapoints are scattered along the line with a slope of ∼0.

Search for Higgs Boson Pair Production in the Four b Quark Final State in Proton-Proton Collisions at sqrt[s]=13 TeV.

A search for pairs of Higgs bosons produced via gluon and vector boson fusion is presented, focusing on the four b quark final state. The data sample consists of proton-proton collisions at a center-of-mass energy of 13 TeV, collected with the CMS detector at the LHC, and corresponds to an integrated luminosity of 138  fb^{-1}. No deviation from the background-only hypothesis is observed.

Measurement of the Coherent Elastic Neutrino-Nucleus Scattering Cross Section on CsI by COHERENT.

We measured the cross section of coherent elastic neutrino-nucleus scattering (CEvNS) using a CsI[Na] scintillating crystal in a high flux of neutrinos produced at the Spallation Neutron Source at Oak Ridge National Laboratory. New data collected before detector decommissioning have more than doubled the dataset since the first observation of CEvNS, achieved with this detector. Systematic uncertainties have also been reduced with an updated quenching model, allowing for improved precision.

Nitrogen-doped carbon dots with high selectivity for hydrosulfide sensing and their living cells imaging.

Hydrosulfuric acid is an aqueous solution of hydrogen sulfide (HS). At physiological pH, approximately 80% of the total amount of HS exists in the form of monoanionic HS. Because HS is both widely distributed and highly toxic to humans, it is necessary to design an efficient method to detect HS with high sensitivity and selectivity.

Dependence of Quantum Dot Toxicity In Vitro on Their Size, Chemical Composition, and Surface Charge.

Semiconductor nanocrystals known as quantum dots (QDs) are of great interest for researchers and have potential use in various applications in biomedicine, such as in vitro diagnostics, molecular tracking, in vivo imaging, and drug delivery. Systematic analysis of potential hazardous effects of QDs is necessary to ensure their safe use. In this study, we obtained water-soluble core/shell QDs differing in size, surface charge, and chemical composition of the core.

On the separation of enantiomers by drift tube ion mobility spectrometry.

Racemic mixtures of twelve common α-amino acids and three chiral drugs were tested for the separation of their enantiomers by drift tube ion mobility spectrometry (IMS)-quadrupole mass spectrometry (QMS) by introducing chiral selectors into the buffer gas of the IMS instrument. ()-α-(Trifluoromethyl)benzyl alcohol, (L)-ethyl lactate, methyl ()-2-chloropropionate, and the and enantiomers of 2-butanol and 1-phenyl ethanol were evaluated as chiral selectors. Experimental conditions were varied during the tests, including buffer gas temperature, concentration and type of chiral selectors, analyte concentration, electrospray (ESI) voltage, ESI solvent pH, and buffer gas flow rate.

Search for Flavor-Changing Neutral Current Interactions of the Top Quark and Higgs Boson in Final States with Two Photons in Proton-Proton Collisions at sqrt[s]=13 TeV.

Proton-proton interactions resulting in final states with two photons are studied in a search for the signature of flavor-changing neutral current interactions of top quarks (t) and Higgs bosons (H). The analysis is based on data collected at a center-of-mass energy of 13 TeV with the CMS detector at the LHC, corresponding to an integrated luminosity of 137  fb^{-1}. No significant excess above the background prediction is observed.

Structure-function relationships in polymeric multilayer capsules designed for cancer drug delivery.

The targeted delivery of cancer drugs to tumor-specific molecular targets represents a major challenge in modern personalized cancer medicine. Engineering of micron and submicron polymeric multilayer capsules allows the obtaining of multifunctional theranostic systems serving as controllable stimulus-responsive tools with a high clinical potential to be used in cancer therapy and detection. The functionalities of such theranostic systems are determined by the design and structural properties of the capsules.

Ion-shift reagent binding energy and the mass-mobility shift correlation in ion mobility spectrometry.

Rationale: Ion mobility spectrometry (IMS) detects illegal substances and explosives in airports, ports, and customs. This is complicated by false positives caused by overlapping peaks. Shift reagents selectively change ion mobilities through adduction with analyte ions.

Probing Charm Quark Dynamics via Multiparticle Correlations in Pb-Pb Collisions at sqrt[s_{NN}]=5.02 TeV.

Multiparticle azimuthal correlations of prompt D^{0} mesons are measured in Pb-Pb collisions at a nucleon-nucleon center-of-mass energy of sqrt[s_{NN}]=5.02  TeV. For the first time, a four-particle cumulant method is used to extract the second Fourier coefficient of the azimuthal distribution (v_{2}) of D^{0} mesons as a function of event centrality and the D^{0} transverse momentum.

Search for Resonances Decaying to Three W Bosons in Proton-Proton Collisions at sqrt[s]=13 TeV.

A search for resonances decaying into a W boson and a radion, where the radion decays into two W bosons, is presented. The data analyzed correspond to an integrated luminosity of 138  fb^{-1} recorded in proton-proton collisions with the CMS detector at sqrt[s]=13  TeV. One isolated charged lepton is required, together with missing transverse momentum and one or two massive large-radius jets, containing the decay products of either two or one W bosons, respectively.

Radiofrequency impedance monitoring of the biological tissues under local heating by optical radiation.

Development of methods for simultaneous control of state of biological tissues during optical treatment is the important tasks in laser surgery. We introduce a novel approach for the monitoring of the state of biological tissues in the process of its local heating by optical radiation. It is based on measurements of the electrical radiofrequency impedance kinetics of the sample during irradiation.

Negative Atmospheric Pressure Chemical Ionization of Chlorinated Hydrocarbons Studied by Ion Mobility Spectrometry (IMS) and IMS-MS Techniques.

Negative polarity atmospheric pressure chemical ionization of selected chlorinated hydrocarbons (tetrachloromethane CCl and hexachloroethane CCl, dichloromethane CHCl, trichloromethane CHCl, 1,1,1,2-tetrachloroethane 1,1,1,2-CHCl, 1,1,2,2-tetrachloroethane 1,1,2,2,-CHCl 1,1,2-trichloroethane 1,1,2-CHCl, and 1,1,2-trichloroethane 1,1,2-CHCl) was studied using ion mobility spectrometry (IMS) and IMS combined with time-of-flight mass spectrometer (IMS-TOF MS) techniques, in the dry air and at two different drift gas temperatures (323 and 373 K). The ionization was performed using the OCO(HO) reactant ions (RIs), and the dominant ionization reaction was the dissociative electron transfer. The ionization resulted in the appearance of Cl ions for all substances and [OH.

Observation of the B_{c}^{+} Meson in Pb-Pb and pp Collisions at sqrt[s_{NN}]=5.02 TeV and Measurement of its Nuclear Modification Factor.

The B_{c}^{+} meson is observed for the first time in heavy ion collisions. Data from the CMS detector are used to study the production of the B_{c}^{+} meson in lead-lead (Pb-Pb) and proton-proton (pp) collisions at a center-of-mass energy per nucleon pair of sqrt[s_{NN}]=5.02  TeV, via the B_{c}^{+}→(J/ψ→μ^{+}μ^{-})μ^{+}ν_{μ} decay.

Hypertriton Production in p-Pb Collisions at sqrt[s_{NN}]=5.02 TeV.

The study of nuclei and antinuclei production has proven to be a powerful tool to investigate the formation mechanism of loosely bound states in high-energy hadronic collisions. The first measurement of the production of _{Λ}^{3}H in p-Pb collisions at sqrt[s_{NN}]=5.02  TeV is presented in this Letter.