Iron-selenide-based titanium dioxide nanocomposites as a novel electrode material for asymmetric supercapacitors operating at 2.3 V.

This study portrays a facile wet-chemical synthesis of FeSe/TiO nanocomposites for the first time for advanced asymmetric supercapacitor (SC) energy storage applications. Two different composites were prepared with varying ratios of TiO (90 and 60%, symbolized as KT-1 and KT-2) and their electrochemical properties were investigated to obtain an optimized performance. The electrochemical properties showed excellent energy storage performance owing to faradaic redox reactions from Fe/Fe while TiO due to Ti/Ti with high reversibility.

Thermal Effects on the Quality Parameters of Extra Virgin Olive Oil Using Fluorescence Spectroscopy.

Extra virgin olive oil is one of the superlative due to its health benefits. In this work, the Fluorescence spectra of extra virgin olive oil (EVOO) from different olive growing regions of Pakistan and Al-Jouf region from the Kingdom of Saudi Arabia (KSA) were obtained. The emission bands depicted relative intensity variations in all non-heated and heated EVOO samples.

Quality Analysis of Canola and Mustard Oil Using Fluorescence Spectroscopy.

The potential of Fluorescence spectroscopy has been utilized for the quality analysis of canola and mustard oil along with the effect of heating on their molecular composition has been investigated. Laser diode at 405 nm has been employed directly to oil surface to excite both oil type samples and their emission spectra has been recorded by an in-house developed Fluorosensor. The emission spectra of both oil types unveiled that they contain carotenoids, isomers of vitamin E and chlorophylls that exhibit their fluorescence at 525 and 675/720 nm, and these can be used as markers for their quality assurance.

Polarimetric and fluorescence spectroscopic based classification of mono and disaccharide solutions.

In this article, we demonstrate the potential application of polarimetry and fluorescence spectroscopy for classifying mono and disaccharides (sugar) both qualitatively and quantitatively. A phase lock-in rotating analyzer (PLRA) polarimeter has been designed and developed for real time quantification of sugar concentration in a solution. Polarization rotation in the form of phase shift in sinusoidal photovoltages of reference and sample beams occurred when incident on the two spatially distinct photodetectors.

Gold nanocubes based optical detection of HIV-1 DNA via surface enhanced Raman spectroscopy.

Optical detection of HIV-1 DNA with surface enhanced Raman spectroscopy (SERS) is a quick and versatile method, having great potential in screening and characterization of HIV-1 virus particle. We have synthesized and applied novel gold nanocubes (AuNCs) for signal enhancement of SERS to study HIV-1 DNA strands by taking into account the specific vibrational bands of functional groups. Raman peaks at 562 cm, 800 cm, 1094 cm were observed in both Human Random Control DNA and HIV-1 DNA, while three new peaks were detected in infected DNA at 421 cm, 1069 cm and 1254 cm.

Processing laser ablated plasmonic nanoparticle aerosols with nonthermal dielectric barrier discharge jets of argon and helium and plasma induced effects.

Dielectric-barrier-discharge (DBD) plasma jets provide viable state-of-the-art nonthermal processes for a wide range of nanomaterials including particle transport and deposition. We report the interaction of argon and helium plasma jets with the particle aerosol, produced by ns laser ablation of a silver target and subsequently their transport for deposition on a distant substrate. The nanofeatures and functionality of the nanoparticles, entrained and deposited with the two plasma jets were compared using high-resolution electron microscopy, helium ion microscopy, scanning electron microscopy, ultraviolet-visible spectroscopy, and in terms of the SERS effect.

Recent Development of Fluorescent Nanodiamonds for Optical Biosensing and Disease Diagnosis.

The ability to precisely monitor the intracellular temperature directly contributes to the essential understanding of biological metabolism, intracellular signaling, thermogenesis, and respiration. The intracellular heat generation and its measurement can also assist in the prediction of the pathogenesis of chronic diseases. However, intracellular thermometry without altering the biochemical reactions and cellular membrane damage is challenging, requiring appropriately biocompatible, nontoxic, and efficient biosensors.

Spectroscopic and crystallographic analysis of nephrite jade gemstone using laser induced breakdown spectroscopy, Raman spectroscopy, and X-ray diffraction.

The elemental composition, mineral phases, and crystalline structure of nephrite jade were investigated using calibration-free laser-induced breakdown spectroscopy (CF-LIBS), Raman spectroscopy, and X-ray diffraction (XRD). For compositional analysis, the laser-induced plasma was generated on the surface of nephrite jade. The plasma emissions were then acquired and analyzed, which revealed several elements in the sample, including Si, Mg, Ca, Li, Fe, Al, Na, K, and Ni.

Absolute response of a proton detector composed of a microchannel plate assembly and a charge-coupled device to laser-accelerated multi-MeV protons.

The absolute response of a real-time proton detector, composed of a microchannel plate (MCP) assembly, an imaging lens, and a charge-coupled device (CCD) camera, is calibrated for the spectral characterization of laser-accelerated protons, using a Thomson parabola spectrometer (TPS). A slotted CR-39 plate was used as an absolute particle-counting detector in the TPS, simultaneously with the MCP-CCD detector to obtain a calibration factor (count/proton). In order to obtain the calibration factor as a function of proton energy for a wide range of proton numbers, the absolute response was investigated for different operation parameters of the MCP-CCD detector, such as MCP voltage, phosphor voltage, and CCD gain.

Anodic SnO Nanoporous Structure Decorated with CuO Nanoparticles for Sensitive Detection of Creatinine: Experimental and DFT Study.

Advanced anodic SnO nanoporous structures decorated with CuO nanoparticles (NPs) were employed for creatinine detection. Anodization of electropolished Sn sheets in 0.3 M aqueous oxalic acid electrolyte under continuous stirring produced complete open top, crack-free, and smooth SnO nanoporous structures.

Synthesis of Geopolymer from a Novel Aluminosilicate-Based Natural Soil Precursor Using Electric Oven Curing for Improved Mechanical Strength.

Natural soil (NS)-based geopolymers (GPs) have shown promise as environmentally friendly construction materials. The production of ordinary Portland cement is known to release significant amounts of greenhouse gas (CO) into the atmosphere. The main objective of this work is to synthesize a geopolymer (GP) from an uncommon aluminosilicate-based NS and a sodium silicate (SS) activating solution that would not only minimize the emission of harmful gases, but also offer improved mechanical strength.

Development of multivariate classification models for the diagnosis of dengue virus infection.

The dengue virus (DENV) infection is a worldwide cause of serious illness and death. Early and efficient prediction of disease may help in proper medical management to control disease. Keeping this in view, multivariate classification models by combining with Raman spectroscopy have been developed for the diagnosis of DENV infection in human blood sera.

Synthesis and photophysical investigations of pyridine-pyrazolate bound boron(III) diaryl complexes.

This study presents the design and synthetic pathway of unsymmetric ligands based on pyridine-pyrazolate scaffold with Donor-Acceptor (D-A) molecular arrays and their boron complexes to achieve a large Stokes shift. Intermolecular charge transfer (ICT) triggered by the uneven molecular charge distribution from electronically dense pyrazolate (donor) part of the ligands to electron-deficient boron centre (acceptor) resulted in a mega Stokes shift up to 263 nm for selected compounds while retaining the characteristic quantum efficiency and chemical stability. The photophysical properties of derivatization of pyrazolate group in the pyridine-pyrazolate scaffold of diaryl boron complexes were explored based on UV-Visible, steady-state and time-resolved fluorescence spectroscopy.

Sol-Gel Synthesized High Entropy Metal Oxides as High-Performance Catalysts for Electrochemical Water Oxidation.

Hexanary high-entropy oxides (HEOs) were synthesized through the mechanochemical sol-gel method for electrocatalytic water oxidation reaction (WOR). As-synthesized catalysts were subjected to characterization, including X-ray diffraction (XRD), Fourier transforms infrared (FTIR) analysis, and scanning electron microscopy (SEM). All the oxide systems exhibited sharp diffraction peaks in XRD patterns indicating the defined crystal structure.

Early detection of stripe rust infection in wheat using light-induced fluorescence spectroscopy.

In the current study, the application of fluorescence spectroscopy along with the advanced statistical technique and confocal microscopy was investigated for the early detection of stripe rust infection in wheat grown under field conditions. The indigenously developed Fluorosensor fitted with LED, emitting monochromatic light was used that covered comparatively larger leaf area for recording fluorescence data thus presenting more reliable current status of the leaf. The examined leaf samples covered the entire range of stripe rust disease infection from no visible symptoms to the complete disease prevalence.

Development of highly permselective Mixed Matrix Membranes comprising of polyimide and Ln-MOF for CO capture.

Mixed Matrix Membranes (MMMs) with hybrid organic-inorganic characteristics offer a strong alternative to traditional polymer-based membranes to reduce the trade-off between gas permeability and selectivity. This work incorporated lanthanum-Metal Organic Frameworks in the Matrimid to fabricate MMMs. To understand the effects of nano-filler on membranes' morphology, porosity, thermal stability, and chemical composition, MMMs were fabricated with three different loadings of nano-filler, i.

Glycol-Chitosan-Based Technetium-99m-Loaded Multifunctional Nanomicelles: Synthesis, Evaluation, and In Vivo Biodistribution.

We hereby propose the use of stable, biocompatible, and uniformly sized polymeric micelles as high-radiotracer-payload carriers at region-of-interest with negligible background activity due to no or low offsite radiolysis. We modified glycol chitosan (GC) polymer with varying levels of palmitoylation (P) and quaternization (Q). Quaternary ammonium palmitoyl glycol chitosan (GCPQ) with a Q:P ratio of 9:35 (Q9P35GC) offers >99% biocompatibility at 10 mg mL−1.

Characterization of Corn Oil Using Fluorescence Spectroscopy.

In these studies, Fluorescence spectroscopy has been utilized for the characterization of pure and commercially available corn oil. The best excitation wavelength of 380 nm has been investigated, where maximum spectral information can be assessed. The emission spectra from pure and commercial corn oil samples disclosed that pure corn oil contained oleic acid, beta-carotenes, chlorophylls, isomers of vitamin E and traces of oxidized products which exhibit fluorescence at 406, 525, 675, 440 and 435/475 nm respectively.

Mesoporous NiCoSnanoflakes as an efficient and durable electrocatalyst for non-enzymatic detection of cholesterol.

The detection of cholesterol is very crucial in clinical diagnosis for rapid and accurate monitoring of multiple disease-biomarkers. There is a great need for construction of a highly reliable and stable electrocatalyst for the efficient detection of cholesterol. In this work, mesoporous NiCoSnanoflakes of enhanced electrochemical properties are prepared through a facile hydrothermal approach.

Diagnosis of dengue virus infection using spectroscopic images and deep learning.

Dengue virus (DENV) infection is one of the major health issues and a substantial epidemic infectious human disease. More than two billion humans are living in dengue susceptible regions with annual infection mortality rate is about 5%-20%. At initial stages, it is difficult to differentiate dengue virus symptoms with other similar diseases.

Quantitative auto-fluorescence quenching of free and bound NADH in HeLa cell line model with Carbonyl cyanide-p-Trifluoromethoxy phenylhydrazone (FCCP) as quenching agent.

The autofluorescence of endogenous biomolecules (Nicotinamide adenine dinucleotide (NAD, its reduced form NADH and the phosphorylated form NAD(P)H take part in cellular metabolic pathways and has vital importance for in vivo and ex vivo photo diagnostic applications of biological tissues. We present a detailed quenching analysis of Carbonyl cyanide-p-Trifluoromethoxy phenylhydrazone (FCCP) 50-1000 µM and analyzed the fluorescence signal from NADH/ NAD(P)H in vitro (in solution) and in vivo (HeLa cell suspension).The in vitro samples of pure NADH/ NAD(P)H were excited at λ=340±1 nm while the fluorescence signal was collected in the range of 400-550 nm.

Evaluating the performance of multilayer perceptron algorithm for tuberculosis disease Raman data.

In spite of developments in various molecular approaches, major challenges remain in rapidly diagnosing infectious diseases triggered by bacteria. Identification of such causative pathogens at an earlier stage and with an acceptable degree of sensitivity and specificity would play a major role in initiating proper treatment. In this study the performance of multilayer perceptron (MLP) algorithm on the Raman Spectroscopic data of tuberculosis disease have been evaluated.

Classification of Sidr honey and detection of sugar adulteration using right angle fluorescence spectroscopy and chemometrics.

Unlabelled: Sidr honey is vulnerable to adulteration with low-grade honey and sugar syrups, which compromises its nutritional and medicinal value, demanding fast and reliable analytical tools for quality assessment. In this study, fluorescence spectroscopy was employed to assess the quality of a honey samples, specifically, Sidr, unifloral (Acacia) and multifloral (Acacia, Carisa and Justicia) honey. Fluorescence spectroscopy revealed characteristic spectral signatures of Sidr honey, compared to Acacia and multifloral honey.