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A series of W-Zr-O /TiO catalysts with hierarchical pore structure were prepared and used for selective catalytic reduction of NO by NH. Results showed that the 5C-WZ/T had a hierarchical pore structure, and exhibited high catalytic activity and good resistance to water and sulfur poisoning. The activity of the 5C-WZ/T catalyst was close to 100% in the range of 350-500 °C.

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