Study on the lifetime of photocatalyst by photocatalytic membrane reactors (PMR).

The continuously photocatalytic degradation of methyl orange (MO) was carried out using a photocatalytic membrane reactor (PMR). The lifetime, cause of deactivation, and regeneration of Degussa P25 titanium dioxide (TiO) were investigated. The photocatalyst was deactivated when the concentration of MO in the effluent of the PMR was stable.

Chemiluminescence imaging immunoassay for simultaneous determination of TBBPA-DHEE and TBBPA-MHEE in aquatic environments.

The environmental concentration of tetrabromobisphenol A bis(2-hydroxyethyl) ether (TBBPA-DHEE) and tetrabromobisphenol A mono(hydroxyethyl) ether (TBBPA-MHEE), as some of the main derivatives and byproducts of tetrabromobisphenol A (TBBPA), are obscure due to lacking available analytical methods. In the present study, a multiplexed competitive chemiluminescent imaging immunoassay (CLIIA) based on specific monoclonal antibody respectively against TBBPA-MHEE and TBBPA-DHEE has been developed for the simultaneous detection of the two targets. To improve the sensitivity of immunoassay, Au nanoparticles (AuNPs) were utilized as solid support for loading horseradish peroxidase, labeled to obtain the multi-enzyme particles.

The establishment of Chinese ecological conservation redline and insights into improving international protected areas.

China proposed the Ecological Conservation Redline (ECR) strategy in 2011 and listed it as an important part of the ecological promotion process in 2013. In 2017, China implemented the designation of ECR at a national scale. The aim was to demarcate areas with unique ecological functions.

Variations in Cadmium Concentrations in Rice and Oxidation-Reduction Potential at the Soil Surface with Supplementation of Fermented Botanical Waste-based Amendment in Large-scale Farmland.

We monitored the relationship between the cadmium (Cd) concentration uptake of rice and the oxidation-reduction potential (ORP) at the soil surface with the supplementation of fermented botanical waste-based amendment (FBWA), an organic fertilizer prepared from woody and food wastes. This study was carried out for 3 years in the western part of Jiangsu Province, China. It was found that the Cd concentration taken up by rice was correlated to a decreased the ORP of the cultivated soil.

Biochar retards Al toxicity to maize (Zea mays L.) during soil acidification: The effects and mechanisms.

Biochar can effectively alleviate the Al phytotoxicity in acidic soils due to its alkaline nature. However, the longevity of this alleviation effect of biochar under re-acidification conditions is still unclear. In the present study, the maize root growth responding to the simulated re-acidification of two acidic soils amended by peanut straw biochar or Ca(OH) was investigated to evaluate the long-term effect of biochar on alleviating Al toxicity in acidic soils.

An evaluation model for aboveground biomass based on hyperspectral data from field and TM8 in Khorchin grassland, China.

Biomass is an important indicator for monitoring vegetation degradation and productivity. This study tests the applicability of Hyperspectral Remote-Sensing in situ measurements for high-precision estimation aboveground biomass (AGB) on regional scales of Khorchin grassland in Inner Mongolia, China. In order to improve prediction accuracy of AGB which is frequently used as an indicator of aboveground net primary productivity (ANPP), this paper combined ground measurement with remote sensing inversion to build the spectral model.

Coupled modeling using PRZM/RICEWQ and SWAT for the North Tiaoxi Watershed.

Watershed exposure caused by the use of pesticide in farmland has become a major environmental concern. Currently, there are two major approaches to quantify the watershed exposure: monitoring and modeling. Watershed monitoring is expensive, and short-term monitoring is difficult to be used to address potential long-term exposure variability.

China's ecological conservation redline: A solution for future nature conservation.

Globally, continuing environmental degradation is leading many countries to strengthen their systems of protected areas. However, this may not be sufficient to halt degradation and conserve biodiversity and ecosystem services. To supplement its growing system of protected areas, the Chinese government is adopting a strategy of Ecological Conservation Redlines (ECRs).

Transgenerational reproductive and developmental toxicity of tebuconazole in Caenorhabditis elegans.

The transgenerational reproductive and developmental toxicity of tebuconazole (TEB) in Caenorhabditis elegans was investigated over five generations (P0 - F4). Only parental C.elegans (P0) were exposed to TEB (0, 0.

[Prediction of potential distribution of the invasive species Procambarus clarkii in China based on ecological niche models].

Procambarus clarkii was introduced into China as an important aquatic product in early 20th century. It has characteristics of high fertility, rapid growth, adaptability and digging burrows, which could cause damage of crops, cropland and facilities, decrease local biodiversity and thus threaten local ecosystem. Thus, predicting the potential distribution of P.

[Impacts of herbicide-resistant soybean ZUTS-33 with g10-epsps gene on field biodiversity].

Evaluating the impacts of genetically modified crops on biodiversity is a necessary step before their release to the field and obtaining environmental safety certificates. To assess the ecological safety of herbicide-resistant soybean ZUTS-33, we compared arthropod diversity, diseases occurrence, nodule number, and weed diversity through spraying herbicide or water on ZUTS-33, and its parental control receptor HC-3 and main cultivar soybean ZH-13 in a field experiment. The results showed that there was no significant difference of arthropod diversity (number of insects per 100 plants, Shannon index, Simpson index and Pielou index), diseases incidence rates and disease index, nodules and weed diversity between ZUTS-33 and non-genetically modified control soybean HC-3 and ZH-13.

The Role of Biochar in Reducing the Bioavailability and Migration of Persistent Organic Pollutants in Soil-Plant Systems: A Review.

The amendment of biochar in soils contaminated with persistent organic pollutants (POPs) is an environmentally friendly in situ remediation measure. Numerous studies focused on the application of biochars to reduce the uptake of POPs by plants in soils. In this review, we summarized the role of biochar in reducing the migration of POPs in soil-plant systems.

Atmospheric deposition of hazardous elements and its accumulation in both soil and grain of winter wheat in a lead-zinc smelter contaminated area, Central China.

Hazardous elements (HEs) and its deposition from atmosphere have become a major healthy and environmental concern worldwide, however, the risks to food safety of deposited HE are still largely unknown, especially for wheat grains (Triticum aestivum L.). This research was to characterize atmospheric deposition of high HEs [such as lead (Pb), cadmium (Cd) and arsenic (As)] at deposited site (TS) and assess its impacts on the soil and winter wheat accumulation in a lead‑zinc smelter contaminated area of Central China.

[Pollution Level and Ecological Risk of Typical Antibiotics in Guiyang Wastewater Treatment Plants].

To determine the removal efficiency of typical antibiotics in Guiyang wastewater treatment plants (WWTPs) and the impact of effluent on aquatic organisms in receiving waters, nine antibiotics in the influent, effluent, and receiving water of two WWTPs in Guiyang City were investigated. The concentrations of antibiotics in the influent and effluent ranged from 0 to 835.60 ng·L and 0 to 286.

[Determination of diethyl aminoethyl hexanoate residues in apples by gas chromatography-mass spectrometry combined with improved QuEChERS].

A method was developed for the determination of diethyl aminoethyl hexanoate (DA-6) residues in apples by gas chromatography-mass spectrometry (GC-MS) combined with improved QuEChERS. The samples were first extracted with warm water, then, the extract was subjected to liquid-liquid re-extraction with dichloromethane, followed by rotary evaporation concentration. The residues were cleaned up with primary secondary amine (PSA).

Antibiotic contamination in a typical water-rich city in southeast China: a concern for drinking water resource safety.

The occurrence and distribution in the aquatic environment of Nanjing of 49 antibiotics from seven therapeutic classes were investigated using an improved analytical method developed for multiclass target analysis. The results showed that these antibiotics are widely present in the water bodies of this city, with a total concentration of up to 1.958 μg L.

[Ecotoxicological effects of transgenic mCry1Ac maize (BT799) on zebrafish].

The safety of feed derived from genetically modified (GM) crops is one of the focuses of attention. To evaluate the ecotoxicological effects of transgenic mCry1Ac maize (BT799) on fish, zebrafish (Danio rerio) were fed extruded feeds containing either 20% GM maize (GMF) or its parental control maize (PF), GM maize meal (GMM) or its parental control maize meal (PMM), and a control commercial feed (CF), respectively. The growth performance, histopathology, reproduction, antioxidant enzyme activity and mRNA expression levels of sensitive protein in the liver were investigated over the course of a 98-day feeding trial.

Speciation and location of arsenic and antimony in rice samples around antimony mining area.

Arsenic (As) and antimony (Sb) are considered as priority environmental pollutants and their accumulation in crop plants particularly in rice has posed a great health risk. This study endeavored to investigate As and Sb contents in paired soil-rice samples obtained from Xikuangshan, the world largest active Sb mining region, situated in China, and to investigate As speciation and location in rice grains. The soil and rice samples were analyzed by coupling the wet chemistry, laser ablation-inductively coupled plasma mass spectrometry (LA-ICP-MS), synchrotron-based micro X-ray fluorescence mapping (μ-XRF) and micro X-ray absorption near-edge structure (μ-XANES) spectroscopy.

Beneficial dual role of biochars in inhibiting soil acidification resulting from nitrification.

The dual role of biochar for inhibiting soil acidification induced by nitrification was determined through two-step incubation experiments in this study. Ca(OH) or biochar was added respectively to adjust soil pH to the same values (pH 5.15 and 5.

An evaluation on the bioavailability of heavy metals in the sediments from a restored mangrove forest in the Jinjiang Estuary, Fujian, China.

The bioavailability of heavy metals in restored mangrove wetland sediments at the Jinjiang Estuary was assessed through acid-volatile sulfide (AVS) and simultaneously extracted metals (SEM). The results indicated that the SEM distributions were more even than the AVS in the restored regions, and the AVS acted as an important carrier for SEM. SEM- was a major part (61.

Emerging Polar Phenolic Disinfection Byproducts Are High-Affinity Human Transthyretin Disruptors: An in Vitro and in Silico Study.

Phenolic disinfection byproducts (phenolic-DBPs) have been identified in recent years. However, the toxicity data for phenolic-DBPs are scarce, hampering their risk assessment and the development of regulations on the acceptable concentration of phenolic-DBPs in water. In this study, the binding potency and underlying interaction mechanism between human transthyretin (hTTR) and five groups of representative phenolic-DBPs (2,4,6-trihalo-phenols, 2,6-dihalo-4-nitrophenols, 3,5-dihalo-4-hydroxybenzaldehydes, 3,5-dihalo-4-hydroxybenzoic acids, halo-salicylic acids) were determined and probed by competitive fluorescence displacement assay integrated with in silico methods.

Persistence of insecticidal Cry toxins in Bt rice residues under field conditions estimated by biological and immunological assays.

One risk of growing Bacillus thuringiensis (Bt) crops is the potential nontarget effects which are likely related to the environmental behavior of crystal (Cry) toxins. Bt rice residues left in field after harvest constitute a main source of Cry toxins entering the environment. To our knowledge, very few studies have simultaneously evaluated the persistence of Cry toxins in Bt rice residues under field conditions using different methods.

Effect of microplastics exposure on the photosynthesis system of freshwater algae.

Microplastics are widely distributed in freshwater environments. At present, most of the studies on the toxicity of microplastics are concentrated on aquatic feeding animals, but relatively few have addressed freshwater algae. This study investigated the effect of microplastics (polypropylene (PP) and polyvinyl chloride (PVC)) exposure on the photosynthetic system of freshwater algae over the logarithmic growth period.

Metaphire guillelmi gut as hospitable micro-environment for the potential transmission of antibiotic resistance genes.

Earthworm gut played an important role in the transformation of various contaminants in the soil environments. With the increasing application of organic fertilizer recently, the ingestion of antibiotics, antibiotic resistance bacteria (ARB), and antibiotic resistance genes (ARGs) made the earthworm gut a potential favorable micro-environment for the transmission of ARGs in the soil. In this work, the conventional plate incubation and high-throughput sequencing methods were both employed to investigate the composition of the cultivable and overall ARB/ARGs in the Metaphire guillelmi earthworm gut.