Metabolic interactions underpinning high methane fluxes across terrestrial freshwater wetlands.

Current estimates of wetland contributions to the global methane budget carry high uncertainty, particularly in accurately predicting emissions from high methane-emitting wetlands. Microorganisms drive methane cycling, but little is known about their conservation across wetlands. To address this, we integrate 16S rRNA amplicon datasets, metagenomes, metatranscriptomes, and annual methane flux data across 9 wetlands, creating the Multi-Omics for Understanding Climate Change (MUCC) v2.

Does amplitude compression help or hinder attentional neural speech tracking?

Amplitude compression is an indispensable feature of contemporary audio production and especially relevant in modern hearing aids. The cortical fate of amplitude-compressed speech signals is not well-studied, however, and may yield undesired side effects: We hypothesize that compressing the amplitude envelope of continuous speech reduces neural tracking. Yet, leveraging such a 'compression side effect' on unwanted, distracting sounds could potentially support attentive listening if effectively reducing their neural tracking.

Acrylpimaric acid-modified chitosan derivatives as potential antifungal agents against Valsa Mali.

In order to the antifungal activity of chitosan (CS) and to obtain a better natural bio-antimicrobial agent, CS was modified with acrylpimaric acid (APA). The grafting sites of APA on CS were controlled by adjusting the reaction time and the ratio of reactants to obtain APA grafted with CS C-NH (NCSAA) and C-OH (CSAA). Intermediates to protect C-NH (PMCSAA) and final sample derivatives (PCSAA) were prepared using phthalic anhydride.

Quaternary ammonium chitosan-functionalized mesoporous silica nanoparticles: A promising targeted drug delivery system for the treatment of intracellular MRSA infection.

The limited membrane permeability and bacterial resistance pose significant challenges in the management of intracellular drug-resistant bacterial infections. To overcome this issue, we developed a bacterial-targeted drug delivery system based on quaternary ammonium chitosan-modified mesoporous silica nanoparticles (MSN-NH-CFP@HACC) for the treatment of intracellular Methicillin-resistant Staphylococcus aureus (MRSA) infections. This system utilizes amino-functionalized mesoporous silica nanoparticles to efficiently load cefoperazone (CFP), and the nanoparticles' surface is coated with 2-hydroxypropyltrimethyl ammonium chloride chitosan (HACC) to target bacteria and enhance macrophage uptake.

Ultrafast Detection of ppb-Level NH Gas at Room Temperature Using CuO Nanoparticles Decorated AlN-Based Surface Acoustic Wave Sensor.

Rational design of heterostructure (HS)-based surface acoustic wave (SAW) smart gas sensors for efficient and accurate subppm level ammonia (NH) detection at room temperature (RT) is of great significance in environmental protection and human safety. This study introduced a novel HS composed of an AlN-based SAW resonator and CuO nanoparticles (NPs) as a chemical interface for NH detection at RT (∼26 °C). The structural, morphological, and chemical compositions were detailly investigated, which demonstrates that the CuO/AlN HS was successfully formed via interfacial modulation.

Electroreduces nitrate to ammonia and converts to nitrogen through chloride ions by CoO/GF cathode: Performance, regulation and mechanism.

With the development of cities, the issue of excess nitrate in wastewater has become increasingly severe. Electrochemical technology has garnered significant attention due to its straightforward operation and environmental sustainability. A CoO/GF cathode was successfully prepared by depositing CoO onto Graphite felt (GF) using an electrochemical deposition-calcination method.

A comparison of objective and subjective measures of physical activity, sedentary and sleep behaviors between persons with and without depressive symptoms.

Background: Major Depressive Disorder (MDD) is characterized by negative recall biases, which may impact how individuals with depressive symptoms report physical activity (PA), sedentary, and sleep behaviors. Additionally, there are discrepancies between subjective and objective behaviors in MDD. Thus, the current study investigated whether individuals with depressive symptoms differ in their subjective and objective PA, sedentary, and sleep behaviors, and whether the magnitude of these discrepancies differ from those in individuals without depressive symptoms.

Nanocomposite TiO/ZnO/chitosan by method sol-gel for self-cleaning application.

TiO/ZnO/Chitosan coated cotton fabric as a self-cleaning, which has been synthesized by various concentrations of TiO: 0.5 g, 1 g, and 2 g through the sol-gel method at pH 9. The self-cleaning test was conducted on TiO/ZnO/Chitosan-coated cotton fabric samples by irradiating for 15 h using UVA-UVB lamps with clothing stain dye.

Associations between long-term exposure to fine particulate matter and its constituents with lung cancer incidence: Evidence from a prospective cohort study in Beijing, China.

Association between long-term exposure to ambient fine particulate matter (PM) and lung cancer incidence is well-documented. However, the role of different PM constituents [black carbon (BC), ammonium (NH), nitrate (NO), organic matter (OM), and inorganic sulfate (SO)] remain unclear. The study aimed to specify the associations between PM constituents and lung cancer incidence.

Circadian gating: concepts, processes, and opportunities.

Circadian clocks provide a biological measure of time that coordinates metabolism, physiology and behaviour with 24 h cycles in the environment. Circadian systems have a variety of characteristic properties, such as entrainment to environmental cues, a self-sustaining rhythm of about 24 h and temperature compensation of the circadian rhythm. In this perspective, we discuss the process of circadian gating, which refers to the restriction of a biological event to particular times of day by the circadian clock.

[Description of the characteristics of invasive home mechanical ventilated patients in Bavaria using routine data from the MD Bavaria].

The number of patients with invasive home mechanical ventilation (IHMV) in Germany is vastly increasing. Currently, only limited data is available on the characteristics of these patients. The aim of the present study was to describe the health care situation of IHMV patients living in Bavaria using routinely collected data within the project OVER BEAS.

The GlnE protein of Azorhizobium caulinodans ORS571 plays a crucial role in the nodulation process of the legume host Sesbania rostrata.

The GlnE enzyme, functioning as an adenylyltransferase/adenylyl-removing enzyme, plays a crucial role in reversible adenylylation of glutamine synthetase (GS), which in turn regulates bacterial nitrogen assimilation. Genomic analysis of Azorhizobium caulinodans ORS571 revealed an open reading frame encoding a GlnE protein, whose function in the free-living and symbiotic states remains to be elucidated. A glnE deletion mutant retained high GS activity even under nitrogen-rich conditions.

Optimizing nitrogen fertilization rate to achieve high yield and high soil quality in paddy ecosystems with straw incorporation.

Plastic film mulching is a potentially water-saving cultivation strategy, while straw return coupled with nitrogen (N) fertilization can ensure sustainable soil productivity and increased soil organic matter (SOM) sequestration. Nevertheless, a comprehensive understanding of how soil quality and agronomic productivity respond to long-term N fertilization and straw incorporation practices under non-flooded conditions with plastic film mulching remains elusive. Herein, a 15-year field experiment with straw incorporation practices (straw return and no straw return) under various N fertilization rates (N0, N1, N2, N3, and N4: 0, 45, 90, 135, and 180 kg N ha, respectively) was conducted to explore their long-term effects.

How to combine SBR and A/O process for pollutant removal in treating digested effluent of swine wastewater.

To solve the problem of low chemical oxygen demand (COD)/N and poor efficiency of single-stage sequencing batch reactor (SBR) or anoxic/oxic process (A/O) in treatment of digested effluent of swine wastewater, combined SBR-A/O and A/O-SBR processes were employed in the addition ratios of 0, 10%, 30%, and 40% (V/V)) of raw swine wastewater (RS). Analysis of pollutants removal performance of SBR-A/O and A/O-SBR systems showed no significant difference between the two systems without RS addition. However, after adding RS, the pollutants removal efficiency of the two systems increased with the increase in the ratio of RS, with SBR-A/O system presenting better pollutants removal performance than A/O-SBR system.

Elucidating molecular characteristics of organic compounds during ozone micro-bubbles treatment based on GC × GC-QTOF-MS and non-targeted analysis.

The ozone micro-bubbles (OCBs) technology is increasingly gaining traction as a promising alternative method for organic compounds removal in wastewater. Nevertheless, there is a scarcity of literature addressing the molecular-level transformation of organic compounds during OCBs treatment. In this work, the secondary effluent from a wastewater treatment plant was treated with ozone milli-bubbles (OLBs) and OCBs, and the fate of organic compounds at the molecular level was investigated using comprehensive two-dimensional gas chromatography quadrupole time-of-flight mass spectrometry (GC × GC-QTOF-MS).

Slow sand filters with variable filtration rates for rainwater purification: Microecological differences between biofilm and water phases.

Slow sand filters (SSFs) have been increasingly applied to rainwater purification in recent years, but the response of SSFs to fluctuating rainfall, as well as the biofilm- and water-phase microecology in SSFs are still poorly understood. This study systematically evaluated the rainwater purification performance of SSFs and compared the bacterial community structure, assembly processes and molecular ecological interactions between the biofilm and water phases. The activated carbon and activated alumina filters exhibited the best performance for NH-N (18.

Insight into nitrogen transformation during the binary NaOH-NaCO molten salt thermal treatment of waste tires.

Molten salt thermal treatment of solid waste is a promising way for energy recovery and pollutant removal. However, the migration of nitrogen during pyrolysis of waste tires poses a challenge for cleaner production. This study investigated nitrogen conversion pathways during waste tires pyrolysis using a binary NaOH-NaCO salt at 425, 500, and 575 °C.

Ethnicity and race as modifiers of the association between patient sex and stage at diagnosis of bladder cancer.

Background: With over 80,000 projected new diagnoses in 2024, bladder cancer remains a significant public health concern. Given the absence of routine screening protocols, identifying high-risk populations becomes crucial for early detection and intervention. This study aimed to investigate whether race and ethnicity modify the association between sex and stage at diagnosis in adults with primary bladder cancer.

Integration of platinum nanoparticles and Pd-porphyrin photosensitiser into a metal-organic framework for effective photocatalytic hydrogen evolution.

A significant enhancement in the photocatalytic activity of metal-organic frameworks (MOFs) is achieved by expanding the visible-light response range through the strategic incorporation of functional groups, such as metalloporphyrins. Herein, Pd-metalised tetrakis(4-carboxyphenyl)porphyrin (PdTCPP) photosensitiser is integrated into the UiO-66-(NH) framework, creating the hybrid material PdTCPP ⊂ UiO-66-(NH) using a facile mixed-ligand strategy. Platinum nanoparticles (Pt NPs) are subsequently introduced as a co-catalyst via in situ photoreduction, resulting in the formation of the Pt/PdTCPP ⊂ UiO-66-(NH) hybrid material, which demonstrates exceptional catalytic performance under visible-light irradiation.

Imaging Electron Beam-Sensitive Twisted Hybrid Perovskite Bilayers at One-Angstrom Resolution.

Twisted halide perovskite bilayers, a type of moiré material, show square moiré patterns with exciting optical properties. Atomic-scale structure analysis and its correlation with properties are difficult to achieve due to the extreme sensitivity of organic-inorganic halide perovskites to the illuminated electron beam in conventional/scanning transmission electron microscopy. Here, we developed a low-dose exit wave reconstruction methodology with a real-space resolution of one angstrom at ∼50 e/Å, which recovers the phase information on the moiré fringes in CHNHPbI (MAPbI) twisted perovskite bilayers at atomic scale, enabling detailed structural analysis of defects and corresponding strain distribution in such moiré materials.

Catalytic Asymmetric Dehydrogenative Si-H/X-H Coupling toward Si-Stereogenic Silanes.

ConspectusChiral organosilicon compounds bearing a Si-stereogenic center have attracted increasing attention in various scientific communities and appear to be a topic of high current relevance in modern organic chemistry, given their versatile utility as chiral building blocks, chiral reagents, chiral auxiliaries, and chiral catalysts. Historically, access to these non-natural Si-stereogenic silanes mainly relies on resolution, whereas their asymmetric synthetic methods dramatically lagged compared to their carbon counterparts. Over the past two decades, transition-metal-catalyzed desymmetrization of prochiral organosilanes has emerged as an effective tool for the synthesis of enantioenriched Si-stereogenic silanes.

A change language for ontologies and knowledge graphs.

Ontologies and knowledge graphs (KGs) are general-purpose computable representations of some domain, such as human anatomy, and are frequently a crucial part of modern information systems. Most of these structures change over time, incorporating new knowledge or information that was previously missing. Managing these changes is a challenge, both in terms of communicating changes to users and providing mechanisms to make it easier for multiple stakeholders to contribute.

Inorganic nitrogen and organic matter jointly regulate ectomycorrhizal fungi-mediated iron acquisition.

Ectomycorrhizal fungi (EMF) play a crucial role in facilitating plant nutrient uptake from the soil although inorganic nitrogen (N) can potentially diminish this role. However, the effect of inorganic N availability and organic matter on shaping EMF-mediated plant iron (Fe) uptake remains unclear. To explore this, we performed a microcosm study on Pinus taeda roots inoculated with Suillus cothurnatus treated with +/-Fe-coated sand, +/-organic matter, and a gradient of NHNO concentrations.