Facile and rapid synthesis of functionalized Zr-BTC for the optical detection of the blistering agent simulant 2-chloroethyl ethyl sulfide (CEES).

2-Chloroethyl ethyl sulfide (CEES) is a simulant for the chemical warfare agent, bis(2-chloroethyl) sulfide, also known as mustard gas. Here, we demonstrate a facile and rapid method to synthesize a functionalized metal-organic framework (MOF) material for the detection of CEES at trace level. During the synthesis of Zr-BTC, the in situ encapsulation of a fluorescent material (fluorescein) into Zr-BTC voids is performed by a simple solvothermal reaction.

Synthesis of a novel Ce(iii)/melamine coordination polymer and its application for corrosion protection of AA2024 in NaCl solution.

We present the synthesis of a new cerium(iii)-melamine coordination polymer (CMCP) by a mixed-solvothermal method and its characterization. Characterization techniques included Raman, Fourier Transformation Infra-Red (FTIR), X-Ray Diffraction (XRD) and Scanning Electron Microscope (SEM), in which the change in the electronic environment and the crystallinity were tracked. The characterization results confirm the coordination of cerium(iii) with melamine through -NH groups, instead of the N atoms of the triazine ring, for which we propose a mechanism of interaction.

Hyperspectral imaging assessment for radiotherapy induced skin-erythema: Pilot study.

Skin cancer (SC) is a widely spread disease in the USA, Canada, and Australia. Skin cancer patients may be treated by many different techniques including radiation therapy. However, radiation therapy has side effects, which may range from skin erythema to skin necrosis.

Delineation of the Arm Blood Vessels Utilizing Hyperspectral Imaging to Assist with Phlebotomy for Exploiting the Cutaneous Tissue Oxygen Concentration.

Significance: The estimation of tissue oxygenation is vital in the diagnosis and therapeutic evaluation of a huge assortment of diseases. The hyperspectral (HS) imaging system is a rising innovation that can be utilized to build a highly sensitive, non-invasive, and tissue hemoglobin immersion map.

Objective: As a result of the urgent need to design and implement early detection devices and applications for the COVID-19 pandemic, we propose building a non-invasive custom optical imaging system to assist with phlebotomy and vascular approach to survey the reliability of blood oxygen saturation (SpO2) levels recovered from spectral images.

Skin erythema and pigmentation: a review of optical assessment techniques.

Background: Skin erythema may present due to many causes. One of the common causes is prolonged exposure to sun rays. Other than sun exposure, skin erythema is an accompanying sign of dermatological diseases such as acne, psoriasis, melasma, post inflammatory hyperpigmentation, fever, as well as exposure to specific electromagnetic wave bands.

Nanocomposite matrix conjugated with carbon nanomaterials for photocatalytic wastewater treatment.

The problem of hazardous wastewater remediation is a complicated issue and a global challenge. Herein, a layered CoNiFeO/SiO/TiO composite matrix was prepared and incorporated with three carbon nanomaterials having different dimensionalities, carbon dots (C-dots, 0D), single-walled carbon nanotubes (1D), and reduced graphene oxide (2D), in an effort to create effective photocatalytic nanocomposites for chloramine-T removal from water. Microstructural analyses confirmed the formation of nanocomposites and revealed their chemistry and structure.

Custom optical imaging system for ex-vivo breast cancer detection based on spectral signature.

Background And Purpose: Breast cancer is a popular well-known tumor in women globally and the subsequent driving reason for malignancy death. The purpose of the present study is to develop Low cost, commercial, and affordable system that discriminates malignant from normal breast tissues by exploiting the unique properties of Hyperspectral (HS) Imaging.

Materials And Methods: The difference in the optical properties of the investigated breast tissues gives various reactions to light transmission, absorption, and especially the reflection over the spectral range.

Engineered nanomaterials as fighters against SARS-CoV-2: The way to control and treat pandemics.

In this editorial trend, we aim to collect and present recently available data about the characteristics of SARS-CoV-2 virus, severity, infection, replication, diagnosis, and current medications. In addition, we propose the role of nanomaterials in controlling and treating COVID-19 through their antiviral and antibacterial potential with suggested action mechanisms indicating the capability of interaction between these nanomaterials and SARS-CoV-2. These nanomaterials might be among the possible and most effective cures against coronavirus.

3D spectral fluorescence signature of cerium(III)-melamine coordination polymer: A novel sensing material for explosive detection.

Hidden or buried explosives are the most common scenario by terrorist attacks; therefore explosive vapour detection is a vital demand. Explosives are electron deficient materials; the vicinity of explosives to fluorescent material can encounter electron migration. This study reports on facile synthesis of cerium (III)-melamine coordination polymer (CeM-CP) with exclusive optical properties.

Nanostructured Mg substituted Mn-Zn ferrites: A magnetic recyclable catalyst for outstanding photocatalytic and antimicrobial potentials.

With recently increasing the environmental problems and expected energy crisis, it is necessary to synthesis a low-cost, efficient, and UV-light responsive photocatalyst for contaminants' degradation. The nanostructured spinel ferrite MnZnMgFeO NPs (x = 0.0, 0.

Crystal structure, vibrational spectroscopy and optical properties of a one-dimensional organic-inorganic hybrid perovskite of [NHCHCH(NH)CH]BiCl.

In this work the crystal structure by single crystal X-ray measurement and optical properties of 1D propane-1,2-diammonium pentachlorobismuthate [NHCHCH(NH)CH]BiCl organic-inorganic hybrid perovskite are presented. It is prepared by mixing ethanolic solution of equimolar ratios (1:1) of its basic components. The title compound crystallized in the noncentrosymmetric orthorhombic space group Pca2 with Z = 8 molecules per unit cell.

Graphene oxide-based nanocomposites (GO-chitosan and GO-EDTA) for outstanding antimicrobial potential against some Candida species and pathogenic bacteria.

To obtain the synergistic antimicrobial potential of nano-composites conjugated with graphene oxide (GO), an alternative approach was developed throughout the hybridization of chitosan (CS) or ethylene diamine tetraacetic acid (EDTA) with GO. The synthesized GO-nanocomposites were identified by XRD, HRTEM, SEM, FTIR, Zeta potential, and Raman spectroscopy. The antimicrobial activity of GO, GO-CS, and GO-EDTA was investigated against some pathogenic bacteria and Candida sp.

Hyperspectral imaging for diagnosis and detection of ex-vivo breast cancer.

Background And Purpose: Breast cancer is one of the most widely recognized tumors. .Diagnosis made in the early stage of disease may imporve outcomes.

Carbon-dot-loaded CoNiFeO; x = 0.9/SiO/TiO nanocomposite with enhanced photocatalytic and antimicrobial potential: An engineered nanocomposite for wastewater treatment.

Water scarcity is now a serious global issue resulting from population growth, water decrease, and pollution. Traditional wastewater treatment plants are insufficient and cannot meet the basic standards of water quality at reasonable cost or processing time. In this paper we report the preparation, characterization and multiple applications of an efficient photocatalytic nanocomposite (CoNiFeO; x = 0.

Tissue characterization utilizing hyperspectral imaging for liver thermal ablation.

Background: Thermal ablation is the dominant modality to treat liver tumors for patients who are not surgical candidates. . However, correctly predicting the volume of the subsequent tissue destruction during the Thermal Ablation technique is a difficult undertaking.

Laser induced fluorescence with 2-D Hilbert transform edge detection algorithm and 3D fluorescence images for white spot early recognition.

Objective: There is a must for non-invasive caries detection method to supplement traditional visual assessment by the clinician before lesion progression reaches a stage requiring invasive therapy.

Material And Methods: In this paper, the nature of tissue response to light interaction has been used for early diagnosis, using laser induced fluorescence spectroscopy. Human tooth sample was illuminated with He-Ne laser sources (633 nm) with energy 5 mW.

Highly selective and sensitive fluorescent zeolitic imidazole frameworks sensor for nitroaromatic explosive detection.

Nitroaromatic explosives, such as 2-4-6 trinitrotoluene (TNT) are dangerous materials that pose safety and environmental risks. Even though many sensors have been reported for the detection of nitroaromatic explosives, a facile, rapid, cost-effective sensor is still sought-after in the field. Here we demonstrate a facile and rapid method to synthesize a fluorescent metal-organic framework for the highly selective and sensitive detection of nitroaromatic explosives.

Microbial acetylcholinesterase inhibitors for Alzheimer's therapy: recent trends on extraction, detection, irradiation-assisted production improvement and nano-structured drug delivery.

Neurodegenerative disorders especially Alzheimer's disease (AD) are significantly threatening the public health. Acetylcholinesterase (AChE) inhibitors are compounds of great interest which can be used as effective agents for the symptomatic treatment of AD. Although plants are considered the largest source for these types of inhibitors, the microbial production of AChE inhibitors represents an efficient, easily manipulated, eco-friendly, cost-effective, and alternative approach.

Nystatin-mediated bismuth oxide nano-drug synthesis using gamma rays for increasing the antimicrobial and antibiofilm activities against some pathogenic bacteria and species.

The novelty of the present research is the synthesis of bismuth oxide nanoparticles (BiO NPs) loaded with the antifungal nystatin drug gamma rays for increased synergistic antimicrobial potential against some pathogenic bacteria and species. The full characterization of the synthesized BiO NPs-Nystatin was achieved by XRD, FT-IR, HR-TEM, and SEM/EDX mapping techniques in order to analyze the crystallinity, chemical functional groups, average particle size, morphology, and elemental structure, respectively. The antimicrobial activities of BiO NPs-Nystatin were examined against pathogenic bacteria and species, including the zone of inhibition (ZOI), minimum inhibitory concentration (MIC), and antibiofilm activity.

Surface modified colloidal silica nanoparticles: Novel aspect for complete identification of explosive materials.

Terrorism by means of explosives has become a crucial threat. Nanoparticles with distinctive properties can offer novel aspects for instant detection of explosive materials. Common explosives are organic compounds that contain nitro group (NO) along with carbon and hydrogen elements.

Merits of photocatalytic and antimicrobial applications of gamma-irradiated Co Ni FeO/SiO/TiO; = 0.9 nanocomposite for pyridine removal and pathogenic bacteria/fungi disinfection: implication for wastewater treatment.

In this paper, we report a layer-by-layer approach for the preparation of a concentric recyclable composite (Co Ni FeO/SiO/TiO; = 0.9) designed for wastewater treatment. The prepared composite was investigated by X-ray diffraction spectroscopy, high-resolution transmission electron microscopy and scanning electron microscopy (SEM) supported with energy dispersive X-ray (EDX) spectroscopy to analyze crystallinity, average particle size, morphology and elemental composition, respectively.

Corrosion protection mechanism of Ce/organic inhibitor for AA2024 in 3.5% NaCl.

Cerium is a rare earth element that has been widely proposed for the corrosion protection of aluminium alloys (AA). Both cerium salts, Ce and Ce, have been used in combination with other compounds to offer synergistic inhibition, however, the inhibitive corrosion mechanism when using Ce with organic compounds is still not clear. In this study, the synergistic inhibition effect of Ce and melamine (M) on the corrosion of aluminium alloy 2024 (AA2024) in 3.

Factorial design-optimized and gamma irradiation-assisted fabrication of selenium nanoparticles by chitosan and Pleurotus ostreatus fermented fenugreek for a vigorous in vitro effect against carcinoma cells.

The novelty of the present work looks in the synthesis of aqueous dispersed selenium nanoparticles (Se NPs) using gamma rays with the aid of various natural macromolecules such as citrus pectin (CP), sodium alginate (Alg), chitosan (CS) and aqueous extract of fermented fenugreek powder (AEFFP) using Pleurotus ostreatus for investigating their impact in vitro toward carcinoma cell. The synthesized Se NPs were characterized by XRD, UV-Vis., DLS, HRTEM, SEM, EDX and FTIR.

Fabrication of Ultra-Pure Anisotropic Zinc Oxide Nanoparticles via Simple and Cost-Effective Route: Implications for UTI and EAC Medications.

The purposes of this work are to evaluate the antimicrobial, antibiofilm, anticancer, and antioxidant abilities of anisotropic zinc oxide nanoparticles (ZnO NPs) synthesized by a cost-effective and eco-friendly sol-gel method. The synthesized ZnO NPs were entirely characterized by UV-Vis, XRD, FTIR, HRTEM, zeta potential, SEM mapping, BET surface analyzer, and EDX elemental analysis. Antimicrobial and antibiofilm activities of ZnO NPs were investigated against multidrug-resistant (MDR) bacteria and yeast causing serious diseases like urinary tract infection (UTI).

Gentamicin-Assisted Mycogenic Selenium Nanoparticles Synthesized Under Gamma Irradiation for Robust Reluctance of Resistant Urinary Tract Infection-Causing Pathogens.

The purpose of this research is to compare and enhance the antimicrobial and antibiofilm potentials of the biogenic selenium nanoparticles (Se NPs) produced by cost-effective and eco-friendly green methods. The synthesis of Se NPs is described in this manuscript by two different methods: a biogenic process using Penicillium chrysogenum filtrate and by utilizing gentamicin drug (CN) following the application of gamma irradiation. Se NPs were characterized by UV-Vis.