Observation of Collective Photoswitching in Free-Standing TATA-Based Azobenzenes on Au(111).

Light-induced transitions between the trans and cis isomer of triazatriangulenium-based azobenzene derivatives on Au(111) surfaces were observed directly by scanning tunneling microscopy, allowing atomic-scale studies of the photoisomerization kinetics. Although the azobenzene units in these adlayers are free-standing and spaced at uniform distances of 1.26 nm, their photoswitching depends on the isomeric state of the surrounding molecules and, specifically, is accelerated by neighboring cis isomers.

Chironomids (Insecta, Diptera, Chironomidae) from alpine lakes in the Eastern Carpathians with comments on newly-recorded species from Ukraine.

Background: The first summarising checklist of Ukrainian Chironomidae (Insecta, Diptera) consisted of 302 species. Compared to other European countries, it is obvious that the real chironomid diversity of Ukraine has not been fully documented and greater effort is needed to discover the actual richness of this family. Thus, our survey focused on the chironomid fauna of some alpine lakes situated above the treeline in the Ukrainian Carpathians (a part of the Eastern Carpathians) aiming to contribute to the knowledge of the Ukrainian chironomid fauna and create the basis for more comprehensive neo- and palaeolimnological studies of these, regionally, little-known ecosystems.

The DIRAC code for relativistic molecular calculations.

DIRAC is a freely distributed general-purpose program system for one-, two-, and four-component relativistic molecular calculations at the level of Hartree-Fock, Kohn-Sham (including range-separated theory), multiconfigurational self-consistent-field, multireference configuration interaction, electron propagator, and various flavors of coupled cluster theory. At the self-consistent-field level, a highly original scheme, based on quaternion algebra, is implemented for the treatment of both spatial and time reversal symmetry. DIRAC features a very general module for the calculation of molecular properties that to a large extent may be defined by the user and further analyzed through a powerful visualization module.

Legionnaires' Disease in Pediatric Patients, Control Measures and 5-Year Follow-up.

Background: Legionnaires' disease (LD) occurs predominantly in adults and elderly people. Its incidence in Europe has been increasing in recent years. It is rare in younger age groups and prone to be reported as healthcare-associated infection with a higher risk of fatal outcome.

Correction to: The Bacterial Population of Neutral Mine Drainage Water of Elizabeth's Shaft (Slovinky, Slovakia).

The article "The Bacterial Population of Neutral Mine Drainage Water of Elizabeth's Shaft (Slovinky, Slovakia)", written by Jana Kisková, Zuzana Perháèová, Ladislav Vlèko, Jana Sedláková, Simona Kvasnová and Peter Pristaš, was originally published electronically on the publisher's internet portal on 12 March 2018 without open access. With the author(s)' decision to opt for Open Choice the copyright of the article changed on 9 April 2020 to © The Author(s) 2018 and the article is forthwith distributed under a Creative Commons Attribution 4.0 International License ( https://creativecommons.

Analysis of Hygrothermal Microclimatic (HTM) Parameters in Specific Food Storage Environments in Slovakia.

The quality of work environment, temperature changes and humidity must be controlled in every production process and in the locations where employees are present. The aim of this paper is to objectively assess the exposure of employees to microclimatic factors of the workplace environment: the warehouse, changing rooms, office and cold room refrigerator. Data were obtained in real working conditions.

The Wedding with a Stolen Goddess: The Ethnography of a Cult in Rural Tamil Nadu.

The paper provides a critical overview of the perspective that stratifies society in India into a series of different classes, resulting in the mobility of particular castes or social groups. For this purpose, the study presents ethnographic material concerning the foundation and development of a non-Brahman temple in the Tamil low-caste settlement of Line Kollai, which is in a neighbourhood close to the city of Krishnagiri. The presented ethnographic material shows how a religious folk cult has been established on the grounds of actualized and modified motives in the vernacular environment.

Occupational Exposure to Dust Produced when Milling Thermally Modified Wood.

During production, thermally modified wood is processed using the same machining operations as unmodified wood. Machining wood is always accompanied with the creation of dust particles. The smaller they become, the more hazardous they are.

Partitioning of interaction-induced nonlinear optical properties of molecular complexes. II. Halogen-bonded systems.

Following our study on hydrogen-bonded (HB) complexes [Phys. Chem. Chem.

Exploration of Disparities in Regions and Specialized Fields of Day Surgery System.

The main objective of this paper was to find similarities among eight Slovak regions from the viewpoint of five specialized day surgery fields and among specialized day surgery fields from the viewpoint of Slovak regions on the basis of day surgery operated and hospitalized patient counts. Day surgery data of paediatric patients and of adult patients from the National Health Information Centre during the years 2009-2017 were used. Correspondence analysis in two dimensions of the Slovak regions and of specialized day surgery fields was applied in order to achieve the paper's objective.

A preliminary checklist of Chironomidae (Diptera) from Albania with first records for the Balkan Peninsula.

The Chironomidae of Albania have so far received limited attention and only 39 species have been recorded prior to the present study. Here we bring the results of random and non-intensive samplings of chironomid pupal exuviae and adults, at five localities in 2012, that provided 55 species and 5 additional taxa, with 51 being new for the Albanian fauna, out of which 7 were new for the Balkan Peninsula. In addition to that, we present a preliminary checklist of Chironomidae based on the data from Fauna Europaea complemented by the results of the recent investigation.

Global distribution of earthworm diversity.

Soil organisms, including earthworms, are a key component of terrestrial ecosystems. However, little is known about their diversity, their distribution, and the threats affecting them. We compiled a global dataset of sampled earthworm communities from 6928 sites in 57 countries as a basis for predicting patterns in earthworm diversity, abundance, and biomass.

Sense of Coherence and Connectedness to Nature as Predictors of Motivation for Practicing Karate.

: Physical activity yields exceptionally positive results when it takes place out in the open air, in contact with nature. Both contact with nature and practicing sport constitute a certain kind of philosophy of life and living by its rules plays a vital role in positive mental health-understood as maintaining a high sense of coherence. Martial arts are examples of sports that are rooted in a philosophy.

Properties and Reactivity of Hydroxides of Group 13 Elements In, Tl, and Nh from Molecular and Periodic DFT Calculations.

Adsorption energies, , of gaseous hydroxides of In, Tl, and the superheavy element Nh on surfaces of Teflon and gold are predicted using molecular and periodic relativistic DFT calculations. The ambition of the work is to assist related "one atom at a time" gas-phase chromatography experiments on the volatility of NhOH. The obtained low values of (MOH), where M = In, Tl, Nh, on Teflon should guarantee easy transportation of the molecules through the Teflon capillaries from the accelerator to the chemistry setup.

Iminothioindoxyl as a molecular photoswitch with 100 nm band separation in the visible range.

Light is an exceptional external stimulus for establishing precise control over the properties and functions of chemical and biological systems, which is enabled through the use of molecular photoswitches. Ideal photoswitches are operated with visible light only, show large separation of absorption bands and are functional in various solvents including water, posing an unmet challenge. Here we show a class of fully-visible-light-operated molecular photoswitches, Iminothioindoxyls (ITIs) that meet these requirements.

Comparative molecular cell biology of phototrophic euglenids and parasitic trypanosomatids sheds light on the ancestor of Euglenozoa.

Parasitic trypanosomatids and phototrophic euglenids are among the most extensively studied euglenozoans. The phototrophic euglenid lineage arose relatively recently through secondary endosymbiosis between a phagotrophic euglenid and a prasinophyte green alga that evolved into the euglenid secondary chloroplast. The parasitic trypanosomatids (i.

Can Density Functional Theory Be Trusted for High-Order Electric Properties? The Case of Hydrogen-Bonded Complexes.

This work reports on an extensive assessment of the performance of a wide palette of density functional approximations in predicting the (high-order) electric properties of hydrogen-bonded complexes. To this end, we compute the electronic and vibrational contributions to the electric polarizability and the first and second hyperpolarizabilities, using the CCSD(T)/aug-cc-pVTZ level of theory as reference. For all the studied properties, the average absolute errors below 20% can only be obtained using the CAM-B3LYP functional, while LC-BLYP and MN15 are shown to be only slightly less accurate (average absolute errors not exceeding 30%).

Functionality of Beech Bark in Adhesive Mixtures Used in Plywood and Its Effect on the Stability Associated with Material Systems.

The results of research into utilizing grinded beech bark in order to substitute commonly used fillers in urea formaldehyde (UF) adhesive mixtures to bond plywood are presented in the present study. Four test groups of plywood with various adhesive mixtures were manufactured under laboratory conditions and used for experimentation. Plywood made using the same technology, with the common filler (technical flour), was used as a reference material.

Flooding and hydrologic connectivity modulate community assembly in a dynamic river-floodplain ecosystem.

Braided river floodplains are highly dynamic ecosystems, where aquatic communities are strongly regulated by the hydrologic regime. So far, however, understanding of how flow variation influences assembly mechanisms remains limited. We collected benthic chironomids and oligochaetes over a year across a lateral connectivity gradient in the semi-natural Tagliamento River (Italy).

The role of organo-zeolitic material in supporting phytoremediation of a copper mining waste dump.

The effect of applying organo-zeolitic (OZ) amendment in supporting phytoremediation of a copper mine waste dump, using a substrate obtained from Ľubietová, Central Slovakia, was studied. Three plant growth substrates were prepared: (i) the untreated substrate sample from the contaminated site (D-O), (ii) the contaminated sample treated with OZ material, with 82% D-O and 18% OZ (DO + OZ), (iii) the soil from a reference site (R). The largest amount of dry biomass was obtained from the DO + OZ sample.

Problematic and risky sexual behaviour under the influence of alcohol among university students.

Objective: The objective of this research was to determine the prevalence of problematic and risky sexual behaviour after alcohol consumption and the correlation between this prevalence and sex, behavioural factors, problematic drinking, and alcohol consumption characteristics.

Methods: A survey of students was carried out at four faculties. Data were gathered via internet and self-administered paper-pencil questionnaires.

Origin and behavior of radionuclides in sediment core: a case study of the sediments collected from man-made reservoirs located in the past mining region in Central Slovakia.

The analyzed sediments were taken from the man-made reservoirs (Velka Richnava, Rozgrund and Vindsachta) located in an area intensively mined for polymetallic ores since the end of the eleventh century (Banska Stiavnica region, Central Europe). The aims of this study were to determine the radioactivity of natural (Ra, Th, Pb) and artificial (Cs and Am) radionuclides, compare the radionuclides' distribution, and indicate the correlation of radioisotopes and their origin related to sediment properties. Two analytical techniques were used.

Peculiar features of the plastids of the colourless alga Euglena longa and photosynthetic euglenophytes unveiled by transcriptome analyses.

Euglenophytes are a familiar algal group with green alga-derived secondary plastids, but the knowledge of euglenophyte plastid function and evolution is still highly incomplete. With this in mind we sequenced and analysed the transcriptome of the non-photosynthetic species Euglena longa. The transcriptomic data confirmed the absence of genes for the photosynthetic machinery, but provided candidate plastid-localised proteins bearing N-terminal bipartite topogenic signals (BTSs) of the characteristic euglenophyte type.

Monitoring of methylated naphthalenes in sludge-derived pyrogenic carbonaceous materials.

Methylated analogues of polycyclic aromatic hydrocarbons (PAHs) represent important environmental contaminants produced often at process of feedstock thermochemical conversion. In the present study, we determined and compared levels of 1-methylnaphtalene and 2-methylnaphtalene in municipal sewage sludge (MSS), sludge-derived pyrogenic carbonaceous materials produced at 350 °C (PCM350) and 500 °C (PCM500) in process of slow pyrolysis. The highest extraction efficiency of both aromatic structures from MSS, PCM350 and PCM500 for toluene as extraction agent and 36 h of extraction time was revealed.