Efficient removal of Cu and methylene blue pollutants from an aqueous solution by applying a new hybrid adsorbent based on alginate-chitosan and HAP derived from Moroccan rock phosphate.

Alginate-chitosan/hydroxyapatite (Alg-Cs/HAP) beads were prepared as adsorbent to remove methylene blue (MB) and copper ions from an aqueous solution using a batch system. FTIR, TGA, point of zero charge (pH), SEM, XRD, and BET analysis were used to characterize the elaborated material. The effect of several parameters such as initial pH value, adsorbent dose, temperature, contact time, and initial pollutant concentration were also investigated.