Interfacial Engineering of MoS@CoS Heterostructure Electrocatalysts for Effective pH-Universal Hydrogen Evolution Reaction.

The practical utilization of the hydrogen evolution reaction (HER) necessitates the creation of electrocatalysts that are both efficient and abundant in earth elements, capable of operating effectively within a wide pH range. However, this objective continues to present itself as an arduous obstacle. In this research, we propose the incorporation of sulfur vacancies in a novel heterojunction formed by MoS@CoS, designed to exhibit remarkable catalytic performances.

Comparison of the Effect of Resistance and Balance Training on Isokinetic Eversion Strength, Dynamic Balance, Hop Test, and Ankle Score in Ankle Sprain.

Ankle sprain is a commonly recurring sports injury. This study aimed to compare the rehabilitation effects of resistance and balance training programs in patients with recurrent ankle sprain. Patients with recurrent lateral ankle sprain completed a home-based rehabilitation program comprising resistance training (RT; = 27) or balance training (BT; = 27).

Phase diagram and superconductivity of compressed zirconium hydrides.

It is known that pressure can be applied to fundamentally alter the bonding patterns between the chemical elements. By employing an unbiased structure search method based on a particle swarm optimization (PSO) methodology, the phase diagram and crystal structures of Zr-H compounds are systematically investigated at a high pressure up to 150 GPa. Interestingly, some unexpectedly stable compounds with unusual chemical and physical properties are predicted to be formed, for example, four stable and metallic species with stoichiometries of ZrH, ZrH, ZrH, and ZrH are identified for the first time.

Crystal structures and superconductivity of technetium hydrides under pressure.

Guided by a simple strategy in search of new superconducting materials, we have performed extensive simulations on crystal structures and electronic properties of Tc-H compounds at high pressures. Three stoichiometries, namely TcH, TcH, and TcH, were predicted to be stable under high pressure. The chemical bonding characters of Tc-H compounds were investigated by introducing the electron localization function and electronic projected density of states, which show that the stable Tc-H compounds including TcH, TcH and TcH are all classified as ionic crystals as a result of Tc → H charge transfer.

Quantum key distribution with prepare-and-measure Bell test.

The prepare-and-measure quantum key distribution (QKD) has the merits of fast speed, high key generation rate, and easy implementation. However, the detector side channel attacks greatly undermine the security of the key bits. The eavesdropper, Eve, exploits the flaws of the detectors to obtain illegal information without violating quantum principles.

Phase diagram and physical properties of iridium tetraboride from first principles.

Using both the swarm-intelligence-based CALYPSO method and the multi-algorithm-collaborative (MAC) algorithm for crystal structure prediction, three unexpected new phases (P63/mmc, C2/m and Cmca) of IrB4 are predicted. The P63/mmc phase is the ground-state structure under ambient conditions, while C2/m and Cmca phases form at high pressure. The phase stabilities, mechanical and electronic properties of the three new phases of IrB4 are investigated systematically.

Stable Lithium Argon compounds under high pressure.

High pressure can fundamentally alter the bonding patterns of chemical elements. Its effects include stimulating elements thought to be "inactive" to form unexpectedly stable compounds with unusual chemical and physical properties. Here, using an unbiased structure search method based on CALYPSO methodology and density functional total energy calculations, the phase stabilities and crystal structures of Li-Ar compounds are systematically investigated at high pressure up to 300 GPa.

Micro-Raman analysis of the pigments on painted pottery figurines from two tombs of the Northern Wei Dynasty in Luoyang.

The pigments on the painted pottery figurines from two tombs of Northern Wei Dynasty (AD 386-534) in Luoyang were analyzed by Raman microscopy. All the pigments were identified compared with the Raman spectra of standard pigments. The red pigments were identified as haematite, the blue pigment as lapis lazuli, the green pigment as malachite, the black pigment as carbon black and the white pigment as calcite.

[Raman, FTIR spectra and normal mode analysis of acetanilide].

The Raman and FTIR spectra of acetanilide (ACN) were measured experimentally in the regions of 3 500-50 and 3 500-600 cm(-1) respectively. The equilibrium geometry and vibration frequencies of ACN were calculated based on density functional theory (DFT) method (B3LYP/6-311G(d, p)). The results showed that the theoretical calculation of molecular structure parameters are in good agreement with previous report and better than the ones calculated based on 6-31G(d), and the calculated frequencies agree well with the experimental ones.

Scattering-induced changes in the temporal coherence length and the pulse duration of a partially coherent plane-wave pulse.

The scattering of a partially coherent plane-wave pulse on a Gaussian-correlated, quasi-homogeneous random medium is investigated. The analytical expressions for the temporal coherence length and the pulse duration of the scattered field are derived. We demonstrate that the scattering-induced changes in the temporal coherence length and the pulse duration may be used to determine the correlation function of the scattering potential of the medium.

[Study on the configuration and applications of high spectral resolution Raman spectrometer].

In the present paper the authors studied theoretically and experimentally the relationship between spectral resolution and grating density, the limitations to improve the spectral resolution by using high density grating, the use of longer focal length grating to increase spectral resolution without compromising instrument throughput and the effect of slit width on spectral resolution and sensitivity. Finally, two experiment results were provided to show why higher spectral resolution is important to ensure that critical information is not lost during a Raman measurement. Stressed silicon was produced by growing a thin crystalline layer of Si on an Si(x)Ge(1-x) substrate.

[Digital acoustic burglar alarm system using infrared radio remote control].

Using butt emission infrared sensors, radio receiving and sending modules, double function integrated circuit with code and code translation, LED etc, a digital acoustic burglar alarm system using infrared radio to realize remote control was designed. It uses infrared ray invisible to eyes, composing area of radio distance. Once people and objects shelter the infrared ray, a testing signal will be output by the tester, and the sender will be triggered to work.

Effects of astigmatism on spectra, coherence and polarization of stochastic electromagnetic beams passing through an astigmatic optical system.

Analytical formulas for the cross-spectral density matrix of stochastic electromagnetic Gaussian Schell-model (EGSM) beams passing through an astigmatic optical system are derived. We show both analytically and by numerical examples the effects of astigmatism on spectra, coherence and polarization of stochastic electromagnetic EGSM beams propagating through an astigmatic lens. A comparison with the aberration-free case is made, and shows that the astigmatism has significant effect on the spectra, coherence and polarization.

Effect of dispersion on the spectrum of partially coherent beams.

Taking the Gaussian Schell-model (GSM) beam as a typical example of partially coherent beams, the analytical expressions of the spectrum of GSM beams propagating in dispersive media are derived, and the spectral properties are studied in detail. It is shown that, in comparison with propagation in free space and in turbulence, whether or not GSM beams satisfy the scaling law, the normalized spectrum of GSM beams in dispersive media changes on propagation in general, because the dispersive medium affects different spectral components differently. As compared with the free-space propagation, for the scaling-law GSM beams the dispersion results in spectrum change, and for the nonscaling-law GSM beams the dispersion gives rise to a further increase in spectral changes.

[Research on infrared safety protection system for machine tool].

In order to ensure personal safety and prevent injury accident in machine tool operation, an infrared machine tool safety system was designed with infrared transmitting-receiving module, memory self-locked relay and voice recording-playing module. When the operator does not enter the danger area, the system has no response. Once the operator's whole or part of body enters the danger area and shades the infrared beam, the system will alarm and output an control signal to the machine tool executive element, and at the same time, the system makes the machine tool emergency stop to prevent equipment damaged and person injured.

[Application of near infrared sensor to the radio control count system].

Using reflective near infrared sensor, radio receiving/transmitting module and four-in-one function mix count integrated circuits, the radio control infrared counter was studied when a product enters the infrared surveillance area, part of the infrared signal will be reflected by the product, received by the photosensitive tube installed parallel with the transmitting tube, and transformed to a similar frequency electric signal, which is amplified by the internal circuits of infrared sensor module. After comparing and processing, a high level signal will be output to start transmitting module. When the receiving device receives the radio control encoded signal, it will demodulate and decode the signal, and send out an encoded pulse.

[Application of pyroelectric infrared sensor to radio control alarm system].

A radio control alarm system was developed, which is composed of a pyroelectric infrared detecting module, a radio receiving/transmitting module, a digital encoding/decoding IC, and a voice recoding/playing module. When somebody enters the surveillance area, the infrared sensor will receive and transform the radiant energy into electric signal, which is amplified by internal circuits, and then generates a control signal to start transmitting system. As the encoded pulse is modulated by the transmitting module, a radio control signal will be spread to space; When received, the signal will be demodulated, amplified, shaped and decoded to trigger the recoding/playing circuits, which play the recoded voice to awake watch people.

[Study on the application of pyroelectric infrared sensor to safety protection system].

Using the infrared ray of human body, which is received and magnified by pyroelectric infrared sensor to form a certain voltage control signal, and using the control signal to trigger a voice recording-reproducing circuit, a pyroelectric infrared detector voice device with auto-control function designed. The circuit adopted new pyroelectric infrared detector assembly and voice recording-reproducing assembly. When someone is present in the detectable range of the pyroelectric infrared detector, first, the pyroelectric infrared sensor will transform the incepted radiation energy to a electric signal, which is then magnified and compared by an inside circuit, and an output control signal, touches off the voice recording-reproducing assembly with the reproducer sending out a beforehand transcribed caution voice to wise the man who does not know well the surrounding condition that the frontage is a danger zone and should not be approched.

Improved diffraction integral for studying the diffracted field of a spherical microlens.

By introducing a new kind of Green function, we formulate an improved diffraction integral, which can be used to numerically evaluate the diffracted field of a microlens of plane-convex shape. Analytical expressions for the diffracted field of microlens are derived for the case where the curvature radius of the convex surface is larger than the dimension of the microlens aperture. The validity of the results and the diffracted field of the microlens are illustrated with numerical examples.

Propagation of Hermite-Gaussian and Laguerre-Gaussian beams beyond the paraxial approximation.

On the basis of the vectorial Rayleigh-Sommerfeld formulas and by means of the relation between Hermite and Laguerre polynomials, the analytical expressions for the propagation of the Hermite-Gaussian (HG) and Laguerre-Gaussian (LG) beams beyond the paraxial approximation are derived, with the corresponding far-field propagation expressions and that for the Gaussian beams being given as special cases of the results. Some detailed comparisons of our results with the expansion series and paraxial expressions are made, which show the advantages of our results over the expansion series. With the results obtained, some typical intensity patterns of nonparaxial HG and LG beams are shown.

Polarization properties of vectorial nonparaxial Gaussian beams in the far field.

The polarization properties of vectorial coherent nonparaxial Gaussian beams are studied. It is shown that, when the source of a nonparaxial Gaussian beam is completely polarized, the degree of polarization of the propagation field maintains a constant value of 1. However, when the source is completely unpolarized, the degree of polarization does not maintain a constant value of 0.

Partially coherent vectorial nonparaxial beams.

Generalized vectorial Rayleigh-Sommerfeld diffraction integrals are developed for the cross-spectral-density matrices of spatially partially coherent beams. Using the Gaussian Schell-model (GSM) beam as an example, we derive the expressions for the propagation of cross-spectral-density matrices and intensity of partially coherent vectorial nonparaxial beams, and the corresponding far-field asymptotic forms, beyond the paraxial approximation. The propagation of the vectorial nonparaxial GSM beams are evaluated and analyzed.

Vectorial nonparaxial propagation equation of elliptical Gaussian beams in the presence of a rectangular aperture.

Based on the vectorial Rayleigh-Sommerfeld diffraction integrals, an analytical propagation equation of vectorial, nonparaxial, elliptical Gaussian beams through a rectangular aperture is derived. Unlike in previous work, the aperture effect and nonrotational symmetry of the beam and aperture are considered in our theoretical model. The results of the far-field and paraxial approximation for the apertured case are treated as special cases of our general expression.

Partially coherent nonparaxial beams.

The concept of a partially coherent nonparaxial beam is proposed. A closed-form expression for the propagation of nonparaxial Gaussian Schell model (GSM) beams in free space is derived and applied to study the propagation properties of nonparaxial GSM beams. It is shown that for partially coherent nonparaxial beams a new parameter f(sigma) has to be introduced, which together with the parameter f, determines the beam nonparaxiality.