Construction of magnetic MoS/NiFeO/MIL-101(Fe) hybrid nanostructures for separation of dyes and antibiotics from aqueous media.

In this study, MoS/NiFeO/MIL-101(Fe) nanocomposite was synthesized by hydrothermal method and used as an adsorbent for the elimination of organic dyes and some antibiotic drugs in aqueous solutions. The synthesized nanocomposite underwent characterization through different techniques, including scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDX), Brunauer-Emmett-Teller (BET) surface area analysis, Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), zeta potential analysis, vibrating sample magnetometry (VSM), and UV-vis diffuse reflectance spectroscopy (UV-vis DRS). These results demonstrated the successful insertion of MoSwithin the cavities of MIL-101(Fe).

Ag NPs decorated on the magnetic rod-like hydroxyapatite/MIL-101(Fe) nanocomposite as an efficient catalyst for the reduction of some nitroaromatic compounds and as an effective antimicrobial agent.

A rod-like magnetic nanocomposite was successfully synthesized in this work by loading Ag and FeO nanoparticles onto the surface of the hydroxyapatite/MIL-101(Fe) metal-organic framework. Various techniques were used to investigate the crystalline nature, size, morphology, and magnetic and structural properties of the HAP/MIL-101(Fe)/Ag/FeO nanocomposite, including X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, Raman spectroscopy, field-emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM), vibrating sample magnetometry (VSM), BET surface area measurements, and zeta potential analysis. The results indicate that the nanocomposite sample is composed of Ag and FeO nanoparticles adhered to rod-like hydroxyapatite/MIL-101(Fe).

Synthesis of magnetic graphene-like carbon nitride-cobalt ferrite (g-CN/CoFeO) nanocomposite for sonocatalytic remediation of toxic organic dyes.

A novel magnetic g-CN/CoFeO nanocomposite was successfully synthesized by a simple hydrothermal method and applied as a new graphene-like carbon nitride-based sonocatalyst for sonodegradation of pollutant dyes. The as-prepared samples were characterized by using X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, field-emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM), vibrating sample magnetometry (VSM), X-ray photoelectron spectroscopy (XPS), UV-visible diffuse reflectance spectroscopy (DRS), BET surface area measurements and photoluminescence (PL) spectroscopy. The results indicate that the nanocomposite sample is composed of spherical CoFeO nanoparticles adhered to g-CN naosheets.

Polyoxometalate supported on a magnetic FeO/MIL-88A rod-like nanocomposite as an adsorbent for the removal of ciprofloxacin, tetracycline and cationic organic dyes from aqueous solutions.

In this work, a magnetic HPWO/FeO/MIL-88A (Fe) rod-like nanocomposite as a stable and effective ternary adsorbent was fabricated by the hydrothermal method and utilized for the removal of ciprofloxacin (CIP), tetracycline (TC) and organic dyes from aqueous solution. Characterization of the magnetic nanocomposite was accomplished by FT-IR, XRD, Raman spectroscopy, SEM, EDX, TEM, VSM, BET specific surface area and zeta potential analyses. The influencing factors on the adsorption potency of the HPWO/FeO/MIL-88A (Fe) rod-like nanocomposite including initial dye concentration, temperature and adsorbent dose were studied.

Adsorptive removal of tetracycline and ciprofloxacin drugs from water by using a magnetic rod-like hydroxyapatite and MIL-101(Fe) metal-organic framework nanocomposite.

A novel porous nanocomposite composed of hydroxyapatite nanorods (HAP), a MIL-101(Fe) metal-organic framework, and FeO nanoparticles was successfully fabricated in this work. The magnetic HAP/MIL-101(Fe)/FeO ternary nanocomposite was identified by various techniques, namely FT-IR spectroscopy, XRD, Raman spectroscopy, SEM, EDX, TEM, BET specific surface area, zeta potential, and VSM measurements. Tetracycline (TC) and ciprofloxacin (CIP) aqueous solutions were used to evaluate the adsorption performance of the resulting HAP/MIL-101(Fe)/FeO composite.

Preparation and characterization of novel polyoxometalate/CoFeO/metal-organic framework magnetic core-shell nanocomposites for the rapid removal of organic dyes from water.

In this study, the MIL-101(Cr) metal-organic framework was functionalized with a Dowson-type polyoxometalate (PWO ; POM) and magnetic spinel cobalt ferrite (CoFeO; CFO) through a hydrothermal route and was characterized by means of FT-IR, XRD, FE-SEM, EDX, BET, and VSM measurements. All analyses confirmed the successful encapsulation of POM (∼32.2 wt%) into the magnetic MIL-101(Cr) framework.

A novel CoFeO@Cr-MIL-101/Y zeolite ternary nanocomposite as a magnetically separable sonocatalyst for efficient sonodegradation of organic dye contaminants from water.

In this research, a novel magnetic sonocatalyst nanocomposite, CoFeO@Cr-MIL-101/Y zeolite, has been successfully fabricated employing a simple hydrothermal method. The as-prepared catalyst was thoroughly identified using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), energy dispersive X-ray spectroscopy (EDS), EDS elemental dot-mapping, transmission electron microscopy (TEM), atomic force microscopy (AFM), vibrating sample magnetometer (VSM), and nitrogen Brunauer-Emmett-Teller (N-BET) analyses. The procured CoFeO@Cr-MIL-101/Y nanocomposite was then assessed for the decomposition of three types of organic dyes namely methylene blue (MB), rhodamine B (RhB) and methyl orange (MO) from water solution using ultrasound irradiation and subsequently monitored UV-Vis absorption technique.

A novel n-type CdS nanorods/p-type LaFeO heterojunction nanocomposite with enhanced visible-light photocatalytic performance.

In this work, a novel n-type CdS nanorods/p-type LaFeO (CdS NRs/LFO) nanocomposite was prepared, for the first time, a facile solvothermal method. The as-prepared n-CdS NRs/p-LFO nanocomposite was characterized by using powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HR-TEM), energy-dispersive X-ray spectroscopy (EDX), UV-visible diffuse reflection spectroscopy (DRS), vibrating sample magnetometry (VSM), photoluminescence (PL) spectroscopy, and Brunauer-Emmett-Teller (BET) surface area analysis. All data revealed the attachment of the LFO nanoparticle on the surface of CdS NRs.

A magnetically separable plate-like cadmium titanate-copper ferrite nanocomposite with enhanced visible-light photocatalytic degradation performance for organic contaminants.

A novel magnetic cadmium titanate-copper ferrite (CdTiO/CuFeO) nanocomposite, in which spherical CuFeO nanoparticles were loaded onto the surface of CdTiO nanoplates, was successfully synthesized a sol-gel hydrothermal route at 180 °C. The structure, morphology, magnetic and optical properties of the as-prepared nanocomposite were respectively characterized by Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), energy dispersive X-ray (EDX) spectroscopy, transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET) surface area analysis, UV-visible diffuse reflectance spectroscopy (DRS), vibrating sample magnetometry (VSM) and photoluminescence (PL) spectroscopy. The photocatalytic activity of this novel CdTiO-based magnetic nanocomposite was investigated for the degradation of organic dye pollutants such as methylene blue (MB), rhodamine B (RhB), and methyl orange (MO) in the presence of HO under visible light irradiation.

Fullerene-modified magnetic silver phosphate (AgPO/FeO/C) nanocomposites: hydrothermal synthesis, characterization and study of photocatalytic, catalytic and antibacterial activities.

In this work, fullerene-modified magnetic silver phosphate (AgPO/FeO/C) nanocomposites with efficient visible light photocatalytic and catalytic activity were fabricated by a simple hydrothermal approach. The composition and structure of the obtained new magnetically recyclable ternary nanocomposites were completely characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy, Brunauer-Emmett-Teller (BET) specific surface area analysis, vibrating sample magnetometery (VSM), diffuse reflectance spectroscopy (DRS), field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray (EDX) spectroscopy and transmission electron microscopy (TEM). This novel magnetically recyclable heterogeneous fullerene-modified catalyst was tested for the HO-assisted photocatalytic degradation of MB dye under visible light.

12-Molybdophosphoric acid anchored on aminopropylsilanized magnetic graphene oxide nanosheets (FeO/GrOSi(CH)-NH/HPMoO): a novel magnetically recoverable solid catalyst for HO-mediated oxidation of benzylic alcohols under solvent-free conditions.

In this work, 12-molybdophosphoric acid (HPMoO, HPMo) was chemically anchored onto the surface of aminosilanized magnetic graphene oxide (FeO/GrOSi(CH)-NH) and was characterized using different physicochemical techniques, such as powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy, energy-dispersive X-ray analysis (EDX), scanning electron microscopy (SEM), BET specific surface area analysis and magnetic measurements. The results demonstrated the successful loading of HPMo (∼31.5 wt%) on the surface of magnetic aminosilanized graphene oxide.