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Article Synopsis
  • The primary perfluoroalcohols CF OH, C F OH, and nC F OH were synthesized using carbonyl compounds in anhydrous HF solution.
  • Experimental reaction enthalpies and entropies were calculated from the temperature-based equilibria of certain reactions monitored through NMR spectroscopy.
  • Computational chemistry methods indicated that these perfluoroalcohols are strong acids, and their protonation in HF/SbF formed perfluoroalkyl oxonium salts.
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