One-dimensional Branched PdAg Nanoalloy Rich in Defects for Boosting Glycerol and Ethanol Oxidation.

The development of Pd-based bimetallic nanoalloys (NAs) with abundant active sites for achieving highly efficient electrocatalysis in alcohol oxidation deserves continuous attention. Herein, we utilized a facile visible-light-assisted liquid-phase method involving adjusting reaction time to generate active sites, successfully synthesizing one-dimensional (1D) PdAg NAs rich in defects. The optimized 1D PdAg NA exhibits remarkable electrochemical activity, stability, and antipoisonous properties in glycerol oxidation reaction (GOR) and ethanol oxidation reaction (EOR), far exceeding pure Pd and commercial Pd/C catalysts.

Radar-Terahertz-Infrared Compatible Stealth Coaxial Silver Nanowire@Carbon Nano-cable Aerogel.

Achieving multi-spectrum compatible stealth in radar-terahertz-infrared bands with robust performance has great prospects for both military and civilian applications. However, the progress of materials encounters substantial challenges due to the significant variability in frequency coupling properties across different electromagnetic wave bands. Here, this work presents the design of a multi-scale structure and fabricates a lightweight aerogel (silver nanowire@carbon, AgNW@C) consisting of a regular coaxial nano-cable, with silver nanowire as the core and amorphous-graphitized hybrid carbon as the outer-layer.

Exploring the interaction between calf thymus DNA and 11H-Indeno[1,2-b]quinoxalin-11-one Thiosemicarbazones: Spectroscopies and in vitro antitumor activity.

Understanding the interactions between small molecules and calf thymus deoxyribonucleic acid (ctDNA) is critical for certain aspects of drug discovery. In this study, three 11H-indeno[1,2-b]quinoxalin-11-one thiosemicarbazones were synthesized and their interaction with ctDNA was examined through various spectroscopic techniques, including ultraviolet (UV) spectroscopy, fluorescence spectroscopy, and circular dichroism (CD) spectrum, and through physicochemical methods, including viscosity measurements. In addition, the effects of these thiosemicarbazone compounds 4a, 4b and 4c on several cancer cell lines were explored.

Moral disengagement as mediator and guilt as moderator between cyber moral literacy and cyberbullying among late adolescents.

The rapid growth of internet usage has led to increased cyberbullying among adolescents, with varying rates reported across countries. This study aimed to investigate the impact of cyber moral literacy on cyberbullying among late adolescents, examining both the mediating role of moral disengagement and the moderating effect of guilt on the relationship between cyber moral literacy and cyberbullying. Data were collected from 7837 late adolescent students (aged 18-21 years) at four universities in Sichuan Province, China.

Chitinases are important virulence factors in Vibrio for degrading the chitin-rich barrier of shrimp.

Vibrio-induced diseases pose a significant threat to shrimp aquaculture. While the mechanisms underlying Vibrio penetration of shrimp shells and the gastrointestinal tract remain unclear, this study implicates chitinases as critical virulence factors. Despite their inability to utilize chitin or shrimp shells as sole carbon and nitrogen sources, three major shrimp pathogens-V.

Application of Polyvinyl Alcohol-Ethylene Glycol Hydrogel Technology for Removing Animal Glue in Book Restoration Based on Fluorescent Labeling Evaluation.

This study developed a novel material based on polyvinyl alcohol-ethylene glycol (PVA-EG) hydrogel and systematically evaluated its potential application in the removal of animal glue from book surfaces. The microstructure, surface properties, and mechanical characteristics of the PVA-EG hydrogel were analyzed using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), contact angle measurements, a universal testing machine, and a dynamic mechanical analysis (DMA). The introduction of ethylene glycol (EG) could weaken hydrogen bonding interactions between PVA chains to enhance the molecular chain flexibility of the hydrogel.

Chlorella-Based Biohybrid Microrobot for Removing Both Nutrient and Microalgae toward Efficient Water Eutrophication Treatment.

Excessive nutrients and explosive growth of harmful microalgae in water environments are key challenges in the treatment of eutrophication. The development of a low-cost, time-saving, and small-space-suitable research method that can simultaneously remove nutrients and microalgae is highly anticipated. This work first proposed applying microrobots to eutrophication treatment.

Electrically driven phosphorus dissolution from iron-nickel phosphate surfaces exposing highly active sites for oxygen evolution reaction.

The enhancement of catalytic activity can be achieved by removing non-active components from the surface of catalyst materials, thereby increasing the accessibility of active sites. In this study, an electrically driven method is described for the removal of non-active phosphorus (P) to optimize the surface composition of iron-nickel phosphide (denoted as P-O-NFF), resulting in the exposure of more active Fe-Ni sites for oxygen evolution reaction (OER). The optimized P-O-NFF electrode exhibits exceptional OER catalytic activity, with an overpotential of 217 mV at 10 mA cm.

Oil-type modulation of the interfacial adsorption behavior of flavonoid-modified walnut protein hydrolysates to improve the storage stability of high internal phase Pickering emulsions.

Background: Currently, protein-polyphenol complexes have garnered increasing attention as surface-active substances in high internal phase Pickering emulsions (HIPPEs). However, the effects of the oil type and flavonoid structure on the HIPPE-stabilizing ability of protein-polyphenol complexes remain unclear. Notably, very few studies have investigated the impacts and mechanisms of different oils (olive, flaxseed, and coconut oils) and the effects of the addition of flavonoids (catechin and quercetin) on the interfacial behavior of walnut protein hydrolysates (WPHs) and the co-oxidation of protein-lipid in the resulting emulsion during storage.

Selection and verification of reference genes for real-time quantitative PCR in endangered mangrove species Acanthus ebracteatus under different abiotic stress conditions.

Acanthus ebracteatus is an endangered true mangrove species with great ecological and medicinal values. Real-time quantitative PCR (RT-qPCR) has been widely used to investigate transcriptional responses in A. ebracteatus, which can facilitate its protection and medicinal usage.

Comprehensive analysis of hub mRNA, lncRNA and miRNA, and associated ceRNA networks implicated in cobia (Rachycentron canadum) scales under hypoosmotic adaption.

Salinity plays a vital role in fish aquaculture, profoundly influencing the growth and development of fish. Scales, as the protective outer layer of fish, function as a critical defense against external factors. In this study, we employed transcriptome sequencing to analyze the ceRNA expression profiles to reveal the effect of salinity acclimation on transcriptional expression changes in the scales of cobia (Rachycentron canadum).

Comparative Plastome Analysis Between Endangered Mangrove Species and Relatives Provides Insights into Its Origin and Adaptive Evolution.

is a typical true mangrove species with great ecological and medicinal values. However, it has become endangered in China. Moreover, because of the similar morphology and distribution, it is commonly confused with the congeneric mangrove species, , which poses challenges to the protection and proper medicinal utilization of .

Glycosparvine A, a new indole alkaloid from the leaves of .

In the course of our ongoing search for biologically active compounds from medicinal plant, the ethyl acetate extract from the leaves of (Rutaceae) was investigated. Six compounds including a new indole alkaloid, glycosparvine A (), and five previously known metabolites (-) were identified. The structure of the new compound () was unambiguously elucidated by spectroscopic analyses, including 1D/2D NMR spectroscopy and HRESIMS.

Effect of Proteins on the Vulcanized Natural Rubber Crosslinking Network Structure and Mechanical Properties.

Proteins are important factors affecting the properties of natural rubber. Therefore, investigating the effect of free and bonded proteins on the structure and mechanical properties of the vulcanized crosslinking network of natural rubber would provide a theoretical basis for the production of high mechanical resistance natural rubber. Herein, natural rubbers with different protein contents and types were prepared by high-speed centrifugation.

Primary Amine-Functionalized Chiral Covalent Organic Framework Enables High-Efficiency Asymmetric Catalysis in Water.

Aqueous asymmetric catalysis using chiral covalent organic frameworks (COFs) represents a significant advancement but remains to be explored. Herein, we present the first example of aqueous asymmetric catalysis catalyzed by a primary amine-tagged chiral -ADP-TAPB COF. The -ADP-TAPB COF was synthesized by the postsynthetic deprotection of -ADP-TAPB-Boc bearing a protective tert-butoxycarbonyl (Boc) group, which was constructed by a Schiff-base reaction between an alanine-derived chiral building block (-ADP-Boc) and 1,3,5-tris(4-aminophenyl)benzene (TAPB).

Mangrove fungi in action: Novel bioremediation strategy for high-chloride wastewater.

Bioremediation of extremely high-chloride wastewater poses significant challenges due to the adverse effects of elevated salt concentrations on most microorganisms, where chloride levels can be as high as 7% (w/v). Mangrove wetlands derived fungus, Aspergillus aculeatus, emerged as a promising candidate, capable of removing approximately 40% of chloride ions in environments with concentration of 15% (w/v), representative of industrial wastewater conditions. Transcriptomics and biochemical assays conducted under increasing salt conditions revealed that elevated chloride concentrations induce the expression and activity of S-adenosyl methionine-dependent methyltransferase, which facilitates the conversion of chloride into chloromethane.