Preventing cation intermixing enables 50% quantum yield in sub-15 nm short-wave infrared-emitting rare-earth based core-shell nanocrystals.

Short-wave infrared (SWIR) fluorescence could become the new gold standard in optical imaging for biomedical applications due to important advantages such as lack of autofluorescence, weak photon absorption by blood and tissues, and reduced photon scattering coefficient. Therefore, contrary to the visible and NIR regions, tissues become translucent in the SWIR region. Nevertheless, the lack of bright and biocompatible probes is a key challenge that must be overcome to unlock the full potential of SWIR fluorescence.

Broadband Photon Harvesting in Organic Photovoltaic Devices Induced by Large-Area Nanogrooved Templates.

Thin-film organic photovoltaic (OPV) devices represent an attractive alternative to conventional silicon solar cells due to their lightweight, flexibility, and low cost. However, the relatively low optical absorption of the OPV active layers still represents an open issue in view of efficient devices that cannot be addressed by adopting conventional light coupling strategies derived from thick PV absorbers. The light coupling to thin-film solar cells can be boosted by nanostructuring the device interfaces at the subwavelength scale.

Absolute quantum yield for understanding upconversion and downshift luminescence in PbF:Er,Yb crystals.

The search for new materials capable of efficient upconversion continues to attract attention. In this work, a comprehensive study of the upconversion luminescence in PbF:Er,Yb crystals with different concentrations of Yb ions in the range of 2 to 7.5 mol% (Er concentration was fixed at 2 mol%) was carried out.

Competing dynamics of intramolecular deactivation and bimolecular charge transfer processes in luminescent Fe(iii) N-heterocyclic carbene complexes.

Steady state and ultrafast spectroscopy on [Fe(phtmeimb)]PF (phtmeimb = phenyl(tris(3-methylimidazol-2-ylidene))borate) was performed over a broad range of temperatures. The intramolecular deactivation dynamics of the luminescent doublet ligand-to-metal charge-transfer (LMCT) state was established based on Arrhenius analysis, indicating the direct deactivation of the LMCT state to the doublet ground state as a key limitation to the lifetime. In selected solvent environments photoinduced disproportionation generating short-lived Fe(iv) and Fe(ii) complex pairs that subsequently undergo bimolecular recombination was observed.

Piezoresistive Free-standing Microfiber Strain Sensor for High-resolution Battery Thickness Monitoring.

Highly sensitive microfiber strain sensors are promising for the detection of mechanical deformations in applications where limited space is available. In particular for in situ battery thickness monitoring where high resolution and low detection limit are key requirements. Herein, the realization of a highly sensitive strain sensor for in situ lithium-ion (Li-ion) battery thickness monitoring is presented.

Enhancement of Amplified Spontaneous Emission by Electric Field in CsPbBr Perovskites.

Perovskite gain materials can sustain continuous-wave lasing at room-temperature. A first step toward the unachieved goal of electrically excited lasing would be an improvement in gain when electrical stimulation is added to the optical. However, to date, electrical stimulation supplementing optical has reduced gain performance.

Distributed Feedback Lasers by Thermal Nanoimprint of Perovskites Using Gelatin Gratings.

To date, thermal nanoimprint lithography (NIL) for patterning hybrid perovskites has always involved an intricate etching step of a hard stamp material or its master. Here, we demonstrate for the first time the successful nanopatterning of a perovskite film by NIL with a low-cost polymeric stamp. The stamp consists of a dichromated gelatin grating structured by holographic lithography.

The Impact of Carbon Nanotube Length and Diameter on their Global Alignment by Dead-End Filtration.

Dead-end filtration has proven to effectively prepare macroscopically (3.8 cm ) aligned thin films from solutionbased single-wall carbon nanotubes (SWCNTs). However, to make this technique broadly applicable, the role of SWCNT length and diameter must be understood.

Gas-assisted blade-coating of organic semiconductors: molecular assembly, device fabrication and complex thin-film structuring.

The competitive performance of optoelectronic devices based on advanced organic semiconductors increasingly calls for suitably scalable processing schemes to capitalise on their application potential. With performance benchmarks typically established by spin-coating fabrication, doctor-blade deposition represents a widely available roll-to-roll-compatible means for the preparation of large-area samples and establishing the device upscaling potential. However, the inherently slower film formation kinetics often result in unfavourable active layer microstructures, requiring empirical and material-inefficient optimisation of solutions to reach the performance of spin-coated devices.

Limitation of room temperature phosphorescence efficiency in metal organic frameworks due to triplet-triplet annihilation.

The effect of triplet-triplet annihilation (TTA) on the room-temperature phosphorescence (RTP) in metal-organic frameworks (MOFs) is studied in benchmark RTP MOFs based on Zn metal centers and isophthalic or terephthalic acid linkers (ZnIPA and ZnTPA). The ratio of RTP to singlet fluorescence is observed to decrease with increasing excitation power density. Explicitly, in ZnIPA the ratio of the RTP to fluorescence is 0.

High Figure-of-Merit Telluride-Based Flexible Thermoelectric Films through Interfacial Modification via Millisecond Photonic-Curing for Fully Printed Thermoelectric Generators.

The thermoelectric generator (TEG) shows great promise for energy harvesting and waste heat recovery applications. Cost barriers for this technology could be overcome by using printing technologies. However, the development of thermoelectric (TE) materials that combine printability, high-efficiency, and mechanical flexibility is a serious challenge.

Inkjet-Printed Dual-Mode Electrochromic and Electroluminescent Displays Incorporating Ecofriendly Materials.

Displays and indicators are an integral component of everyday electronics. However, the short lifecycle of most applications is currently contributing to the unsustainable growth of electronic waste. In this work, we utilize ecofriendly materials in combination with sustainable processing techniques to fabricate inkjet-printed, ecofriendly dual-mode displays (DMDs).

Printed temperature sensor array for high-resolution thermal mapping.

Fully-printed temperature sensor arrays-based on a flexible substrate and featuring a high spatial-temperature resolution-are immensely advantageous across a host of disciplines. These range from healthcare, quality and environmental monitoring to emerging technologies, such as artificial skins in soft robotics. Other noteworthy applications extend to the fields of power electronics and microelectronics, particularly thermal management for multi-core processor chips.

Monolithic Two-Terminal Perovskite/CIS Tandem Solar Cells with Efficiency Approaching 25.

Monolithic two-terminal (2T) perovskite/CuInSe (CIS) tandem solar cells (TSCs) combine the promise of an efficient tandem photovoltaic (PV) technology with the simplicity of an all-thin-film device architecture that is compatible with flexible and lightweight PV. In this work, we present the first-ever 2T perovskite/CIS TSC with a power conversion efficiency (PCE) approaching 25% (23.5% certified, area 0.

Cluster-Glass for Low-Cost White-Light Emission.

The development of efficient and high-brilliance white-light sources is an essential contribution to innovative emission technologies. Materials exhibiting strong nonlinear optical properties, in particular second-harmonic generation (SHG) or white-light generation (WLG), have therefore been investigated with great activity in recent times. While many new approaches have been reported until now, the processability of the compounds remains a challenge.

Fabrication of Bragg Mirrors by Multilayer Inkjet Printing.

Bragg mirrors are widely applied in optical and photonic devices due to their capability of light management. However, the fabrication of Bragg mirrors is mainly accomplished by physical and chemical vapor deposition processes, which are costly and do not allow for lateral patterning. Here, the fabrication of Bragg mirrors by fully inkjet printing is reported.

Photonic Curing Enables Ultrarapid Processing of Highly Conducting β-CuSe Printed Thermoelectric Films in Less Than 10 ms.

It has been a challenge to obtain high electrical conductivity in inorganic printed thermoelectric (TE) films due to their high interfacial resistance. In this work, we report a facile synthesis process of Cu-Se-based printable ink for screen printing. A highly conducting TE β-CuSe phase forms in the screen-printed Cu-Se-based film through ≤10 ms sintering using photonic-curing technology, minimizing the interfacial resistance.

Eco-friendly fabrication of organic solar cells: electrostatic stabilization of surfactant-free organic nanoparticle dispersions by illumination.

Earlier reports have discussed the manifold opportunities that arise from the use of eco-friendly organic semiconductor dispersions as inks for printed electronics and, in particular, organic photovoltaics. To date, poly(3-hexylthiophene) (P3HT) plays an outstanding role since it has been the only organic semiconductor that formed nanoparticle dispersions with sufficient stability and concentration without the use of surfactants. This work elucidates the underlying mechanisms that lead to the formation of intrinsically stable P3HT dispersions and reveals prevailing electrostatic effects to rule the nanoparticle growth.

Two-Photon Vision in Age-Related Macular Degeneration: A Translational Study.

The recently introduced term “two-photon vision” relates to the visual perception resulting from a simultaneous absorption of two photons by photoreceptors. In this study, we determined two-photon retinal sensitivity in age-related macular degeneration (AMD) and compared it that in normal aging. Microperimetry was performed with visible (white) light and infrared (IR) light, which was perceived as green in the two-photon stimulation.

Drying and Coating of Perovskite Thin Films: How to Control the Thin Film Morphology in Scalable Dynamic Coating Systems.

Hybrid perovskite photovoltaics combine high performance with the ease of solution processing. However, to date, a poor understanding of morphology formation in coated perovskite precursor thin films casts doubt on the feasibility of scaling-up laboratory-scale solution processes. Oblique slot jet drying is a widely used scalable method to induce fast crystallization in perovskite thin films, but deep knowledge and explicit guidance on how to control this dynamic method are missing.

Dual-color dynamic anti-counterfeiting labels with persistent emission after visible excitation allowing smartphone authentication.

A significant impediment to the deployment of anti-counterfeiting technologies is the reliance on specialized hardware. Here, anti-counterfeiting labels are developed that are both excited and detected using a smartphone. The persistent luminescence pattern and color changes on the timescale of hundreds of milliseconds to seconds.

BODIPY-pyrene donor-acceptor sensitizers for triplet-triplet annihilation upconversion: the impact of the BODIPY-core on upconversion efficiency.

Triplet-triplet annihilation upconversion (TTA-UC) is an important type of optical process with applications in biophotonics, solar energy harvesting and photochemistry. In most of the TTA-UC systems, the formation of triplet excited states takes place spin-orbital interactions promoted by heavy atoms. Given the crucial role of heavy atoms (especially noble metals, such as Pd and Pt) in promoting intersystem crossing (ISC) and, therefore, in production of UC luminescence, the feasibility of using more readily available and inexpensive sensitizers without heavy atoms remains a challenge.

Cubic hexagonal - phase, size and morphology effects on the photoluminescence quantum yield of NaGdF:Er/Yb upconverting nanoparticles.

Upconverting nanoparticles (UCNPs) are well-known for their capacity to convert near-infrared light into UV/visible light, benefitting various applications where light triggering is required. At the nanoscale, loss of luminescence intensity is observed and thus, a decrease in photoluminescence quantum yield (PLQY), usually ascribed to surface quenching. We evaluate this by measuring the PLQY of NaGdF:Er,Yb UCNPs as a function of size ( 15 to 100 nm) and shape (spheres, cubes, hexagons).

Emergence of Deep Traps in Long-Term Thermally Stressed CHNHPbI Perovskite Revealed by Thermally Stimulated Currents.

Defect states are known to trigger trap-assisted nonradiative recombination, restricting the performance of perovskite solar cells (PSCs). Here, we investigate the trap states in long-term thermally stressed methylammonium lead iodide (MAPbI) perovskite thin films over 500 h at 85 °C employing thermally stimulated current measurements. A prominent deep trap level was detected with an activation energy of ∼0.

Electrical performance of efficient quad-crescent-shaped Si nanowire solar cell.

The electrical characteristics of quad-crescent-shaped silicon nanowire (NW) solar cells (SCs) are numerically analyzed and as a result their performance optimized. The structure discussed consists of four crescents, forming a cavity that permits multiple light scattering with high trapping between the NWs. Additionally, new modes strongly coupled to the incident light are generated along the NWs.