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A simple, efficient, and convenient activation of perfluoroalkyl iodides by BuONa or KOH, without expensive photo- or transition metal catalysts, allows the promotion of versatile α-sp C-H amidation reactions of alkyl ethers and benzylic hydrocarbons, C-H iodination of heteroaryl compounds, and perfluoroalkylations of electron-rich π bonds. Mechanistic studies show that these novel protocols are based on the halogen bond interaction between perfluoroalkyl iodides and BuONa or KOH, which promote homolysis of perfluoroalkyl iodides under mild conditions.
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