Molecular Order Induced Charge Transfer in a C-Topological Insulator Moiré Heterostructure.

We synthesized and spectroscopically investigated monolayer (ML) C on the topological insulator (TI) BiTe. This C/BiTe heterostructure is characterized by an excellent translational order in a novel (4 × 4) C superstructure on a (9 × 9) cell of BiTe. Angle-resolved photoemission spectroscopy (ARPES) of C/BiTe reveals that ML C accepts electrons from the TI at room temperature, but no charge transfer occurs at low temperatures.

Post-Degradation Recovery of CsPbI Quantum Dot Solar Cells.

The stability of perovskite quantum dot solar cells is one of the key challenges of this technology. This study reveals the unique degradation behavior of cesium lead triiodide (CsPbI) quantum dot solar cells. For the first time, it is shown that the oxygen-induced degradation and performance loss of CsPbI quantum dot photovoltaic devices can be reversed by exposing the degraded samples to humidity, allowing the performance to recover and even surpass the initial performance.

Aero-TiO three-dimensional nanoarchitecture for photocatalytic degradation of tetracycline.

One of the biggest issues of wide bandgap semiconductor use in photocatalytic wastewater treatment is the reusability of the material and avoiding the contamination of water with the material itself. In this paper, we report on a novel TiO aeromaterial (aero-TiO) consisting of hollow microtetrapods with ZnTiO inclusions. Atomic layer deposition has been used to obtain particles of unique shape allowing them to interlock thereby protecting the photocatalyst from erosion and damage when incorporated in active filters.

Kinetics of Volatile and Nonvolatile Halide Perovskite Devices: The Conductance-Activated Quasi-Linear Memristor (CALM) Model.

Memristors stand out as promising components in the landscape of memory and computing. Memristors are generally defined by a conductance mechanism containing a state variable that imparts a memory effect. The current-voltage cycling causes transitions of conductance, which are determined by different physical mechanisms, such as the formation of conducting filaments in an insulating surrounding.

Skeletal Nitrogen Functionalization of Isostructural 2D Conjugated MOFs for Enhancement of the Dual-Ion Storage Capacity.

Two-dimensional conjugated metal-organic frameworks (2D c-MOFs) are emerging as promising electrode materials for electrochemical energy storage devices. However, a viable path to realize superior dual-ion storage in 2D c-MOFs has remained elusive. Here, we report the synthesis of Cu(N-OHPTP) 2D c-MOFs (x=0,1,2; OHPTP=octahydroxyphenanthrotriphenylene) with precise aromatic carbon-nitrogen arrangements, based on the π-conjugated OHPTP ligand incorporated with one or two nitrogen atoms.

Noncollinear Magnetic Structures in the Chiral Antiperovskite β-FeSeO.

We present the magnetic properties of the chiral, polar, and possibly magnetoelectric antiperovskite β-FeSeO as derived from magnetization and specific-heat measurements as well as from powder neutron diffraction and Mössbauer experiments. Our macroscopic data unambiguously reveal two magnetic phase transitions at ≈ 103 K and ≈ 78 K, while Rietveld analysis of neutron powder diffraction data reveals a noncollinear antiferromagnetic structure featuring magnetic moments in the - plane of the trigonal structure and a ferromagnetic moment along . The latter is allowed by symmetry between and , weakly visible in the magnetization data yet unresolvable microscopically.

Physical-Mechanical Properties and Mineral Deposition of a Pit-and-Fissure Sealant Containing Niobium-Fluoride Nanoparticles-An In Vitro Study.

This study investigated the combined effects of adding niobium-fluoride (NbF) nanoparticles to a pit-and-fissure sealant. One resin sealant was reinforced with varying amounts of nanoparticles (0.3, 0.

Observation of Circular Dichroism Induced by Electronic Chirality.

Chiral phases of matter, characterized by a definite handedness, abound in nature, ranging from the crystal structure of quartz to spiraling spin states in helical magnets. In 1T-TiSe_{2} a source of chirality has been proposed that stands apart from these classical examples as it arises from combined electronic charge and quantum orbital fluctuations. This may allow its chirality to be accessed and manipulated without imposing either structural or magnetic handedness.

Room Temperature Synthesis of Tellurium by Solution Atomic Layer Deposition.

This study demonstrates the deposition of tellurium (Te) on silicon/silicon nitride substrates using solution atomic layer deposition (sALD) at ambient temperature. The process employs tellurium tetrachloride (TeCl) and bis(triethylsilyl)-telluride ((TES)Te) as precursors, with toluene as the solvent. Growth parameters were optimized through systematic variation of the pulse and purge times.

Comparison of Levitation Properties between Bulk High-Temperature Superconductor Blocks and High-Temperature Superconductor Tape Stacks Prepared from Commercial Coated Conductors.

Bulk high-temperature superconductors (HTSs) such as BaCuO (BCO, = Y, Gd) are commonly used in rotationally symmetric superconducting magnetic bearings. However, such bulks have several disadvantages such as brittleness, limited availability and high costs due to the time-consuming and energy-intensive fabrication process. Alternatively, tape stacks of HTS-coated conductors might be used for these devices promising an improved bearing efficiency due to a simplification of manufacturing processes for the required shapes, higher mechanical strength, improved thermal performance, higher availability and therefore potentially reduced costs.

Oxidative stress-modifying effects of TiOnanoparticles with varying content of Ti(Ti) ions.

Nanoparticles (NPs) with reactive oxygen species (ROS)-regulating ability have recently attracted great attention as promising agents for nanomedicine. In the present study, we have analyzed the effects of TiOdefect structure related to the presence of stoichiometric (Ti) and non-stoichiometric (Tiand Ti) titanium ions in the crystal lattice and TiONPs aggregation ability on HO- and tert-butyl hydroperoxide (tBOOH)-induced ROS production in L929 cells. Synthesized TiO-A, TiO-B, and TiO-C NPs with varying Ti(Ti) content were characterized by x-ray powder diffraction, transmission electron microscopy, small-angle x-ray scattering, x-ray photoelectron spectroscopy, and optical spectroscopy methods.

Thirty Years of Hide-and-Seek: Capturing Abundant but Elusive M@(8)-C Isomer, and the Study of Magnetic Anisotropy Induced in Dy Ion by the Fullerene π-Ligand.

Our knowledge about endohedral metallofullerenes (EMFs) is restricted to the structures with sufficient kinetic stability to be extracted from the arc-discharge soot and processed by chromatographic and structural techniques. For the most abundant rare-earth monometallofullerene M@C, experimental studies repeatedly demonstrated (9) and (6) carbon cage isomers, while computations predicted equal stability of the "missing" (8) isomer. Here we report that this isomer is indeed formed but has not been recovered from soot using standard protocols.

Synthesis and properties of SrLaNiWO, a new S = 1 triangular lattice magnet.

Magnetic materials featuring triangular arrangements of spins are frequently investigated as platforms hosting magnetic frustration. Hexagonal perovskites with ordered vacancies serve as excellent candidates for two-dimensional triangular magnetism due to the considerable separation of the magnetic planes. In this work, the effects of chemical pressure on the ferromagnetic ground state of BaLaNiWO by substitution of Ba with Sr to produce SrLaNiWO are investigated.

Hydroflux Synthesis and Structural Phase Transition of Rare-Earth Borate Hydroxides Na[RE(BO)(OH)] (RE=Y, Gd-Er).

Reacting REO and HBO in an ultra-alkaline NaOH hydroflux at about 250 °C yielded pure, crystalline samples of Na[RE(BO)(OH)] (RE=Y, Gd-Er). The compounds dehydrate to NaRE(BO) upon heating in air to about 500 °C. Na[RE(BO)(OH)] (RE=Tb-Er) are photoluminescent under UV radiation.

Stabilization Strategies of Lithium Metal Anode Toward Dendrite-Free Lithium-Sulfur Batteries.

Lithium-sulfur (Li-S) batteries are considered as a most promising rechargeable lithium metal batteries because of their high energy density and low cost. However, the Li-S batteries mainly suffer the capacity decay issue caused by the shutting effect of lithium polysulfides and the safety issues arising from the Li dendrites formation. This review outlines the current issues of Li-S batteries.

Synaptic Response of Fluidic Nanopores: The Connection of Potentiation with Hysteresis.

Iontronic fluidic ionic/electronic components are emerging as promising elements for artificial brain-like computation systems. Nanopore ionic rectifiers can be operated as a synapse element, exhibiting conductance modulation in response to a train of voltage impulses, thus producing programmable resistive states. We propose a model that replicates hysteresis, rectification, and time domain response properties, based on conductance modulation between two conducting modes and a relaxation time of the state variable.

Spin-Orbit-Lattice Entangled State in A_{2}MgReO_{6} (A=Ca, Sr, Ba) Revealed by Resonant Inelastic X-Ray Scattering.

The 5d^{1} ordered double perovskites present an exotic playground for studying novel multipolar physics due to large spin-orbit coupling. We present Re L_{3} edge resonant inelastic x-ray scattering (RIXS) results that reveal the presence of the dynamic Jahn-Teller effect in the A_{2}MgReO_{6} (A=Ca, Sr, Ba) family of 5d^{1} double perovskites. The spin-orbit excitations in these materials show a strongly asymmetric line shape and exhibit substantial temperature dependence, indicating that they are dressed with lattice vibrations.

Exploring the heteroanionic 2D materials RhSeCl and RhTeCl as promising semiconductor materials.

Heteroanionic materials show promising potential as 2D semiconductors due to their tunable band gaps, making them excellent candidates for photocatalytic water splitting applications. We conducted detailed theoretical and experimental analysis of two selected materials by synthesizing crystals through chemical vapor transport and investigating the impact of anion variation on crystal structure and properties. Using powder X-ray diffraction and convergent beam electron diffraction, we elucidated the non-centrosymmetric space groups of these compounds.

Narrow Bandgap 1D Lead Iodide Perovskite with Aminophenyl Viologen.

One-dimensional (1D) perovskites (perovskitoids) occupy an important place among modern semiconducting materials, offering design flexibility together with a wide range of properties. However, most such materials have a large bandgap, which limits their application in photovoltaics. Here, we present a new 1D hybrid perovskite containing the functional cation aminophenyl viologen (APhV).

Facile and Scalable Colloidal Synthesis of Transition Metal Dichalcogenide Nanoparticles with High-Performance Hydrogen Production.

Transition metal dichalcogenides (TMDs) have garnered significant attention as efficient electrocatalysts for the hydrogen evolution reaction (HER) due to their high activity, stability, and cost-effectiveness. However, the development of a convenient and economical approach for large-scale HER applications remains a persistent challenge. In this study, we present the successful synthesis of TMD nanoparticles (including MoS, RuS, ReS, MoSe, RuSe, and ReSe) using a general colloidal method at room temperature.

From Chalcogen Bonding to S-π Interactions in Hybrid Perovskite Photovoltaics.

The stability of hybrid organic-inorganic halide perovskite semiconductors remains a significant obstacle to their application in photovoltaics. To this end, the use of low-dimensional (LD) perovskites, which incorporate hydrophobic organic moieties, provides an effective strategy to improve their stability, yet often at the expense of their performance. To address this limitation, supramolecular engineering of noncovalent interactions between organic and inorganic components has shown potential by relying on hydrogen bonding and conventional van der Waals interactions.