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Synthesis, Crystal Structure, and Optical Characterization of the Sulfide Chloride Oxide CsBaVSClO with a Near-Infrared Fluorescence.
Inorg Chem
November 2019
Leibniz Institute for Materials and Solid State Research IFW e.V., Helmholtzstraße 20 , DE-01069 Dresden , Germany.
When CsCl, BaS, BaO, V, and S are reacted in a solid-state reaction under inert conditions, pure powders and single crystals of senary CsBaVSClO can be obtained. Its unique crystal structure has the symmetry 3̅ (no. 148) and unit cell parameters = 9.
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