Dehydrocoupling of Ammonia/Amine Boranes and Related Transformations Catalysed by Group 4 Metal Complexes.

Ammonia borane and amine boranes are main group analogues of alkanes, which are characterised by their large gravimetric hydrogen content. This hydrogen can be released in dehydrocoupling and dehydropolymerisation reactions to obtain B-N oligomers and polymers that are of importance as precursors for functional B-N materials. Furthermore, amine boranes are potent reagents for application in transfer hydrogenation reactions, representing a versatile, easy-to-handle alternative to the use of gaseous hydrogen for the reduction of organic compounds.

Cobalt Catalysts for [2+2+2] Cycloaddition Reactions: Isolated Precatalysts and in situ Generated Catalysts.

[2+2+2] Cycloaddition reactions belong to the not even large class of reactions, which can be catalyzed or mediated by a significant number of different transition metals. Cobalt complexes belong to the catalysts that paved the way for the extensive use and profound mechanistic knowledge on this particular transformation. Beside the established role, cyclopentadienyl (Cp) cobalt complexes inherit in synthetic applications of the cyclotrimerization reaction, modification of the precatalysts opened up novel reactivities and versatility for such catalytic initiators.