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Enantioselective total syntheses of six natural and two proposed meroterpenoids from .
Chem Sci
May 2023
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University Lanzhou 730000 China
The first enantioselective total syntheses of six natural and two proposed meroterpenoids isolated from have been achieved in 7-9 steps from 2-methylcyclohexanone. The current synthetic approaches feature a high level of synthetic flexibility, stereodivergent fashion and short synthetic route, thereby providing a potential platform for the preparation of numerous this-type meroterpenoids and their -natural products.
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