Synthesis and the growth mechanism of ultrafine silver nanowires by using 5-chloro-2-thienylmagnesium bromide as the additive.

Synthesis of silver nanowires (Ag NWs) has been studied for decades. However, Ag NWs with diameters below 20 nm synthesised by simple and robust approaches are still rarely reported. In this work, Ag NWs with an average diameter of ∼15 nm and an aspect ratio of over 1000 have been prepared by using a Grignard reagent 5-chloro-2-thienylmagnesium bromide as an assistant additive.

Morphology-controlled silver nanowire synthesis using a cocamidopropyl betaine-based polyol process for flexible and stretchable electronics.

Silver nanowire (AgNW) based transparent conductive films (TCFs) are promising building blocks for flexible and stretchable electronics to replace brittle metal oxides. Ultra-long AgNWs are preferred for enabling TCFs with excellent photoelectric properties and mechanical flexibility. Herein, a novel polyol process is proposed for the synthesis of ultra-long AgNWs, with the new finding that the addition cocamidopropyl betaine (CAB) to polyol synthesis allows the rapid production of AgNWs with an average length of ∼120 μm in a high yield of ∼90%.

A novel synthesis of silver nanowires by using 6-chlorohexylzinc bromide as an additive for low haze transparent conductive films.

High-quality silver nanowires (AgNWs) with a small diameter of ∼20 nm and a length of ∼40 μm were prepared by using a novel organic 6-chlorohexylzinc bromide as an assistant additive. The diameter of as-synthesized AgNWs was confirmed to be strongly dependent on the dosage of 6-chlorohexylzinc bromide. Moreover, a two-dimensional (2D) transparent conductive film (TCF) with an excellent optical performance was fabricated by as-synthesized AgNWs, which has a 90.

One-step synthesis of ultra-long silver nanowires of over 100 μm and their application in flexible transparent conductive films.

Silver nanowires (AgNWs) >100 μm and even 160 μm in length have been synthesized using a facile and rationally designed solvothermal method by heating preservation at 150 °C. The length of the as-synthesized AgNWs is over 4-5 times longer than those previously reported, while the diameter range is from 40 nm to 85 nm. A transparent conducting film (TCF) was fabricated using hydroxyethyl cellulose (HEC) as the adhesive polymer, and it achieved exceptional and stable optoelectronic properties.