Laser-Induced Silver Nanowires/Polymer Composites for Flexible Electronics and Electromagnetic Compatibility Application.

Nowadays, the Internet of Things (IOT), electronics, and neural interfaces are becoming an integral part of our life. These technologies place unprecedentedly high demands on materials in terms of their mechanical and electrical properties. There are several strategies for forming conductive layers in such composites, e.

Synthesis, X-ray Crystallography, Spectroscopic Characterizations, Density Functional Theory, and Hirshfeld Surface Analyses of a Novel (Carbonato) Picket Fence Iron(III) Complex.

An Fe(III)-carbonato six-coordinate picket fence porphyrin complex with the formula [K(2,2,2-crypt)][Fe(TpivPP)(CO)]·CHCl·3HO () has been synthesized and characterized by UV-Vis and FT-IR spectra. The structure of (carbonato)(α,α,α,α-tetrakis(-pivalamidophenyl)porphinato)ferrate(III) was also established by XRD. The iron atom is hexa-coordinated by the four nitrogen atoms of the pyrrol rings and the two oxygen atoms of the CO group.

[Characteristics of lipid peroxidation processes and factors of the antioxidant defense system in chronic rhinitis].

Unlabelled: The problem of chronic rhinitis (CR) remains unresolved in the world, while it has a negative impact on the quality of life of patients. Chronic forms of rhinitis suffer from 10-20% of the population, and its symptoms in epidemiological studies are noted in 40% of respondents. One of the leading mechanisms of disease occurrence is oxidative stress.

[Theories of the pathogenesis of polypous rhinosinusitis and the asthmatic triad].

Unlabelled: Polypous rhinosinusitis (PRS) is a chronic inflammatory disease of the mucous membrane of the nasal cavity and paranasal sinuses, characterized by the formation and recurrent growth of polyps. Often, PRS is a manifestation of the most severe clinical symptom complex - the asthmatic triad (AT). AT is characterized by three main clinical manifestations: bronchial asthma (BA) itself, PRS, intolerance to acetylsalicylic acid, other nonsteroidal anti-inflammatory drugs (NSAIDs) and NA.

Monitoring and Prediction of Siberian Silk Moth Tschetv. (Lepidoptera: Lasiocampidae) Outbreaks Using Remote Sensing Techniques.

The feasibility of risk assessment of a Siberian silk moth ( Tschetv.) outbreak was analyzed by means of landscape and weather characteristics and tree condition parameters. Difficulties in detecting forest pest outbreaks (especially in Siberian conditions) are associated with the inability to conduct regular ground surveillance in taiga territories, which generally occupy more than 2 million km.

Hybrid Tamm and quasi-BIC microcavity modes.

The microcavity in the form of a liquid crystal defect layer embedded in a one-dimensional photonic crystal is considered. The microcavity mode has a tunable radiation decay rate in the vicinity of a bound state in the continuum. It is demonstrated that coupling between the microcavity mode and a Tamm plasmon polariton results in hybrid Tamm-microcavity modes with a tunable factor.

Novel somatic Missense Mutations in Exon 11 of the KIT Gene are Detected in Melanoma.

Objective: The aim of the present study was to analyze mutations of the mast/stem cell growth factor receptor Kit (KIT) gene in patients with melanoma from Eastern Siberia regions of the Russian Federation.

Methods: KIT gene mutations in exons 11 and 13 were analyzed by Sanger sequencing in 57 tumor samples obtained from patients with KIT-positive melanomas localized in preferable locations.

Result: Mutations were identified in 21% of patients.

Fractionation of Aspen Wood to Produce Microcrystalline, Microfibrillated and Nanofibrillated Celluloses, Xylan and Ethanollignin.

A new method for extractive-catalytic fractionation of aspen wood to produce microcrystalline (MCC), microfibrillated (MFC), nanofibrilllated (NFC) celluloses, xylan, and ethanollignin is suggested in order to utilize all of the main components of wood biomass. Xylan is obtained with a yield of 10.2 wt.

Synthesis, characterization and identification of inhibitory activity on the main protease of COVID-19 by molecular docking strategy of (4-oxo-piperidinium ethylene acetal) trioxonitrate.

In this investigation a single crystal of (-xo-iperidinium thylene cetal) trioxoitrate () was synthesized by modifying the mechanism of gradual evaporation at ambient temperature. The operational groupings are found in the complex material in the elaborate substance, according to the infrared spectrum. Single crystal X-ray diffraction suggests, (4OPEAN) with the chemical formula (CHNO)NO belongs to the orthorhombic space group nma and is centrosymmetric in three dimensions with the aforementioned network configurations, a = 11.

Fatty Acid Profiles of Some Siberian Bryophytes and Prospects of Their Use in Chemotaxonomy.

The composition of fatty acids (FAs) in gametophyte samples of 20 Siberian bryophyte species from four orders of mosses and four orders of liverworts collected in relatively cold months (April and/or October) was examined. FA profiles were obtained using gas chromatography. Thirty-seven FAs were found, from 12:0 to 26:0; they included mono-, polyunsaturated (PUFAs) and rare FAs, such as 22:5n-3 and two acetylenic FAs, 6a,9,12-18:3 and 6a,9,12,15-18:4 (dicranin).

[Pharmacoepidemiological analysis of antihypertensive therapy in older age groups with senile asthenia syndrome].

Aim: To conduct a pharmacoepidemiological study to determine the characteristics of antihypertensive therapy in older patients with senile asthenia syndrome (SSA) and compliance of this therapy with modern clinical recommendations.

Materials And Methods: The study included 146 patients diagnosed with stage I-III hypertension who underwent inpatient treatment in the therapeutic department of the Krasnoyarsk Regional Hospital for War Veterans, the subjects were divided into two groups. The first group included 55 elderly patients (WHO, 2012) with hypertension and SSA.

Molecular Structure, Electronic Properties, Reactivity (ELF, LOL, and Fukui), and NCI-RDG Studies of the Binary Mixture of Water and Essential Oil of .

Essential oils are volatile oil-like liquids with a characteristic strong smell and taste. They are formed in plants and are then extracted. Essential oils have extremely strong physiological and pharmacological properties, which are used in the medicine, cosmetics, and food industries.

Molecular Structure, Spectral Analysis, Molecular Docking and Physicochemical Studies of 3-Bromo-2-hydroxypyridine Monomer and Dimer as Bromodomain Inhibitors.

In this paper, both methods (DFT and HF) were used in a theoretical investigation of 3-bromo-2-Hydroxypyridine (3-Br-2HyP) molecules where the molecular structures of the title compound have been optimized. Molecular electrostatic potential (MEP) was computed using the B3LYP/6-311++G(d,p) level of theory. The time-dependent density functional theory (TD-DFT) approach was used to simulate the HOMO (highest occupied molecular orbital) and LUMO (lowest unoccupied molecular orbital) on the one hand to achieve the frontier orbital gap and on the other hand to calculate the UV-visible spectrum of the compound in gas phase and for different solvents.

Spadefoot Pelobates vespertinus (Amphibia, Pelobatidae) as a transmitter of fatty acids from water to land in a forest-steppe floodplain.

The transfer of biomass and polyunsaturated fatty acids by the spadefoot P. vespertinus (previously subspecies of P. fuscus) from aquatic to terrestrial ecosystems was studied for five years in small floodplain water bodies of a forest-steppe zone.

Sulfation of Birch Wood Microcrystalline Cellulose with Sulfamic Acid Using Ion-Exchange Resins as Catalysts.

Cellulose sulfates are important biologically active substances with a wide range of useful properties. The development of new methods for the production of cellulose sulfates is an urgent task. In this work, we investigated ion-exchange resins as catalysts for the sulfation of cellulose with sulfamic acid.

Synthesis, Empirical and Theoretical Investigations on New Histaminium Bis(Trioxonitrate) Compound.

In this paper, a novel hybrid material, entitled histaminium bis(trioxonitrate), with the general chemical formula (CHN)(NO), denoted by HTN was presented. Single-crystal X-ray diffraction was used to determine the structural characteristics of this compound after it was made using a slow evaporation method at room temperature. This compound was elaborated and crystallized to the monoclinic system with space group 2/c, and the lattice parameters obtained were: a = 10.

Structure and Vibrational Spectroscopy of C Fullerenol Valent Isomers: An Experimental and Theoretical Joint Study.

Gd@COH endohedral complexes for advanced biomedical applications (computer tomography, cancer treatment, etc.) were synthesized using high-frequency arc plasma discharge through a mixture of graphite and GdO oxide. The Gd@C endohedral complex was isolated by high-efficiency liquid chromatography and consequently oxidized with the formation of a family of Gd endohedral fullerenols with gross formula Gd@CO(OH).

Polymer Membrane Modified with Photocatalytic and Plasmonic Nanoparticles for Self-Cleaning Filters.

In this study, we developed a filtering material for facial masks, which is capable of trapping and subsequent inactivation of bacteria under white light emitting diodes (LED) or sunlight irradiation. Such a functionality is achieved via the modification of the composite membrane based on porous polymer with photocatalytic (TiO) and plasmonic (Ag) nanoparticles. The porous polymer is produced by means of a computer numerical control machine, which rolls a photoresist/thermoplastic mixture into a ~20-µm-thick membrane followed by its thermal/ultraviolet (UV) hardening and porosification.

Comprehensive Study of the Ammonium Sulfamate-Urea Binary System.

The physicochemical properties of binary systems are of great importance for the application of the latter. We report on the investigation of an ammonium sulfamate-urea binary system with different component ratios using a combination of experimental (FTIR, XRD, TGA/DSC, and melting point) and theoretical (DFT, QTAIM, ELF, RDG, ADMP, etc.) techniques.

[Food allergy as a risk factor for acne].

Acne is a multifactorial disease in which genetic, hormonal, environmental and nutritional factors are involved. Data on the role of food and other etiological forms of allergy in the development of acne, as well as the nature of the sensitization spectrum, are extremely scarce, which makes the study relevant. of the study was to analyze the features of the spectrum of sensitization to food, pollen, fungal allergens in patients with acne and establish the role of food allergy in the development of the pathology.

Sublayer-Enhanced Growth of Highly Ordered MnGe Thin Film on Si(111).

MnGe epitaxial thin films previously grown mainly on Ge substrate have been synthesized on Si(111) using the co-deposition of Mn and Ge at a temperature of 390 °C. RMS roughness decreases by almost a factor of two in the transition from a completely polycrystalline to a highly ordered growth mode. This mode has been stabilized by changing the ratio of the Mn and Ge evaporation rate from the stoichiometric in the buffer layer.

Synthesis of Co-Ni Alloy Particles with the Structure of a Solid Substitution Solution by Precipitation in a Supercritical Carbon Dioxide.

Mixed Co-Ni bimetallic systems with the structure of a solid substitution solution have been synthesized using the supercritical antisolvent precipitation (SAS) method, which uses supercritical CO as an antisolvent. The systems obtained have been characterized in detail using X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), Fourier-transform infrared (FTIR) spectroscopy, and magnetostatic measurements. It has been found that Co-enriched systems have a defective hexagonal close-packed (hcp) structure, which was described by a model which embedded cubic fragments of packaging into a hexagonal close-packed (hcp) structure.

Aptamers Regulating the Hemostasis System.

The hemostasis system is a complex structure that includes the fibrinolysis system, and Yes this is correct coagulation and anticoagulation parts. Due to the multicomponent nature, it becomes relevant to study the key changes in the functioning of signaling pathways, and develop new diagnostic methods and modern drugs with high selectivity. One of the ways to solve this problem is the development of molecular recognition elements capable of blocking one of the hemostasis systems and/or activating another.

A Comprehensive Study of N-Butyl-1H-Benzimidazole.

Imidazole derivatives have found wide application in organic and medicinal chemistry. In particular, benzimidazoles have proven biological activity as antiviral, antimicrobial, and antitumor agents. In this work, we experimentally and theoretically investigated N-Butyl-1H-benzimidazole.