Effect of catalyst and oxidant concentrations in a TEMPO oxidation system on the production of cellulose nanofibers.

In traditional TEMPO oxidation systems, the high cost of TEMPO catalysts has been a significant barrier to the industrialization of oxidized CNF. From an economic perspective, presenting the characteristics of various CNFs produced with the oxidation systems with reduced catalyst usage could facilitate the industrial application of CNF across a wide range of fields. In this study, it was demonstrated that reducing the amount of TEMPO catalyst used (from 0.

A comprehensive review on sustainable surfactants from CNSL: chemistry, key applications and research perspectives.

Surfactants, a group of amphiphilic molecules ( with hydrophobic(water insoluble) as well as hydrophilic(water soluble) properties) can modulate interfacial tension. Currently, the majority of surfactants depend on petrochemical feedstocks (such as oil and gas). However, deployment of these petrochemical surfactants produces high toxicity and also has poor biodegradability which can cause more environmental issues.

Electrochemical preparation system for unique mesoporous hemisphere gold nanoparticles using block copolymer micelles.

Gold nanoparticles (AuNPs) are widely used in various applications, such as biological delivery, catalysis, and others. In this report, we present a novel synthetic method to prepare mesoporous hemisphere gold nanoparticles (MHAuNPs) electrochemical reduction reaction with the aid of polymeric micelle assembly as a pore-directing agent.

Catalytic reactivity of an iridium complex with a proton responsive N-donor ligand in CO hydrogenation to formate.

Catalytic hydrogenation of CO into formic acid/formate is an attractive conversion in the utilization of CO. Although various catalysts with high catalytic efficiency are reported, a very few studies have been carried out to correlate/understand the efficacy and stability of the hydrogenation catalysts, which could be helpful to direct the future design strategy of corresponding catalysts. Herein, a half-sandwich iridium complex containing bibenzimidazole as a proton responsive N-donor ligand, [Cp*Ir(BiBzImH)Cl]Cl, has been synthesized and fully characterized.