Highly porous, soft, and flexible vapor-phase polymerized polypyrrole-styrene-ethylene-butylene-styrene hybrid scaffold as ammonia and strain sensor.

Herein, vapor-phase polymerization (VPP) of pyrrole on an oxidant-impregnated styrene-ethylene-butylene-styrene (SEBS) matrix comprising a three-dimensional sugar particle assembly was used to produce a soft and porous polypyrrole (PPy)-SEBS hybrid scaffold. Characterization of the PPy-SEBS hybrid scaffold using field-effect scanning electron microscopy, Fourier-transform infrared spectroscopy, energy-dispersive X-ray spectroscopy, and micro-computerized tomography confirmed the successful uniform and homogenous polymerization of PPy onto the SEBS matrix with a porous morphology. The performance of the hybrid scaffold of different pore sizes as an ammonia sensor under different temperature conditions was evaluated in terms of resistance change.

Immobilization of Ni Complex on Amine-Grafted SiO₂ for Ethylene Polymerization.

The results on the In-Situ synthesis of Ni complex on amine-grafted SiO2 and its ethylene polymerization were explained. SiO2/2NS/(DME)NiBr2 and SiO2/3NS/(DME)NiBr2(Ni(II) bromide ethylene glycol dimethyl ether) catalysts were active for ethylene polymerization. The highest activity was shown at the polymerization temperature of 25 °C, and SiO2/2NS/(DME)NiBr2 exhibited higher activity than SiO2/3NS/(DME)NiBr2.