Synthesis and characterization of mesoporous silica supported metallosalphen-azobenzene complexes: efficient photochromic heterogeneous catalysts for the oxidation of cyclohexane to produce KA oil.

The oxidation of cyclohexane to produce KA oil (cyclohexanone and cyclohexanol) is important industrially but faces challenges such as low cyclohexane conversion at high KA oil selectivity, and difficult catalyst recyclability. This work reports the synthesis and evaluation of new heterogeneous catalysts consisting of Co(ii), Mn(ii), Ni(ii) and Cu(ii) salphen-azobenzene complexes [ML] immobilized on amino-functionalized mesoporous silica (SBA-15, MCM-41, MCM-48) through coordination bonding. In the first step, the salphen-azobenzene ligand was synthesized and complexed with Co, Mn, Ni and Cu metal ions.