Multiscale approach to the theory of nonisothermal homogeneous nucleation.

Molecular dynamics (MD) of the Lennard-Jones cluster in the environment of supersaturated vapor at fixed temperature and density is used for the investigation of nonisothermal nucleation. The results allow one to single out different processes occurring at different time scales, the Ornstein-Uhlenbeck fluctuations at the short time scale and a combination of slow diffusion and drift of the fluctuation packet that represents a cluster, at the long time scale. The multiscale approach is developed, in which a separate treatment of different time scales makes it possible to consider strongly correlated cluster size and temperature.

Motility provides specific adhesion patterns and improves Listeria monocytogenes invasion into human HEp-2 cells.

Listeria monocytogenes is motile at 22°C and non-motile at 37°C. In contrast, expression of L. monocytogenes virulence factors is low at 22°C and up-regulated at 37°C.

Infrared spectroscopic and thermographic evidence for the interaction of ethylene and 1,3-butadiene with NO at cryogenic temperatures.

The possibility of the reaction of ethylene at cryogenic temperatures with dinitrogen tetroxide (NO), at least at -40 °C, has been demonstrated. An infrared (IR) spectroscopic analysis of the condensed reaction products was carried out, which showed the presence of substances containing organic nitro compounds and organic nitrates. The latter particularly means the possibility of the formation of explosive substances, as in the known explosive cryogenic reaction of NO with butadiene.

Can Rare Earth Elements Be Considered as Markers of the Varietal and Geographical Origin of Wines?

The possibility of establishing the varietal and territorial affiliation of wines by the content of rare earth elements (REE) in them was studied. ICP-OES and ICP-MS with subsequent chemometric processing of the results were applied to determine the elemental image of soils containing negligible REE amounts, grapes grown on these soils, and wine materials of Cabernet Sauvignon, Merlot, and Moldova varieties produced from these grapes. To stabilize and clarify wine materials, the traditional processing of wine materials with various types of bentonite clays (BT) was used, which turned out to be a source of REE in the wine material.

Percolation Conduction of Carbon Nanocomposites.

Carbon nanocomposites present a new class of nanomaterials in which conducting carbon nanoparticles are a small additive to a non-conducting matrix. A typical example of such composites is a polymer matrix doped with carbon nanotubes (CNT). Due to a high aspect ratio of CNTs, inserting rather low quantity of nanotubes (on the level of 0.

Thermodynamics and the structure of clusters in the dense Au vapor from molecular dynamics simulation.

Clusters of atoms in dense gold vapor are studied via atomistic simulation with the classical molecular dynamics method. For this purpose, we develop a new embedded atom model potential applicable to the lightest gold clusters and to the bulk gold. Simulation provides the equilibrium vapor phases at several subcritical temperatures, in which the clusters comprising up to 26 atoms are detected and analyzed.

Dust coupling parameter of radio-frequency-discharge complex plasma under microgravity conditions.

Oscillation of particles in a dust crystal formed in a low-pressure radio-frequency gas discharge under microgravity conditions is studied. Analysis of experimental data obtained in our previous study shows that the oscillations are highly isotropic and nearly homogeneous in the bulk of a dust crystal; oscillations of the neighboring particles are significantly correlated. We demonstrate that the standard deviation of the particle radius vector along with the local particle number density fully define the coupling parameter of the particle subsystem.

Density distribution of a dust cloud in three-dimensional complex plasmas.

We propose a method of determination of the dust particle spatial distribution in dust clouds that form in three-dimensional (3D) complex plasmas under microgravity conditions. The method utilizes the data obtained during the 3D scanning of a cloud, and it provides reasonably good accuracy. Based on this method, we investigate the particle density in a dust cloud realized in gas discharge plasma in the PK-3 Plus setup onboard the International Space Station.

Electromagnetic wave band structure due to surface plasmon resonances in a complex plasma.

The dielectric properties of complex plasma containing either metal or dielectric spherical inclusions (macroparticles, dust) are investigated. We focus on surface plasmon resonances on the macroparticle surfaces and their effect on electromagnetic wave propagation. It is demonstrated that the presence of surface plasmon oscillations can significantly modify plasma electromagnetic properties by resonances and cutoffs in the effective permittivity.

Enhancement of the droplet nucleation in a dense supersaturated Lennard-Jones vapor.

The vapor-liquid nucleation in a dense Lennard-Jones system is studied analytically and numerically. A solution of the nucleation kinetic equations, which includes the elementary processes of condensation/evaporation involving the lightest clusters, is obtained, and the nucleation rate is calculated. Based on the equation of state for the cluster vapor, the pre-exponential factor is obtained.

Dust acoustic waves in three-dimensional complex plasmas with a similarity property.

Dust acoustic waves in the bulk of a dust cloud in complex plasma of low-pressure gas discharge under microgravity conditions are considered. The complex plasma is assumed to conform to the ionization equation of state (IEOS) developed in our previous study. This equation implies the ionization similarity of plasmas.

The cluster model of a hot dense vapor.

We explore thermodynamic properties of a vapor in the range of state parameters where the contribution to thermodynamic functions from bound states of atoms (clusters) dominates over the interaction between the components of the vapor in free states. The clusters are assumed to be light and sufficiently "hot" for the number of bonds to be minimized. We use the technique of calculation of the cluster partition function for the cluster with a minimum number of interatomic bonds to calculate the caloric properties (heat capacity and velocity of sound) for an ideal mixture of the lightest clusters.

Molecular dynamics study of nanobubbles in the equilibrium Lennard-Jones fluid.

We employ a model, in which the density fluctuations in a bulk liquid are represented as presence of the clusters of molecules with the lowered number of nearest neighbors (number of bonds). The nanobubble size distribution is calculated on the basis of a close analogy between the surface part of the work of formation for a cluster and for a nanobubble. The pre-exponential factor for this distribution is related to the fluid compressibility.

Onset of cavity deformation upon subsonic motion of a projectile in a fluid complex plasma.

We study the deformation of a cavity around a large projectile moving with subsonic velocity in the cloud of small dust particles. To solve this problem, we employ the Navier-Stokes equation for a compressible fluid with due regard for friction between dust particles and atoms of neutral gas. The solution shows that due to friction, the pressure of a dust cloud at the surface of a cavity around the projectile can become negative, which entails the emergence of a considerable asymmetry of the cavity, i.

Nonviscous motion of a slow particle in a dust crystal under microgravity conditions.

Subsonic motion of a large particle moving through the bulk of a dust crystal formed by negatively charged small particles is investigated using the PK-3 Plus laboratory onboard the International Space Station. Tracing the particle trajectories shows that the large particle moves almost freely through the bulk of the plasma crystal, while dust particles move along characteristic α-shaped pathways near the large particle. In the hydrodynamic approximation, we develop a theory of nonviscous dust particle motion about a large particle and calculate particle trajectories.

Thermal fluctuations of clusters with the long-range interaction.

Analysis of surface fluctuation spectra is performed for a large cluster of particles interacting via a sum of the short-range Lennard-Jones potential and long-range ±1/r potential, where the positive sign corresponds to the gravity, and negative corresponds to the electrostatic interaction. The spectral amplitudes of thermally driven capillary modes in a self-consistent field induced by cluster particles including the modes with no axial symmetry are derived in the approximation of small amplitudes. It is demonstrated that within used approximation, the surface tension is independent of the field strength.

Bactericidal effects of non-thermal argon plasma in vitro, in biofilms and in the animal model of infected wounds.

Non-thermal (low-temperature) physical plasma is under intensive study as an alternative approach to control superficial wound and skin infections when the effectiveness of chemical agents is weak due to natural pathogen or biofilm resistance. The purpose of this study was to test the individual susceptibility of pathogenic bacteria to non-thermal argon plasma and to measure the effectiveness of plasma treatments against bacteria in biofilms and on wound surfaces. Overall, Gram-negative bacteria were more susceptible to plasma treatment than Gram-positive bacteria.

Motion of plasma-dust structures and gas in a magnetic field.

Numerous studies have revealed that the superposition of magnetic field causes plasma-dust structures to rotate in the plane normal to the field. The only explanation for this rotation found in the literature is that the plasma-dust structures are acted upon by the forces of ion entrainment (ion drag forces) from ions moving under the effect of the magnetic field in the azimuthal direction. However, this study demonstrates that the experimentally observed motion of plasma-dust structures cannot be explained by the forces of ion entrainment alone.

Equilibrium fluctuations of the Lennard-Jones cluster surface.

Spectra of the cluster surface equilibrium fluctuations are treated by decomposition into the bulk and net capillary ones. The bulk fluctuations without capillary ones are simulated by the surface of a cluster truncated by a sphere. The bulk fluctuation spectrum is shown to be generated primarily by the discontinuity in the spatial distribution of cluster internal particles.

Superluminal tunneling of microwaves in smoothly varying transmission lines.

Tunneling of microwaves through a smooth barrier in a transmission line is considered. In contrast to standard wave barriers, we study the case where the dielectric permittivity is positive, and the barrier is caused by the inhomogeneous dielectric profile. It is found that reflectionless, superluminal tunneling can take place for waves with a finite spectral width.

Self-consistent electric field inside ordered dust structures.

We report finding a self-consistent electric field of electrons, ions, and dust grains inside an ordered dust cloud in glow discharge, and show that this field differs radically from that of an isolated grain. Besides, the screening radius coincides with the size of Wigner-Seitz cell. The value of potential necessary for containing dust particles in the direction perpendicular to the discharge axis is estimated.