1 results match your criteria: "Jinan University Guangzhou 510632 People's Republic of China cmwang2019@jnu.edu.cn zhoucy2018@jnu.edu.cn.[Affiliation]"
Asymmetric dearomative cyclopropanation of naphthalenes to construct polycyclic compounds.
Chem Sci
November 2022
College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University Guangzhou 510632 People's Republic of China
Catalytic asymmetric dearomatization (CADA) reactions is an important synthetic method for constructing enantioenriched complex cyclic systems from simple aromatic feedstocks. However, the CADA reactions of nonactivated arenes, such as naphthalenes and benzenes, have been far less explored than those of electronically activated arenes, such as phenols, naphthols and indoles. Herein, we disclose an asymmetric dearomative cyclopropanation of naphthalenes for the rapid construction of polycyclic compounds.
View Article and Find Full Text PDF