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Vapor phase -methylation of 4-chlorophenol with methanol was studied over MnO catalyst with two kinds of morphologies. Here, MnO was prepared by a precipitation and hydrothermal method, and showed the morphology of nanoparticles and nanowires, respectively. XRD characterization and BET results showed that, with the increase of calcination temperature, MnO had a higher crystallinity and a smaller specific surface area.

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