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Jiangxi Normal University Nanchang 3300... Publications | LitMetric

1 results match your criteria: "Jiangxi Normal University Nanchang 330022 P. R. China yannan@jxnu.edu.cn.[Affiliation]"

A mild, convenient and transition-metal-free protocol for the synthesis of aryl 1-thioglycosides is presented arynes generated combined with glycosyl thiols in the presence of TBAF(BuOH). The methodology provides a general and efficient way to prepare a series of functionalized thioglycosides in good to excellent yields with a perfect control of the anomeric configuration at room temperature. In addition, the reaction conditions tolerate a variety of the pentoses and hexoses, and the reaction also performs smoothly on protected monosaccharides and disaccharides.

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