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Intensified electrochemiluminescence and photoluminescence supramolecular anion recognition interactions.

Chem Sci

August 2024

Key Laboratory of Optoelectronic Chemical Materials and Devices, Ministry of Education, School of Optoelectronic Materials and Technology, Jianghan University Wuhan Hubei 430056 China

Article Synopsis
  • Researchers demonstrated enhanced electrochemiluminescence (ECL) and photoluminescence (PL) through supramolecular interactions, using a specially designed compound, BIPPD, that interacts with dihydrogen phosphate anion.
  • The study found that interactions with this anion increased ECL quantum efficiency by 5.5 times and PL quantum yield by 1.5 times, indicating strong selective recognition by BIPPD.
  • Mechanistic analyses using techniques like H NMR and ECL/PL spectra showed differences in ECL processes based on anion coordination, enhancing understanding of these chemical interactions for potential applications in supramolecular and analytical chemistry.
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