Correction: Electron counting in cationic and anionic silver clusters doped with a 3d transition-metal atom: endo- exohedral geometry.

Correction for 'Electron counting in cationic and anionic silver clusters doped with a 3d transition-metal atom: endo- exohedral geometry' by Kento Minamikawa , , 2022, DOI: 10.1039/d1cp04197e.

Electron counting in cationic and anionic silver clusters doped with a 3d transition-metal atom: endo- exohedral geometry.

Electron counting is a concept that often governs properties of molecules, clusters, and complexes. Here we explore silver clusters doped with a transition-metal atom, where it has been an issue whether or not 3d electrons delocalize to participate in electron counting. The experiment is performed on AgM (M = Sc-Ni) clusters to examine their stability through chemical reactivity, enabling systematic control of the number of valence electrons by the cluster size, the charge state, and the transition-metal element across the periodic table.

Freezing of micrometer-sized liquid droplets of pure water evaporatively cooled in a vacuum.

Freezing processes are reported for pure-water droplets generated in a vacuum in the size range of 49-71 μm in diameter. The process is characterized for each size by measurement of a freezing curve, where the fraction of frozen droplets is evaluated as a function of time. The 49 μm droplet was found to freeze at a time between 7.