Advancing lithium-ion battery performance with heteroatom-based anode architectures for fast charging and high capacity.

Electric vehicles (EVs) are on the brink of revolutionizing transportation, but the current lithium-ion batteries (LIBs) used in them have significant limitations in terms of fast-charging capabilities and energy density. This feature article begins by examining the key challenges of using graphite for fast charging and silicon for achieving high energy density in LIBs. Firstly, it explores various design strategies employed by researchers worldwide to improve the fast-charging performance of graphite, such as surface coatings, morphological modifications, and binder design.

Nickel Vanadate Cathode Induced In Situ Phase Transition for Improved Zinc Storage by Low Migration Barrier and Zn/H Co-Insertion Mechanism.

Designing cathode materials that exhibit excellent rate performance and extended cycle life is crucial for the commercial viability of aqueous zinc (Zn)-ion batteries (ZIBs). This report presents a hydrothermal synthesis of stable NiVO·1.22HO (NVOH) cathode material, demonstrating high-rate performance and extended cycle life.

Autohomogenization of Polybenzimidazole Composites with Enhanced Mechanical Performance by Air Incorporation.

Polybenzimidazoles are one of the most thermally and chemically stable polymers due to their rigid chemical structure with π-π stacking and conjugated bonding. Poly(2,5-benzimidazole) (ABPBI), the simplest structure of polybenzimidazole, was synthesized, but the cast film was not homogeneous and featured thick brown areas, which limited their further application. Silica nanospheres were adapted as porogen to generate nanopores in the ABPBI film by successive etching with hydrofluoric acid.

Sodium-Poor, Hydroxyl-Rich, Defective NaTiO Prepared by γ-Irradiation and Its Enhanced Proton Conductivity.

The use of γ-irradiation to tailor the physicochemical properties of materials is not widely applied to layered alkali metal oxides. Herein, we show that γ-irradiation (up to 400 kGy) of NaTiO leads to a sodium-poor, hydroxyl-rich analogue where the layered structure, plate-like morphology, and textural properties are preserved. The deintercalation of sodium ions modifies the Ti-O bond lengths and expands the unit cell; the latter is supported by density functional theory (DFT) calculations.

Bio-based poly(benzimidazole--amide)-derived N, O co-doped carbons as fast-charging anodes for lithium-ion batteries.

Lithium-ion batteries (LIBs) that can be charged faster while delivering high capacity are currently in significant demand, especially for electric vehicle applications. In this context, this study introduces a less-explored subject: nitrogen and oxygen dual-doped carbons derived from bio-based copolymers, specifically poly(benzimidazole--amide). The synthesis involved varying proportions of benzimidazole to amide, namely, 8.

Proton Intercalation into an Open-Tunnel Bronze Phase with Near-Zero Volume Change.

Managing safety and supply-chain risks associated with lithium-ion batteries (LIBs) is an urgent task for sustainable development. Aqueous proton batteries are attractive alternatives to LIBs because using water and protons addresses these two risks. However, most host materials undergo large volume changes upon H intercalation, which induces intraparticle cracking to accelerates parasitic reactions.

Spectral and HPLC Analyses of Synthesized Butin and Butein.

Butin and butein are significant bioactive flavanones derived from plants, existing as tautomers of each other. However, their physicochemical attributes, such as their spectral profiles under varying experimental conditions in aqueous solutions and established chromatographic methods for distinguishing between them, remain undetermined. In this study, we determined the basic properties of butin and butein using conventional spectroscopic, reversed-phase, and chiral HPLC analyses.

Contractile and Tensile Measurement of Molecular Artificial Muscles for Biohybrid Robotics.

A printable artificial muscle assembled from biomolecular motors, which we have recently developed, showed great potential in overcoming the design limitations of conventional biohybrid robots as a new bio-actuator. Characterizing its contractility for extending its applicability is important. However, conventional measurement methods are composed of complex operations with poor reproducibility, flexibility, and real-time responsiveness.

Helix-Sense-Selective Permeation of Racemic Helical Oligoacetylenes through One-Handed Helical Channels in Polymer Membranes.

Helix-sense-selective permeation (HSSPerm) of racemic helical oligoacetylenes through one-handed helical channels has been realized. The one-handed helical channels were created in the one-handed helical polyacetylene membranes by the helix-sense-selective decomposition (HSS-SCAT) of the corresponding racemic helical polyacetylene membranes, followed by removing the formed oligomers. Since the HSS-SCAT reaction proceeds with just circularly polarized visible light with no reagents, no catalysts, no solvent, and high selectivity, the chiral channel-containing membrane with high purity was obtained easily.

Incorporation of Aramids into Polybenzimidazoles to Achieve Ultra-High Thermoresistance and Toughening Effects.

Polybenzimidazoles (PBIs) are recognized for their remarkable thermal stability due to their unique molecular structure, which is characterized by aromaticity and rigidity. Despite their remarkable thermal attributes, their tensile properties limit their application. To improve the mechanical performance of PBIs, we made a vital modification to their molecular backbone to improve their structural flexibility.

Synthesis and Direct Observation of Chiral Supramolecular Polymer of Porphyrin Having Cholesteryl Groups.

We report the synthesis and microscopic investigations of two chiral helical porphyrin supramolecular polymers with different coordinating metals that are expected to be capable of serving as synthetic macromolecular motors driven by thermal fluctuations. Furthermore, based on their microscopic images, we propose a stepwise process for the formation of higher-order structures. These porphyrins formed completely different association states, and this was reflected in the marked differences in the shapes of the supramolecular polymers.

Nanoscrolls of Janus Monolayer Transition Metal Dichalcogenides.

Tubular structures of transition metal dichalcogenides (TMDCs) have attracted attention in recent years due to their emergent physical properties, such as the giant bulk photovoltaic effect and chirality-dependent superconductivity. To understand and control these properties, it is highly desirable to develop a sophisticated method to fabricate TMDC tubular structures with smaller diameters and a more uniform crystalline orientation. For this purpose, the rolling up of TMDC monolayers into nanoscrolls is an attractive approach to fabricating such a tubular structure.

Electromagnetic enhancement spectra of one-dimensional plasmonic hotspots along silver nanowire dimer derived via surface-enhanced fluorescence.

We developed a spectroscopic method for directly obtaining the spectra of electromagnetic (EM) enhancement of plasmonic hotspots (HSs). The method was applied to one-dimensional (1D) HSs generated between silver nanowire (NW) dimers. The EM enhancement spectra were derived by dividing the spectra of surface-enhanced fluorescence (SEF) from single NW dimers with SEF obtained from large nanoparticle aggregates, where aggregate-by-aggregate variations in the SEF spectra were averaged out.

Synthesis and Direct Observation of Molecules of 2D Polymers: With High Molecular Weights, Large Areas, Small Micropores, Solubility, Membrane Forming Ability, and High Oxygen Permselectivity.

If ideal 2D polymer (2DP) macromolecules with small pores that are similar in size to gas molecules, large areas, small thickness, and excellent membrane-forming ability are synthesized, ultimate gas separation membranes would be obtained. However, as far it is known, such ideal well-characterized 2DP macromolecules are not isolated. In this study, an ideal 2DP macromolecule is synthesized by using the successive three reactions (Glaser coupling, SCAT reaction, and the introduction of octyl groups), in which the conjugated framework structure is maintained, from a fully conjugated 1D polymer.

Examination of Factors Affecting Site-Directed RNA Editing by the MS2-ADAR1 Deaminase System.

Adenosine deaminases acting on RNA (ADARs) have double-stranded RNA binding domains and a deaminase domain (DD). We used the MS2 system and specific guide RNAs to direct ADAR1-DD to target adenosines in the mRNA encoding-enhanced green fluorescence protein. Using this system in transfected HEK-293 cells, we evaluated the effects of changing the length and position of the guide RNA on the efficiency of conversion of amber (TAG) and ochre (TAA) stop codons to tryptophan (TGG) in the target.

Demonstration of electromagnetic enhancement correlated to optical absorption of single plasmonic system coupled with molecular excitons using ultrafast surface-enhanced fluorescence.

The relationship between the electromagnetic (EM) enhancement of the optical responses of molecules and plasmon resonance has been investigated using Rayleigh scattering or the extinction spectra of plasmonic systems coupled with molecular excitons. However, quantum optics predicts that the EM enhancement of such optical responses, e.g.

Correlated Polarization Dependences between Surface-Enhanced Resonant Raman Scattering and Plasmon Resonance Elastic Scattering Showing Spectral Uncorrelation to Each Other.

We investigated the origin of the identical polarization angle dependence between surface-enhanced resonant Raman scattering (SERRS) and plasmon resonance elastic scattering (PRES) for two types of single silver nanoparticle aggregates. The first type (Type I), in which the SERRS spectral envelopes are similar to the PRES spectra, shows the identical polarization dependence between the SERRS and PRES. The second type (Type II), in which the SERRS envelopes largely deviate from the PRES spectra, also exhibits identical polarization dependence.

Toward Chemical Accuracy Using the Jastrow Correlated Antisymmetrized Geminal Power .

Herein, we report accurate atomization energy calculations for 55 molecules in the Gaussian-2 (G2) set using lattice regularized diffusion Monte Carlo (LRDMC). We compare the Jastrow-Slater determinant with a more flexible JsAGPs (Jastrow correlated antisymmetrized geminal power with singlet correlation) . AGPs is built from pairing functions, which explicitly include pairwise correlations among electrons, and hence, this is expected to be more efficient in recovering the correlation energy.

Topological Data Analysis for Revealing the Structural Origin of Density Anomalies in Silica Glass.

Topological data analysis (TDA) is a newly emerging and powerful tool for understanding the medium-range structure ordering of multiscale data. This study investigates the density anomalies observed during the cooling of liquid silica from a topological point of view using TDA. The density of liquid silica does not monotonically increase during cooling; it instead shows a maximum and minimum.

Toward a New Era of SERS and TERS at the Nanometer Scale: From Fundamentals to Innovative Applications.

Surface-enhanced Raman scattering (SERS) and tip-enhanced Raman scattering (TERS) have opened a variety of exciting research fields. However, although a vast number of applications have been proposed since the two techniques were first reported, none has been applied to real practical use. This calls for an update in the recent fundamental and application studies of SERS and TERS.

Mutation-driven evolution of antibacterial function in an ancestral antifungal scaffold: Significance for peptide engineering.

Mutation-driven evolution of novel function on an old gene has been documented in many development- and adaptive immunity-related genes but is poorly understood in immune effector molecules. Drosomycin-type antifungal peptides (DTAFPs) are a family of defensin-type effectors found in plants and ecdysozoans. Their primitive function was to control fungal infection and then co-opted for fighting against bacterial infection in plants, insects, and nematodes.

Social Networking Services as a Tool for Support of Mothers: A Literature Review.

Background: Difficulties experienced by mothers in raising their children can be resolved using social networking services (SNSs). Being aware of issues associated with SNSs in such situations may be useful for supporting mothers. We herein review the issues associated with using SNSs to support mothers.

Microbial pyrazine diamine is a novel electrolyte additive that shields high-voltage LiNiCoMnO cathodes.

The uncontrolled oxidative decomposition of electrolyte while operating at high potential (> 4.2 V vs Li/Li) severely affects the performance of high-energy density transition metal oxide-based materials as cathodes in Li-ion batteries. To restrict this degradative response of electrolyte species, the need for functional molecules as electrolyte additives that can restrict the electrolytic decomposition is imminent.

Potential use of gold-silver core-shell nanoparticles derived from peel for anticancer compound, protocatechuic acid delivery.

Colorectal cancer is one of the most killing cancers and this has become a global problem. Current treatment and anticancer drugs cannot specifically target the cancerous cells, thus causing toxicity towards surrounding non-cancer cells. Hence, there is an urgent need to discover a more target-specific therapeutic agent to overcome this problem.