Rubizhne Institute - A Birthplace of Photochromic Molecules.

We introduce the community to the remarkable fact that two significant discoveries in the field of organic photoswitches are associated to the Rubizhne (Rubezhnoe) branch of the Research Institute of Organic Intermediates and Dyes during the last century. The institute in Rubizhne was a place where researchers of various nationalities carried out studies of organic dyes for printing and textiles. These efforts resulted in the discoveries of photoswitchable hemithioindigos by M.

Black and white truffles as a source of neuroactive biogenic amines.

This study reports the first data about content of serotonin, histamine, and dopamine in black and white truffles fruiting body based on UHPLC-ESI-QqQ-MS/MS. Here we have demonstrated that black () and white () truffles are a source of biogenic amines. Also, we demonstrated the absence of correlation between the quality of truffles and the content of biogenic amines.

Advancing forest carbon stocks' mapping using a hierarchical approach with machine learning and satellite imagery.

Remote sensing of forests is a powerful tool for monitoring the biodiversity of ecosystems, maintaining general planning, and accounting for resources. Various sensors bring together heterogeneous data, and advanced machine learning methods enable their automatic handling in wide territories. Key forest properties usually under consideration in environmental studies include dominant species, tree age, height, basal area and timber stock.

Photoreactions of Semi-Stiff-Diarylethenes Based on the Cyclohexenol Motif.

Nonsymmetric diarylethenes with an additional "stiff" cyclohexenol ring undergo various types of tandem transformations launched by light-induced 6π-photocyclization. Among these, there are two novel reactions (formal [1,3]-H migration and complete aromatization to an anthracene derivative) as well as photorearrangement and formal methane elimination. This diverse reactivity demonstrates the great potential of --diarylethenes in synthetic photochemistry.

Triadic interaction in the background of a pairwise spin-glass.

Developing an equilibrium solution for a pairwise spin-glass with a quenched random infinite range shows a continuous phase transition. Models with p-spin interactions have been studied and the exact solution was provided that shows a continuous phase transition for p=2 and a first-order one for p>2. Although the p-spin interactions were studied individually without considering lower-order interactions, is it always feasible to ignore the lower ones? Here, we are interested in finding an analytical solution for considering a triadic interaction as a perturbation in the background of a pairwise interaction in the Sherrington-Kirkpatrick spin-glass model.

Reliability Study of Metal-Oxide Semiconductors in Integrated Circuits.

This paper is devoted to the study of CMOS IC parameter degradation during reliability testing. The paper presents a review of literature data on the issue of the reliability of semiconductor devices and integrated circuits and the types of failures leading to the degradation of IC parameters. It describes the tests carried out on the reliability of controlled parameters of integrated circuit TPS54332, such as quiescent current, quiescent current in standby mode, resistance of the open key, and instability of the set output voltage in the whole range of input voltages and in the whole range of load currents.

On the nature of sub-THz continuum absorption in CO gas, its mixture with Ar, and in pure water vapor.

Detailed analysis of the unique broadband millimeter-wave (70-360 GHz) collision-induced absorption spectra in pure CO and in its mixture with Ar is presented. The nature of the observed continuum absorption is examined using classical trajectory simulation along with statistical physics consideration. Bimolecular continuum is decomposed in the phase space into separate contributions from the so-called free, quasibound, and true bound molecular pairs, the proportions of which greatly vary with temperature.

Activation of Anthraquinone's Electrophilicity by Light for a Dynamic C-O Bond.

Coupling of photoswitching with dynamic covalent chemistry enables control of the formation and cleavage of covalent bonds by light irradiation. -Aryloxyanthraquinones feature an exclusive ability to switch electrophilicity by interconversion between - and -quinone isomers, which was used for the first time for the implementation of a dynamic C-O bond. Photogenerated -isomers undergo a concerted -Michael addition of phenols to give hitherto unknown 4-hydroxy-10,10-diaryloxyanthracen-9-ones.

Revisiting Peri-Aryloxyquinones: From a Forgotten Photochromic System to a Promising Tool for Emerging Applications.

Emerging applications of photochromic compounds demand new molecular designs that can be inspired by some long-known yet currently forgotten classes of photoswitches. In the present review, we remind the community about Peri-AryloxyQuinones (PAQs) and their unique photoswitching behavior originally discovered more than 50 years ago. At the heart of this phenomenon is the light-induced migration of an aromatic moiety (arylotropy) in peri-aryloxy-substituted quinones resulting in ana-quinones.

A structural approach to detecting opinion leaders in Twitter by random matrix theory.

This paper presents a novel approach leveraging Random Matrix Theory (RMT) to identify influential users and uncover the underlying dynamics within social media discourse networks. Focusing on the retweet network associated with the 2021 Iranian presidential election, our study reveals intriguing findings. RMT analysis unveils that power dynamics within both poles of the network do not conform to a "one-to-many" pattern, highlighting a select group of users wielding significant influence within their clusters and across the entire network.

Simulating accurate and effective solutions of some nonlinear nonlocal two-point BVPs: Clique and QLM-clique matrix methods.

This research work deals with two spectral matrix collocation algorithms based on (novel) clique functions to solve two classes of nonlinear nonlocal elliptic two-points boundary value problems (BVPs) arising in diverse physical models. The nonlinearity together with nonlocality makes the models so difficult to solve numerically. In both matrix methods by expanding the unknown solutions in terms of clique polynomials the nonlocality in the models is handled.

Seamless Multilayer─A Novel Total Energy Partition Scheme for Embedded and Hybrid Calculations.

In this paper, we provide general formulation of a multilayer approach, covering both additive and subtractive quantum mechanics/molecular mechanics (QM/MM) as special cases. After that, we suggest a novel definition of QM/MM total energy based on the consideration of a system divided into three layers. In a simplified form, it is , where layers 1, 2, and 3 represent inner QM, outer QM, and classical MM regions, respectively.

Tobacco smoking model containing snuffing class.

In recent years, the world has faced many destructive diseases that have taken many lives across the globe. To resist these diseases, humankind needs medicine to control, cure, and predict the behaviour of such problems. Recently, the Corona virus, which primarily affects the lungs, has threatened the globe.

2,3-Diarylmaleate salts as a versatile class of diarylethenes with a full spectrum of photoactivity in water.

There is incessant interest in the transfer of common chemical processes from organic solvents to water, which is vital for the development of bioinspired and green chemical technologies. Diarylethenes feature a rich photochemistry, including both irreversible and reversible reactions that are in demand in organic synthesis, materials chemistry, and photopharmacology. Herein, we introduce the first versatile class of diarylethenes, namely, potassium 2,3-diarylmaleates (DAMs), that show excellent solubility in water.

Response of the competitive balance model to the external field.

The competitive balance model was proposed as an extension of the structural balance theory, aiming to account for heterogeneities observed in real-world networks. In this model, different paradigms lead to form different friendship and enmity. As an example, friendship or enmity between countries can have a political or religious basis.

Quantum Bohmian-Inspired Potential to Model Non-Gaussian Time Series and Its Application in Financial Markets.

We have implemented quantum modeling mainly based on Bohmian mechanics to study time series that contain strong coupling between their events. Compared to time series with normal densities, such time series are associated with rare events. Hence, employing Gaussian statistics drastically underestimates the occurrence of their rare events.

Deep Learning in Precision Agriculture: Artificially Generated VNIR Images Segmentation for Early Postharvest Decay Prediction in Apples.

Food quality control is an important task in the agricultural domain at the postharvest stage for avoiding food losses. The latest achievements in image processing with deep learning (DL) and computer vision (CV) approaches provide a number of effective tools based on the image colorization and image-to-image translation for plant quality control at the postharvest stage. In this article, we propose the approach based on Generative Adversarial Network (GAN) and Convolutional Neural Network (CNN) techniques to use synthesized and segmented VNIR imaging data for early postharvest decay and fungal zone predictions as well as the quality assessment of stored apples.

Light-Induced Dyotropic Rearrangement of Diarylethenes: Scope, Mechanism, and Prospects.

Irreversible two-photon photorearrangement of 1,2-diarylethenes is a unique process providing access to complex 2a ,5a-dihydro-5,6-dithiaacenaphthylene (DDA) heterocyclic core. This reaction was serendipitously discovered during studies on photoswitchable diarylethenes and was initially considered as a highly undesired process. However, in recent years, it has been recognized as an efficient photochemical reaction, interesting by itself and as a promising synthetic method for the synthesis of challenging molecules.

Production of Workpieces from Martensitic Stainless Steel Using Electron-Beam Surfacing and Investigation of Cutting Forces When Milling Workpieces.

The aim of this study was to investigate cutting force when milling 40 × 13 stainless steel samples obtained via electron-beam surfacing. The samples were obtained by surfacing the wire made from the martensitic 40 × 13 stainless steel. The microstructure of the samples and the hardness are discussed in the present study.

Effect of Sodium Lauryl Sulfate on Sorption of Cells of the Electrogenic Bacterium Strain on Carbon Cloth.

Results of a study into the effect of anionic surfactant sodium lauryl sulfate on the sorption of cells of the electrogenic bacteria strain 1-I on the surface of carbon cloth used as electrodes in microbial fuel cell (MFC) technology are presented. Investigations using spectrophotometry, microscopy and microbiology revealed an increase in the degree of sorption of microbial cells on carbon cloth under the action of sodium lauryl sulfate at concentrations of 10 and 100 mg/l. The sorption of cells did not significantly differ from the control at a surfactant content of 200, 400 and 800 mg/l.

Provision of Rational Parameters for the Turning Mode of Small-Sized Parts Made of the 29 NK Alloy and Beryllium Bronze for Subsequent Thermal Pulse Deburring.

The increase in the share of physical and technical processing methods in the arsenal of deburring technologies used in modern production is associated both with the use of difficult-to-machine materials, such as beryllium bronze and the 29 NK alloy, and with the need to solve technological problems for the production of small-sized products with hard-to-reach surfaces. The aim of the study is to improve the processes of blade processing of small-sized parts made of beryllium bronze and the 29 NK alloy to provide rational conditions for thermal pulse deburring. Surface samples were experimentally obtained after turning in different modes on a CITIZEN CINCOM K16E-VII automatic lathe equipped with an Applitec micromechanics tool.

Multifunctional fluorescent diarylethene: time-resolved study of photochemistry.

A study of luminescence and photochromic properties of ()-2,3-bis(2,5-dimethylthiophen-3-yl)-5-(4-(pyrrolidin-1-yl)benzylidene)cyclopent-2-en-1-one, which is a diarylethene with a push-pull system between carbonyl and dimethylamino groups, was performed using time-resolved methods. The intramolecular charge transfer (ICT) process as well as 6π-electrocyclization and -/-isomerization contribute to the complex light-induced properties of this molecule. Formation of unexpected short-lived intermediates was detected in the time range from 100 fs to 100 μs.

Magnetic dipole and quadrupole transitions in the ν + ν vibrational band of carbon dioxide.

This paper aims at the theoretical study of the CO magnetic-dipole ν + ν rovibrational absorption band that was recently detected in the Martian atmosphere. Specific characteristics of the magnetic dipole operator are carefully examined. Our evaluation of the magnetic-dipole line intensities is based on the variational calculations and the use of molecular properties is determined through specially performed ab initio quantum chemical calculations.

Performance of magnetic dipole contribution on ferromagnetic non-Newtonian radiative MHD blood flow: An application of biotechnology and medical sciences.

Casson flow ferromagnetic liquid blood flow over stretching region is studied numerically. The domain is influence by radiation and blood flow velocity and thermal slip conditions. Blood acts an impenetrable magneto-dynamic liquid yields governing equations.

Toxicity of Different Types of Surfactants via Cellular and Enzymatic Assay Systems.

Surfactants have a widespread occurrence, not only as household detergents, but also in their application in industry and medicine. There are numerous bioassays for assessing surfactant toxicity, but investigations of their impact on biological systems at the molecular level are still needed. In this paper, luminous marine bacteria and their coupled NAD(P)H:FMN-oxidoreductase + luciferase (Red + Luc) enzyme system was applied to examine the effects of different types of surfactants, including cationic cetyltrimethylammonium bromide (CTAB), non-ionic polyoxyethylene 20 sorbitan monooleate (Tween 80) and anionic sodium lauryl sulfate (SLS), and to assess whether the Red + Luc enzyme system can be used as a more sensitive indicator of toxicity.