Diversity of chemical composition and nutritional value in grain from selected winter wheat cultivars grown in south-western Poland.

Given the low protein coverage by legumes in Poland, alternatives (with high protein content and high nutritional value) are being sought (with high protein content and high nutritional value of protein) that could replace these plants. Cereal cultivation dominates in Poland; hence, the search for high-value plants will also consider this group of plants. The aim of the study was to compare the nutritional value of proteins from two wheat cultivars.

Modulation of Prostanoids Profile and Counter-Regulation of SDF-1α/CXCR4 and VIP/VPAC2 Expression by Sitagliptin in Non-Diabetic Rat Model of Hepatic Ischemia-Reperfusion Injury.

Molecular mechanisms underlying the beneficial effect of sitagliptin repurposed for hepatic ischemia-reperfusion injury (IRI) are poorly understood. We aimed to evaluate the impact of IRI and sitagliptin on the hepatic profile of eicosanoids (LC-MS/MS) and expression/concentration (RTqPCR/ELISA) of GLP-1/GLP-1R, SDF-1α/CXCR4 and VIP/VPAC1, VPAC2, and PAC1 in 36 rats. Animals were divided into four groups and subjected to ischemia (60 min) and reperfusion (24 h) with or without pretreatment with sitagliptin (5 mg/kg) (IR and SIR) or sham-operated with or without sitagliptin pretreatment (controls and sitagliptin).

Optimized isolation method of humin fraction from mineral soil material.

Humic substances, including humin fraction, play a key role in the fate of organic and inorganic xenobiotics contaminating the environment. Humin is an important fraction of humic substances, which has been the least studied to date. This is due to the difficulties connected with its isolation that pose a number of methodological problems.

Impacts of oxalic acid-activated phosphate rock and root-induced changes on Pb bioavailability in the rhizosphere and its distribution in mung bean plant.

Rhizosphere acidification in leguminous plants can release P from the dissolution of phosphate compounds which can reduce Pb bioavailability to them via the formation of insoluble Pb compounds in their rhizosphere. A soil polluted from Pb-acid batteries effluent (SPBE), having total Pb = 639 mg kg, was amended with six different rates (0, 0.5, 1, 2, 4 and 6%) of oxalic acid-activated phosphate rock (OAPR) and their effects on pH, available P and bioavailable Pb concentrations in the rhizosphere and bulk soils of mung bean plant were evaluated.

Soil development and spatial differentiation in a glacial river valley under cold and extremely arid climate of East Pamir Mountains.

Melting glaciers release new ground surfaces, which may be either a source of greenhouse gas emissions or a sink for carbon dioxide. Studies carried out in subpolar and alpine ecosystems confirm the relatively rapid soil development and increase of carbon and nitrogen pools. However, observations from high-mountain glacier forelands in cold and dry climate are very scarce.

Simultaneous LC-MS/MS-Based Quantification of Free 3-Nitro-l-tyrosine, 3-Chloro-l-tyrosine, and 3-Bromo-l-tyrosine in Plasma of Colorectal Cancer Patients during Early Postoperative Period.

Quantification with satisfactory specificity and sensitivity of free 3-Nitro-l-tyrosine (3-NT), 3-Chloro-l-tyrosine (3-CT), and 3-Bromo-l-tyrosine (3-BT) in biological samples as potential inflammation, oxidative stress, and cancer biomarkers is analytically challenging. We aimed at developing a liquid chromatography-tandem mass spectrometry (LC-MS/MS)-based method for their simultaneous analysis without an extract purification step by solid-phase extraction. Validation of the developed method yielded the following limits of detection (LOD) and quantification (LOQ) for 3-NT, 3-BT, and 3-CT: 0.

Arsenic Uptake by Two Tolerant Grass Species: and Growing in Soils Contaminated by Historical Mining.

The study focused on two grass species and abundant in the sites of former As mining and processing in the Sudetes. Arsenic uptake from soils was examined to assess a risk associated with its accumulation in grass shoots and to check its dependence on soil fertilization. The research involved a field study and greenhouse experiment.

The contribution of water extractable forms of plant nutrients to evaluate MSW compost maturity: a case study.

The object of the experiment was to evaluate municipal solid waste (MSW) compost. Composting was carried out in a pile under aerobic conditions. Total content as well as water-extractable forms of macro and microelements were analysed during composting.

Assessment and monitoring of soil and plant contamination with trace elements around Europe's largest copper ore tailings impoundment.

Europe's largest copper ore tailings impoundment has been considered a potential source of risk for human health, thus leading to the elimination of agricultural production in the surrounding area and its subsequent afforestation. The aim of this study was to analyse the level, spatial distribution and temporal changes in soil and edible plant contamination with trace elements around the impoundment, taking into account the local soil properties. The mean concentrations of Zn, Pb and As (31.

Wheat Straw Biochar as a Specific Sorbent of Cobalt in Soil.

There is an urgent need to search for new sorbents of pollutants presently delivered to the environment. Recently biochar has received much attention as a low-cost, highly effective heavy metal adsorbent. Biochar has been identified as an efficient material for cobalt (Co) immobilization from waters; however, little is known about the role of Co immobilization in soil.

Accumulation of Arsenic by Plants Growing in the Sites Strongly Contaminated by Historical Mining in the Sudetes Region of Poland.

The uptake of As by various plants growing in highly enriched sites was examined in order to identify potential As accumulators and to assess the risk associated with As presence in plant shoots. Representative samples of 13 plant species, together with soil samples, were collected from various sites affected by historical As mining: mine and slag dumps, tailings and contaminated soils with As concentrations in a range 72-193,000 mg/kg. Potentially and actually soluble As forms, extracted with 0.

Residues of Persistent Organic Pollutants (POPs) in Agricultural Soils Adjacent to Historical Sources of Their Storage and Distribution-The Case Study of Azerbaijan.

The aim of this study was to identify and examine the levels of organochlorine pesticides (OCPs), polycyclic aromatic hydrocarbons (PAHs), and polychlorinated biphenyls (PCBs) in soil collected from the surroundings of historical pesticide storage facilities on former agricultural aerodromes, warehouses, and pesticide distribution sites located in the most important agricultural regions in Azerbaijan. The conducted research included determination of three groups of POPs (occurring together), in the natural soil environment influenced for many years by abiotic and biotic factors that could have caused their transformations or decomposition. In this study, soil samples were collected in 21 georeferenced points located in the administrative area of Bilasuvar, Saatly, Sabirabad, Salyan and Jalilabad districts of Azerbaijan.

Arsenic accumulation by red fescue (Festuca rubra) growing in mine affected soils - Findings from the field and greenhouse studies.

Soils strongly enriched in arsenic in historical mining sites pose the environmental risk. Phytostabilization is a reasonable method for their remediation. A suitability of red fescue (Festuca rubra L.

Ecotoxicity of pore water in soils developed on historical arsenic mine dumps: The effects of forest litter.

Arsenic release from dump soils in historical mining sites poses the environmental risk. Decomposing forest litter can affect mobilization of As and other toxic elements, change their speciation in pore water and influence the toxicity to biota. This study examined the chemistry and ecotoxicity of pore water acquired from four soils that developed on the dumps in former As mining sites, in the presence and absence of forest litter collected from beech and spruce stands.

Antimony in soils of SW Poland-an overview of potentially enriched sites.

Great concern has been recently focused on antimony in the environment due to the potential risks posed by this metalloid to humans. In Poland, the concentrations of Sb in soils have not been well recognized. The aim of this study was to identify the sites in south-western Poland where soils are considerably enriched in Sb and to make a rough assessment of a related environmental risk.

1,2,3-propanetriol radicals formed during oxidative stress.

The presented results attempt to approximate the proper structure of the radical formed as a result of the oxidation of 1,2,3-propanetriol. To fulfil the aim unstable radical originated in 1,2,3-propanetriol was trapped by PBN. Resulted spin adduct was measured using EPR spectroscopy and the isotropic hyperfine coupling constants a ( N) and a ( H) were obtained by simulation of the EPR spectrum.

The Release of Antimony from Mine Dump Soils in the Presence and Absence of Forest Litter.

This study examined the changes in antimony (Sb) solubility in soils, using organic matter introduced with forest litter, in various moisture conditions. Soils containing 12.8⁻163 mg/kg Sb were taken from the top layers of dumps in former mining sites in the Sudetes, South-West Poland.

Can Carbamates Undergo Radical Oxidation in the Soil Environment? A Case Study on Carbaryl and Carbofuran.

Radical oxidation of carbamate insecticides, namely carbaryl and carbofuran, was investigated with spectroscopic (electron paramagnetic resonance [EPR] and UV-vis) and theoretical (density functional theory [DFT] and ab initio orbital-optimized spin-component scaled MP2 [OO-SCS-MP2]) methods. The two carbamates were subjected to reaction with OH, persistent DPPH and galvinoxyl radical, as well as indigenous radicals of humic acids. The influence of fulvic acids on carbamate oxidation was also tested.

Seasonal dynamics of nitrate and ammonium ion concentrations in soil solutions collected using MacroRhizon suction cups.

The aims of the study were to analyse the concentration of nitrate and ammonium ions in soil solutions obtained using MacroRhizon miniaturized composite suction cups under field conditions and to determine potential nitrogen leaching from soil fertilized with three types of fertilizers (standard urea, slow-release urea, and ammonium nitrate) at the doses of 90 and 180 kg ha, applied once or divided into two rates. During a 3-year growing experiment with sugar sorghum, the concentration of nitrate and ammonium ions in soil solutions was the highest with standard urea fertilization and the lowest in variants fertilized with slow-release urea for most of the months of the growing season. Higher concentrations of both nitrogen forms were noted at the fertilizer dose of 180 kg ha.

Soil pollution indices conditioned by medieval metallurgical activity - A case study from Krakow (Poland).

The studied soil profile under the Main Market Square (MMS) in Krakow was characterised by the influence of medieval metallurgical activity. In the presented soil section lithological discontinuity (LD) was found, which manifests itself in the form of cultural layers (CLs). Moreover, in this paper LD detection methods based on soil texture are presented.

Some adverse effects of soil amendment with organic Materials-The case of soils polluted by copper industry phytostabilized with red fescue.

The study was aimed to examine the effects of soil amendment with organic waste materials on the growth of red fescue and the uptake of Cu and Zn by this grass, in view of its potential usage for phytostabilization of Cu-polluted soils. Five soils, containing 301-5180 mg/kg Cu, were collected from the surroundings of copper smelter Legnica, and amended with lignite (LG) and limed sewage sludge (SS). Plant growth and the concentrations of Cu and Zn in the shoots and roots of grass were measured in a pot experiment and related to the results of Pytotoxkit and Microtox® tests performed on soil solution.

Influence of soil properties and phosphate addition on arsenic uptake from polluted soils by velvetgrass (Holcus lanatus).

Four kinds of soil material were used in a pot experiment with velvetgrass (Holcus lanatus). Two unpolluted soils: sand (S) and loam (L) were spiked with sodium arsenite (As II) and arsenate (As V), to obtain total arsenic (As) concentrations of 500 mg As kg(-1). Two other soils (ZS I, ZS III), containing 3320 and 5350 mg As kg(-1), were collected from Zloty Stok where gold and arsenic ores were mined and processed for several centuries.

Spatial variability and temporal changes in the heavy metal content of soils with a deep furrow-and-ridge microrelief formed by an afforestation plowing.

An appropriate sampling method that provides for the representation of the collected material and the reliability of results plays a crucial role in environmental monitoring. This is especially important in soil quality investigations on sites with a differentiated surface microrelief, as in the case of afforested post-arable soils that have a specific, deep furrow-and-ridge microrelief. The present research was carried out on three sites afforested with pine (4-, 8-, and 15-year-old stands) located near a large tailings pond collecting the wastes from copper ore enrichment.