Estimating nitrogen flows of agricultural soils at a landscape level - A modelling study of the Upper Enns Valley, a long-term socio-ecological research region in Austria.

This paper explores the fate of reactive nitrogen (Nr) on the landscape scale of present agricultural production practice on arable and grassland soils. We use the soil modelling tool LandscapeDNDC (landscape scale DeNitrification-DeComposition model) to quantify resulting flows of Nr distributed to the atmosphere, hydrosphere and the crops. Test area is a watershed in the Austrian Alps characterized by arable production in the low-lying areas and grassland in the mountains.

A global database of water vapor isotopes measured with high temporal resolution infrared laser spectroscopy.

The isotopic composition of water vapour provides integrated perspectives on the hydrological histories of air masses and has been widely used for tracing physical processes in hydrological and climatic studies. Over the last two decades, the infrared laser spectroscopy technique has been used to measure the isotopic composition of water vapour near the Earth's surface. Here, we have assembled a global database of high temporal resolution stable water vapour isotope ratios (δO and δD) observed using this measurement technique.

Source partitioning of atmospheric methane using stable carbon isotope measurements in the Reuss Valley, Switzerland.

Measurements of methane ( ) mole fractions and that resolve the diel cycle in the agriculturally dominated Reuss Valley, Switzerland, were used to quantify the contributions of different sources to the atmospheric source mix. Both a nocturnal (NBL) and a diurnal convective boundary layer (CBL) approach were employed. A diel course of mole fractions was found with a daytime minimum (background around 1900 ppb) and a nocturnal maximum (up to 3500 ppb).

Chemical Characterization of Highly Functionalized Organonitrates Contributing to Night-Time Organic Aerosol Mass Loadings and Particle Growth.

Reactions of volatile organic compounds (VOC) with NO radicals and of reactive intermediates of oxidized VOC with NO can lead to the formation of highly functionalized organonitrates (ON). We present quantitative and chemical information on ON contributing to high night-time organic aerosol (OA) mass concentrations measured during July-August 2016 in a rural area in southwest Germany. A filter inlet for gases and aerosols coupled to a high-resolution time-of-flight chemical ionization mass spectrometer (FIGAERO-HR-ToF-CIMS) was used to analyze the molecular composition of ON in both the gas and particle phase.

The mysterious long-range transport of giant mineral dust particles.

Giant mineral dust particles (>75 μm in diameter) found far from their source have long puzzled scientists. These wind-blown particles affect the atmosphere's radiation balance, clouds, and the ocean carbon cycle but are generally ignored in models. Here, we report new observations of individual giant Saharan dust particles of up to 450 μm in diameter sampled in air over the Atlantic Ocean at 2400 and 3500 km from the west African coast.

A semi-empirical model of the energy balance closure in the surface layer.

It has been hypothesized that the energy balance closure problem of single-tower eddy-covariance measurements is linked to large-scale turbulent transport. In order to shed light on this problem, we investigate the functional dependence of the normalized residual for the potential temperature and humidity conservation equations, i.e.

Drip fertigation significantly reduces nitrogen leaching in solar greenhouse vegetable production system.

Vegetable production in solar greenhouses in northern China results in the excessive use of nitrogen (N) fertilizers and water via flooding irrigation. Both factors result in low N use efficiency and high environmental costs because groundwater becomes contaminated with nitrate (NO). Four consecutive tomato (Lycopersicum esculentum Mill.

Ice Nucleation at the Water-Sapphire Interface: Transient Sum-Frequency Response without Evidence for Transient Ice Phase.

Heterogeneous ice nucleation at the water-sapphire interface is studied using sum-frequency generation spectroscopy. We follow the response of the O-H stretch mode of interfacial water during ice nucleation as a function of time and temperature. The ice and liquid states each exhibit very distinct, largely temperature-independent responses.

Global soil nitrous oxide emissions since the preindustrial era estimated by an ensemble of terrestrial biosphere models: Magnitude, attribution, and uncertainty.

Our understanding and quantification of global soil nitrous oxide (N O) emissions and the underlying processes remain largely uncertain. Here, we assessed the effects of multiple anthropogenic and natural factors, including nitrogen fertilizer (N) application, atmospheric N deposition, manure N application, land cover change, climate change, and rising atmospheric CO concentration, on global soil N O emissions for the period 1861-2016 using a standard simulation protocol with seven process-based terrestrial biosphere models. Results suggest global soil N O emissions have increased from 6.

Volatility of Amorphous Solid Water.

Amorphous solid water is probably the most abundant form of solid water in the universe. Its saturation vapor pressure and thermodynamic properties, however, are not well known. We have investigated the saturation vapor pressure over vapor-deposited amorphous ice at temperatures between 133 and 147 K using a novel experimental method.

Climate change to severely impact West African basin scale irrigation in 2 °C and 1.5 °C global warming scenarios.

West Africa is in general limited to rainfed agriculture. It lacks irrigation opportunities and technologies that are applied in many economically developed nations. A warming climate along with an increasing population and wealth has the potential to further strain the region's potential to meet future food needs.

Estimation of evapotranspiration of temperate grassland based on high-resolution thermal and visible range imagery from unmanned aerial systems.

Spatially distributed high-resolution data of land surface temperature (LST) and evapotranspiration (ET) are important information for crop water management and other applications in the agricultural sector. While satellite data can provide LST high-resolution data of 100 m, the current development of unmanned aerial systems (UAS) and affordable low-weight thermal cameras allows LST and subsequent ET to be derived at resolutions down to centimetre scale. In this study, UAS-based images in the thermal infrared (TIR) and visible spectral range were collected over a managed temperate grassland in July 2016 at the Terrestrial Environmental Observatories Networks TERENO preAlpine observatory site at Fendt, Germany.

The Kobresia pygmaea ecosystem of the Tibetan highlands - Origin, functioning and degradation of the world's largest pastoral alpine ecosystem: Kobresia pastures of Tibet.

With 450,000 kmKobresia (syn. Carex) pygmaea dominated pastures in the eastern Tibetan highlands are the world's largest pastoral alpine ecosystem forming a durable turf cover at 3000-6000 m a.s.

Impact of climate change on backup energy and storage needs in wind-dominated power systems in Europe.

The high temporal variability of wind power generation represents a major challenge for the realization of a sustainable energy supply. Large backup and storage facilities are necessary to secure the supply in periods of low renewable generation, especially in countries with a high share of renewables. We show that strong climate change is likely to impede the system integration of intermittent wind energy.

Reassessment of pre-industrial fire emissions strongly affects anthropogenic aerosol forcing.

Uncertainty in pre-industrial natural aerosol emissions is a major component of the overall uncertainty in the radiative forcing of climate. Improved characterisation of natural emissions and their radiative effects can therefore increase the accuracy of global climate model projections. Here we show that revised assumptions about pre-industrial fire activity result in significantly increased aerosol concentrations in the pre-industrial atmosphere.

Land-use emissions play a critical role in land-based mitigation for Paris climate targets.

Scenarios that limit global warming to below 2 °C by 2100 assume significant land-use change to support large-scale carbon dioxide (CO) removal from the atmosphere by afforestation/reforestation, avoided deforestation, and Biomass Energy with Carbon Capture and Storage (BECCS). The more ambitious mitigation scenarios require even greater land area for mitigation and/or earlier adoption of CO removal strategies. Here we show that additional land-use change to meet a 1.

Processes that determine the interplay of root exudation, methane emission and yield in rice agriculture.

Rice is the most important staple food for half of the world's population, but also accounts for about 10% of all anthropogenic CH emissions. In spite of a wealth of information on the mechanistic basis and the importance of the rice plant in mediating these emissions, the significance of root exudation for CH emissions and the processes that determine root exudation are not well understood. Root exudates derive from photosynthate allocated to the root and subjected to root anabolic and catabolic processes.

Land-use and abandonment alters methane and nitrous oxide fluxes in mountain grasslands.

Grasslands cover more than one fifth of total land area in Europe and contribute significantly to the total greenhouse gas budget. The impact of management and land use on the carbon cycle and carbon sequestration in grasslands has been well-studied, however effects on emissions of NO and CH remain uncertain. Additionally, the majority of studies have focussed on management differences between intensively managed grasslands, with few results available for lightly managed grasslands and in particular grassland abandonment.

Early stage litter decomposition across biomes.

Through litter decomposition enormous amounts of carbon is emitted to the atmosphere. Numerous large-scale decomposition experiments have been conducted focusing on this fundamental soil process in order to understand the controls on the terrestrial carbon transfer to the atmosphere. However, previous studies were mostly based on site-specific litter and methodologies, adding major uncertainty to syntheses, comparisons and meta-analyses across different experiments and sites.

Perspectives of regional paleoclimate modeling.

Regional climate modeling bridges the gap between the coarse resolution of current global climate models and the regional-to-local scales, where the impacts of climate change are of primary interest. Here, we present a review of the added value of the regional climate modeling approach within the scope of paleoclimate research and discuss the current major challenges and perspectives. Two time periods serve as an example: the Holocene, including the Last Millennium, and the Last Glacial Maximum.

Larval exposure to the neonicotinoid imidacloprid impacts adult size in the farmland butterfly .

Populations of farmland butterflies have been suffering from substantial population declines in recent decades. These declines have been correlated with neonicotinoid usage both in Europe and North America but experimental evidence linking these correlations is lacking. The potential for non-target butterflies to be exposed to trace levels of neonicotinoids is high, due to the widespread contamination of agricultural soils and wild plants in field margins.

Intra-specific relatedness, spatial clustering and reduced demographic performance in tropical rainforest trees.

Intra-specific negative density dependence promotes species coexistence by regulating population sizes. Patterns consistent with such density dependence are frequently reported in diverse tropical tree communities. Empirical evidence demonstrating whether intra-specific variation is related to these patterns, however, is lacking.