Unraveling the infrared detection properties of BiTe depending on thickness under the semiconductor and metal surface states.

BiTe recently emerges as a promising candidate material for the next generation of mid-wave to long-wave infrared photodetection owing to its exceptionally narrow bandgap (approximately 0.2 eV) and the favorable photoelectronic properties. In particular, its topological insulator structure is safeguarded by time-reversal symmetry, leading to electronic structures with distinct surface and bulk states as well as distinctive optoelectronic properties.

Electrosynthesis of Atomically Precise Au Nanoclusters.

Innovation in synthesis methodologies is crucial for advancing the discovery of new materials. This work reports the electrosynthesis of a [Au(4-BuPhC≡C)(Dppe)]Cl nanocluster (Au NC) protected by alkynyl and phosphine ligands. From simple precursor, HAuCl and ligands, the whole synthesis is driven by a constant potential in single electrolytic cell.

Organelle-targeted BODIPY-conjugated platinum(IV) anticancer prodrugs for overcoming drug resistance.

Platinum-based chemotherapy, despite being a cornerstone of cancer treatment, faces significant challenges due to acquired drug resistance. To address this issue, we have designed three organelle-targeting platinum(IV) prodrugs conjugated with BODIPY fluorophores, enabling spatiotemporal control through green light irradiation. These BODIPY-Pt(IV) conjugates exhibit excellent stability in PBS buffer, demonstrating resilience under physiological conditions.

Gold-Catalyzed Cross-Coupling Reactions of Organoiodides with Disulfides: Access to Aryl Sulfides and Vinyl Sulfide Derivatives.

Thioethers and their derivatives play important roles in synthetic chemistry, medicinal chemistry, and materials science. Herein, we report a hemilabile P,N-ligand-assisted gold-catalyzed C-S cross-coupling reaction of organoiodides with disulfides. In this reaction, alkyl or aryl disulfides react smoothly with aryl or vinyl iodides to afford a series of aryl sulfide and vinyl sulfide derivatives in good to excellent yields.

Tungsten Oxide/g-CN Heterostructures: Composition, Structure, and Photocatalytic Applications.

The construction of heterostructures promotes extending the light adsorption range of graphitic carbon nitride (g-CN) materials, improving the photogenerated charge carrier separation/transfer efficiency for attaining much enhanced performances. Because defective tungsten oxide (WO) materials possess rich composition/morphology and an extended light response in the near-infrared region, WO is a quite popular nanocomponent for modifying g-CN, forming heterostructures that can be used for various photocatalytic applications involving water splitting, CO reduction, NO removal, HO generation, and related chemical to fuel conversion reactions. In this review, important aspects of WO/g-CN heterostructure photocatalysts are reviewed to provide paradigms for composition adjustment, structural design, and photocatalytic applications of these materials.

Updated Insights Into the Mechanism of Salt-Induced Aggregation-Based Single-Molecule Surface-Enhanced Raman Spectroscopy.

Since its discovery in 1997, the single molecule surface-enhanced Raman spectroscopy (SM-SERS) has attracted wide interest owing to its enormous potential in many fields. However, the commercialized applications of SM-SERS are still limited by the lack of a clear understanding of the relevant mechanism in the famous SM-SERS experiments. In this study, a salt-gradient model is proposed to deeply investigate the physical nature and update insights into the morphological, structural, and component evolution processes of Ag NPs from dispersed nanostructures to aggregation states in the salt-induced aggregation SERS strategy.

Dual Functional Electroconductive Biofortified Electrospun Scaffold Functionalized With MWCNTs and Bacopa Monnieri for Accelerated Peripheral Nerve Regeneration.

Peripheral nerve injuries (PNIs) often lead to semi or complete loss of motor, sensory and autonomic functions. Although autografts are still the best option for PNI repair, their use is restricted due to the morbidity and availability of donor nerves. Because electrospun scaffolds may replicate the structure of native extracellular matrix (ECM), they provide a viable alternative.

Harnessing Intelligence from Brain Cells In Vitro.

Harnessing intelligence from brain cells in vitro requires a multidisciplinary approach integrating wetware, hardware, and software. Wetware comprises the in vitro brain cells themselves, where differentiation from induced pluripotent stem cells offers ethical scalability; hardware typically involves a life support system and a setup to record the activity from and deliver stimulation to the brain cells; and software is required to control the hardware and process the signals coming from and going to the brain cells. This review provides a broad summary of the foundational technologies underpinning these components, along with outlining the importance of technology integration.

Carboxyl-CNTs Act as "Defensive Shield" to Boost Proton Insertion for Stable and Fast-Charging Aqueous Zn-Mn Batteries.

Proton insertion mechanism with fast reaction kinetics is attracting more and more attention for high-rate and durable aqueous Zn─MnO batteries. However, hydrated Zn insertion reaction accompanied with Jahn-Teller effect and Mn disproportionation generally leads to sluggish rate capability and irreversible structure transformation. Here, carboxyl-carbon nanotubes supported α-MnO nanoarrays (C─MnO) cathode is successfully fabricated by a convent grinding process for high-performance Zn batteries.

Recommendations for Design, Execution, and Reporting of Studies on Experimental Thoracic Aortopathy in Preclinical Models.

There is a recent dramatic increase in research on thoracic aortic diseases that includes aneurysms, dissections, and rupture. Experimental studies predominantly use mice in which aortopathy is induced by chemical interventions, genetic manipulations, or both. Many parameters should be deliberated in experimental design in concert with multiple considerations when providing dimensional data and characterization of aortic tissues.

Effects of tea polyphenols disinfectant on microbial communities and potential pathogenic bacteria in water.

The structural and abundance changes in water disinfected by tea polyphenols were investigated in high-abundance microbial communities (HAMC), medium-abundance microbial communities (MAMC), and low-abundance microbial communities (LAMC), also included the interactions within and between these communities. The antibacterial effect of tea polyphenols was observed at concentrations of 20-300 mg/L. If the tea polyphenols concentration is greater than or equal to 200 mg/L, it can continue to inhibit the growth of bacteria, and keep the total number of bacteria in 48 hours no more than100 CFU/ml, and this reflected the continuity of tea polyphenols disinfectant in the pipe network.

Chaotic Direct Ink Writing (ChDIW) of Hybrid Hydrogels: Implication for Fabrication of Micro-ordered Multifunctional Cryogels.

The modern era demands multifunctional materials to support advanced technologies and tackle complex environmental issues caused by these innovations. Consequently, material hybridization has garnered significant attention as a strategy to design materials with prescribed multifunctional properties. Drawing inspiration from nature, a multi-scale material design approach is proposed to produce 3D-shaped hybrid materials by combining chaotic flows with direct ink writing (ChDIW).

Highly Efficient Indoor Perovskite Solar Cells with 40% Efficiency Using Perylene Diimide-Based Zwitterionic Cathode Interlayers.

Metal halide perovskites are ideal candidates for indoor photovoltaics (IPVs) due to their tunable bandgaps, which allow the active layers to be optimized for artificial light sources. However, significant non-radiative carrier recombination under low-light conditions has limited the full potential of perovskite-based IPVs. To address this challenge, an integration of perylene diimide (PDI)-based sulfobetaines as cathode interlayers (CILs) is proposed and the impact of varying alkyl chain length (from 1,2-ethylene to 1,5-pentylene) between the cationic and the anionic moieties is examined.

Controlled Modulation of Intrinsic Electron Response in C/CoT Nanoplates Toward Multispectral Excitation Devices.

Electromagnetic materials with adjustable dielectric and magnetic properties are constantly sought after in electronic and industrial fields. In this study, an innovative strategy that customizes anchored Co-based nanoparticles to optimize the electronic behaviors is proposed for the first time, enabling a controllable and high-efficiency evolution of the macroscopic electromagnetic response of Co-based (C/CoT) nanoplates across the X-ray, light in the solar band and gigahertz band. Specifically, in the gigahertz band, the C/Co and C/CoSe nanoplates with high-power loss capabilities can effectively attenuate and convert electromagnetic energy into heat energy, which not only prevents space electromagnetic radiation but also powers energy for various electromagnetic devices such as thermoelectric generators and microwave actuators.

Crystalline CoP@ Amorphous WP Coaxial Nanowire Arrays as Bifunctional Electrocatalyst for Water Splitting.

The crystalline CoP@ amorphous WP core-shell nanowire arrays are oriented grown on the Ni foam (CoP@WP/NF). The amorphous WP shell provides more active sites, and the interface charge coupling accelerates the kinetic of the catalytic reaction, making the CoP@WP/NF catalysts excellent activity. In acidic, only 13 and 97 mV overpotentials are needed to reach 10 mA cm and 100 mA cm, respectively, which are the lowest overpotentials among all reported Transition metal phosphide (TMP) catalysts, of course, much lower than that of the Pt/C catalyst (31 mV at 10 mA cm, 120 mV at 100 mA cm).

Integration of Photodiagnosis and Therapy Guided by Micro/Nanorobots.

Micro/Nanorobots(MNRs)integrated with phototherapy represent an emerging approach to cancer treatment and hold significant potential for addressing bacterial infections, neurological disorders, cardiovascular diseases, and related conditions. By leveraging micro/nanoscale motor systems in conjunction with phototherapy, these robots enable real-time guidance and monitoring of therapeutic processes, improving drug delivery precision and efficiency. This integration not only enhances the effectiveness of phototherapy but also minimizes damage to surrounding healthy tissues.

A multi-objective function for deep learning-based automatic energy efficiency power allocation in multicarrier noma system using hybrid heuristic improvement.

Non-Orthogonal Multiple Access (NOMA) is the successive multiple-access methodologies for modern communication devices. Energy Efficiency (EE) is suggested in the NOMA system. In dynamic network conditions, the consideration of NOMA shows high computational complexity that minimizes the EE to degrade the system performance.

Regulation of immune responses to therapeutic factor VIII by transplacental delivery of Fc-fused immunodominant factor VIII domains or peptides.

Patients with severe hemophilia A (HA) often develop undesired immune responses to therapeutic factor VIII (FVIII) that hamper replacement therapy with FVIII-derived products. The transplacental delivery of two Fc-fused FVIII domains in pregnant HA mice was shown to induce partial FVIII-specific immune tolerance in the offspring. Here, we evaluated whether the transplacental delivery of Fc-fused FVIII (rFVIIIFc) induces complete immune tolerance towards FVIII.

Tetramethylurea Based Intermediate Phase Engineering for Efficient and Stable Perovskite Solar Cells.

Perovskite solar cells (PSCs) are emerging photovoltaic devices renowned for their high efficiency and low cost. Efficient and stable PSCs depend on high-quality perovskite films, which are strongly influenced by the excellent nucleation and growth. The choice of solvent is critical for the crystallization behavior of perovskite films.

Stochastic Impact Electrochemistry of Alkanethiolate-Functionalized Silver Nanoparticles.

This study uses single-impact experiments to explore how the nanoparticles' surface chemistry influences their redox activity. 20 and 40 nm-sized silver nanoparticles are functionalized with alkanethiol ligands of various chain lengths (n = 3, 6, 8, and 11) and moieties (carboxyl ─COOH / hydroxyl ─OH), and the critical role of the particle shell is systematically examined. Short COOH-terminated ligands enable efficient charge transfer, resulting in higher impact rates and fast, high-amplitude transients.

Manipulation of Single Nanowire and its Applications.

Micro/nano manipulation of single nanowire has emerged as a popular direction of study in the field of nanotechnology, with promising applications in cutting-edge technologies such as device manufacturing, medical treatment, and nanorobotics. The synthesis of nanowires with controllable length and diameter makes them meet various micro/nano manipulation demands. As manipulation techniques have advanced, including the use of optical tweezers, electric and magnetic fields, mechanical control, and several more control methods, they have demonstrated unique advantages in different application fields.

Layered-Hierarchical Dual-Lattice Strain Suppresses NiSe Surface Reconstruction for Stable OER in Alkaline Fresh/Seawater Splitting.

Transition metal selenides (TMSe) are promising oxygen evolution reaction (OER) electrocatalysts but act as precursors rather than the actual active phase, transforming into amorphous oxyhydroxides during OER. This transformation, along with the formation of selenium oxyanions and unstable heterointerfaces, complicates the structure-activity relationship and reduces stability. This work introduces novel "layered-hierarchical dual lattice strain engineering" to inhibit the surface reconstruction of NiSe by modulating both the nickel foam (NF) substrate with MoN nanosheets (NM) and the NiSe nanorods-nanosheets catalytic layer (NiSe-NiSe-NiO, NSN) with ultrafast interfacial bimetallic amorphous NiFeOOH coating, achieving the optimized NM/NSN/NiFeOOH configuration.

Recent Advances for Cation-Anion Aggregates in Solid Polymer Electrolytes: Mechanism, Strategies, and Applications.

Solid polymer electrolytes (SPEs) have garnered significant attention from both academic and industrial communities due to their high safety feature and high energy density in combination with lithium(Li) metal anode. Nevertheless, their practical applications remain constrained by the relatively low room-temperature ionic conductivity and interface issues. Anion-derived cation-anion aggregates (AGGs), derived from high-concentration liquid electrolytes, promote a stable solid-electrolyte interphase layer, which have gradually propelled their application in SPEs.

MXenes and MXene-based composites for biomedical applications.

MXenes, a novel class of two-dimensional materials, have recently emerged as promising candidates for biomedical applications due to their specific structural features and exceptional physicochemical and biological properties. These materials, characterized by unique structural features and superior conductivity, have applications in tissue engineering, cancer detection and therapy, sensing, imaging, drug delivery, wound treatment, antimicrobial therapy, and medical implantation. Additionally, MXene-based composites, incorporating polymers, metals, carbon nanomaterials, and metal oxides, offer enhanced electroactive and mechanical properties, making them highly suitable for engineering electroactive organs such as the heart, skeletal muscle, and nerves.

Tuning Transition Metal 3d Spin state on Single-atom Catalysts for Selective Electrochemical CO Reduction.

Tuning transition metal spin states potentially offers a powerful means to control electrocatalyst activity. However, implementing such a strategy in electrochemical CO reduction (COR) is challenging since rational design rules have yet to be elucidated. Here we show how the addition of P dopants to a ferromagnetic element (Fe, Co, and Ni) single-atom catalyst (SAC) can shift its spin state.