A high-efficient electrochemical degradation of diclofenac in water on planar and microstructured 2D, and macroporous 3D boron-doped diamond electrodes: Identification of degradation and transformation products.

The highly efficient degradation of persistent organic substances by electrochemical advanced oxidation processes (EAOPs), which don't result in the formation of potentially harmful by-products, is crucial for the future of water management. In this study, boron-doped diamond electrodes (BDDE) with three morphologies (planar 2D, microstructured 2D, and macroporous 3D) were employed for the anodic oxidation of diclofenac (DCF) in two working electrolytes (NaCl and NaSO). In total, 11 by-products formed during the electrochemical oxidation of DCF were identified via HPLC-HRMS.

Emerging organic micropollutants as serious environmental problem: A comprehensive review.

The escalating problem of environmental pollution can be attributed to the accelerated pace of global development, which often prioritizes human needs over planetary health. Despite huge global attempts endeavours to mitigate legacy pollutants, the uninterrupted introduction of novel substances such as the emerging organic micropollutants (EOMs) represents a significant menace to the natural environment and all forms of life on the earth. The widespread occurrence of EOMs in water and wastewater is a consequence of both their growing consumption as well as the limitations of the conventional wastewater treatment methods containing such pollutants resulting in deterioration of water quality and its supplies as well as this is a significant challenge for researchers and the scientific community alike.

-Mediated Biosynthesis of MnO Nanoparticles: Structural, Electrochemical, and Biological Investigations.

MnO nanoparticles (NPs) find diverse applications in the fields of medicine, biomedicine, biosensors, water treatment and purification, electronics, electrochemistry, and photoelectronics. The production of MnO NPs was reported earlier through various physical, chemical, and green routes, but no studies have still been performed on their biosynthesis from . We synthesized manganese oxide NPs, i.

Carboligation towards production of hydroxypentanones.

2-Hydroxy-3-pentanone and 3-hydroxy-2-pentanone are flavor molecules present in various foods, such as cheese, wine, durian, and honey, where they impart buttery, hay-like, and caramel-sweet aromas. However, their utilization as flavoring agents is constrained by a lack of developed synthesis methods. In this study, we present their synthesis from simple starting compounds available in natural quality, catalyzed by previously characterized ThDP-dependent carboligases.

Catalytic Stability of -1-(4-Hydroxyphenyl)-Ethanol Dehydrogenase from .

Derived from the denitrifying bacterium EbN1 ( sp.), the enzyme -1-(4-hydroxyphenyl)-ethanol dehydrogenase (S-HPED) belongs to the short-chain dehydrogenase/reductase family. Using research techniques like UV-Vis spectroscopy, dynamic light scattering, thermal-shift assay and HPLC, we investigated the catalytic and structural stability of S-HPED over a wide temperature range and within the pH range of 5.

Completely Methylene-Free Side Chain Enables Significant Microphase Separation at Medium IECs for Fuel-Cell Anion Exchange Membranes.

The introduction of hydrophobic side chain structures in anion exchange membranes (AEMs) to facilitate ion transport has been widely studied; however, low or moderate hydrophobic hydrocarbon and semifluorinated side chains are insufficient to induce a high degree of microphase separation. Herein, we design and prepare poly(aryl piperidinium) AEMs with completely methylene-free perfluorinated side chains, which can maximize the thermodynamic incompatibility between main- and side chains, thus enhancing microphase separation at medium ion exchange capacities (IECs). According to the molecular dynamics study, the methylene-free perfluorinated side chain leads to better hydration of cations.

Enzymatic reactions towards aldehydes: An overview.

Many aldehydes are volatile compounds with distinct and characteristic olfactory properties. The aldehydic functional group is reactive and, as such, an invaluable chemical multi-tool to make all sorts of products. Owing to the reactivity, the selective synthesis of aldehydic is a challenging task.

Influent wastewater analysis to investigate emerging trends of new psychoactive substances use in Europe.

Wastewater-based epidemiology (WBE) can provide objective and timely information on the use of new psychoactive substances (NPS), originally designed as legal alternatives of internationally controlled drugs. NPS have rapidly emerged on the global drug market, posing a challenge to drug policy and constituting a risk to public health. In this study, a WBE approach was applied to monitor the use of more than 300 NPS, together with fentanyl and its main metabolite norfentanyl, in influent wastewater collected from 12 European cities during March-June 2021.

Valorization of algal biomass to synthesize heterogeneous gCN-Biochar photocatalyst for the treatment of industrial wastewater using photocatalysis-persulfate oxidation process.

Textile wastewater, heavily contaminated with organic dyes, is generating severe problems to environment and human health. The implementation of gCN with biochar (gCN-BC) for the treatment of textile wastewater is less effective due to the limited adsorption capacity and slower degradation kinetics. To tackle these problems, peroxydisulfate (PDS) is integrated with gCN-BC photocatalyst to enhance the process efficiency and kinetics.

Automated SEM/EDX imaging for the in-depth characterization of non-exhaust traffic emissions from the Munich subway system.

A SEM/EDX based automated measurement and classification algorithm was tested as a method for the in-depth analysis of micro-environments in the Munich subway using a custom build mobile measurements system. Sampling was conducted at platform stations, to investigate the personal exposure of commuters to subway particulate matter during platform stays. EDX spectra and morphological features of all analyzed particles were automatically obtained and particles were automatically classified based on pre-defined chemical and morphological boundaries.

Exploration of linear and third-order nonlinear optical properties for donor-π-linker-acceptor chromophores derived from ATT-2 based non-fullerene molecule.

In the current study, seven non-fullerene compounds abbreviated as ATTD2-ATTD8 were designed through structural tailoring and their nonlinear optical (NLO) properties were reported. The objective of this study was to explore the potential for newly configured D-π-A type non-fullerene-based compounds. Quantum chemical methods were adopted and revealed the molecules as highly efficient materials with favorable NLO characteristics for use in optoelectronic devices.

A 2D Nano-architecture (NPSMC@Ir-Ru@rGO) Derived from Graphene Enfolded Polyphosphazene Nanospheres Decorated Ir-Ru Metals (PZS@Ir-Ru@GO) towards Bifunctional Water Splitting.

A leap-forward approach has been successfully devised to synthesize a novel hierarchical binary metal modified heteroatom doped 2D micro-/mesporous carbon-graphene nanostructure (NPSMC@Ir-Ru@rGO) for overall water splitting application. To investigate the role of decorating metals, different electrolcatalysts like NPSMC, NPSMC@rGO, NPSMC@Ir@rGO, and NPSMC@Ru@rGO were also synthesized and structural changes were compared and investigated by physiochemical techniques. All of the samples have shown electrocatalytic activities attributed to the presence of heteroatom (N, P, S) doped micro-/mesoporous carbonaceous matrix, amorphous carbon in the coexistence of graphitic lattice carbons, presence of active metal NPs (Ir and/-or Ru), an even distribution of active sites, and graphene 2D interconnected channels to promote electron transfer ability, respectively.

Exploration of nonlinear optical enhancement in acceptor-π-donor indacenodithiophene based derivatives structural variations: a DFT approach.

Herein, a series of indacenodithiophene-based derivatives (TNPD1-TNPD6) were designed having D-π-A architecture end capped acceptor modulation of a reference molecule (TNPR) to investigate nonlinear optical (NLO) behavior. Quantum chemical calculations were accomplished to examine electronic, structural and optical properties utilizing a density functional theory (DFT) approach at M06 functional with 6-311G(d,p) basis set. For this, natural bond orbitals (NBOs), density of states (DOS), frontier molecular orbitals (FMOs), transition density matrix (TDM) and non-linear optical (NLO) analyses were performed for TNPR and TNPD1-TNPD6.

Fabrication of Ternary MoS/CdS/BiS-Based Nano Composites for Photocatalytic Dye Degradation.

The synthesis and design of low-cost visible-light-active catalysts for the photodegradation of organic dyes have been regarded as an efficient way to use solar energy in addressing environmental issues. We report the fabrication of MoS/CdS nanoparticles functionalized with BiS nanoflakes. The ternary composites of "MoS/CdS/BiS" were synthesized in situ by a hydrothermal method at different temperatures.

Sensing interface based on electrodeposited Cu-BTC microporous film for electrochemical detection of the painkiller paracetamol.

The use of metal-organic framework materials in electrochemical sensors has been gaining more attention in the last few years due to their highly porous structure and electrocatalytic activity. In this work, a novel paracetamol electrochemical sensor based on a Cu-BTC microporous film electrochemically grown onto glassy carbon electrode was introduced. The Cu-BTC film was deposited directly onto the electrode surface an electrochemical approach using a EtN probase to accelerate the growth of Cu-BTC.

Inactivation and aggregation of R-specific 1-(4-hydroxyphenyl)-ethanol dehydrogenase from Aromatoleum aromaticum.

R-specific 1-(4-hydroxyphenyl)-ethanol dehydrogenase (R-HPED) is a promising biotool for stereoselective synthesis of chiral aromatic alcohols. This work focused on the evaluation of its stability under storage and in-process conditions in the pH range from 5.5 to 8.

Monitoring Alcohol Consumption in Slovak Cities during the COVID-19 Lockdown by Wastewater-Based Epidemiology.

The consumption of alcohol in a population is usually monitored through individual questionnaires, forensics, and toxicological data. However, consumption estimates have some biases, mainly due to the accumulation of alcohol stocks. This study's objective was to assess alcohol consumption in Slovakia during the COVID-19 pandemic-related lockdown using wastewater-based epidemiology (WBE).

Spinach-derived boron-doped g-CN/TiO composites for efficient photo-degradation of methylene blue dye.

Green synthesis of nanoparticles can be beneficial due to their low toxicity, cost-effectiveness, and environment-friendliness. Its synthesis involves the use of eco-friendly and biodegradable materials such as plant extracts, natural products, and microorganisms to reduce the negative environmental impacts of traditional nanoparticle synthesis methods. Herein, Spinacia oleracea leaves are used as a boron source, and a visible light active photo-catalyst is produced.

Removal of ceftriaxone sodium antibiotic from pharmaceutical wastewater using an activated carbon based TiO composite: Adsorption and photocatalytic degradation evaluation.

The water pollution becomes a serious concern for the sustainability of ecosystems due to the existence of pharmaceutical products (ceftriaxone (CEF) antibiotic). Even in low concentration of CEF has lethal effects on ecosystem and human health. To remove CEF, TiO is considered as an effective and efficient nanoparticles, however its performance is reduced due to wider energy gap and rapid recombination of charge carriers.

Adsorption Performance of a Multimodal Anion-Exchange Chromatography Membrane: Effect of Liquid Phase Composition and Separation Mode.

Membrane chromatography is a modern, high-throughput separation method that finds important applications in therapeutic protein purification. Multimodal, salt-tolerant membranes are the most recent innovation in chromatographic membrane adsorbents. Due to the complex structure of their ligands and the bimodal texture of their carriers, their adsorption properties have not been sufficiently investigated.

Medium engineering of phenylethanoid transfructosylation catalysed by yeast β-fructofuranosidase.

Tyrosol and hydroxytyrosol, by-products of olive oil production, are valuable substrates for enzymatic transglycosylation that can provide products with pharmaceutical potential. Phenylethanoid fructosides are produced from sucrose and phenylethanoids by the catalytic action of β-fructofuranosidases. This work dealt with the potential of the most abundant β-fructofuranosidase, baker's yeast invertase, for this bioconversion.

Aerosol emissions from a marine diesel engine running on different fuels and effects of exhaust gas cleaning measures.

The emissions of marine diesel engines have gained both global and regional attentions because of their impact on human health and climate change. To reduce ship emissions, the International Maritime Organization capped the fuel sulfur content of marine fuels. Consequently, either low-sulfur fuels or additional exhaust gas cleaning devices for the reduction in sulfur dioxide (SO) emissions became mandatory.