Calcined Clays as Concrete Additive in Structural Concrete: Workability, Mechanical Properties, Durability, and Sustainability Performance.

Calcined clays (CCs) as supplementary cementitious materials (SCMs) can be a promising option to reduce clinker content and CO emissions in eco-friendly concretes. Although CCs as components of composite cements in combination with Ordinary Portland Cement (OPC) and limestone powder (LSP) have attracted industry interest, their use as concrete additives is limited. This study investigates the effects of the addition of CCs on the fresh and hardened properties of industry-standard ready-mixed concretes.

Investigations on Stability of Polycarboxylate Superplasticizers in Alkaline Activators for Geopolymer Binders.

Calcined clays are interesting starting materials to be used as SCMs (supplementary cementitious materials) in cements or to be converted to geopolymers by activation with a high alkaline activator. The adjustment of the properties in the fresh state, especially regarding the consistency of these binders, is almost exclusively achieved by the addition of water, since commercially available superplasticizers seem to be ineffective in low-calcium geopolymer systems. The aim of this study was a systematic investigation of various PCE (polycarboxylate ester/ether) superplasticizers (methacrylate ester PCE: MPEG, isoprenol ether PCE: IPEG, methallyl ether PCE: HPEG) with respect to their stability in different alkaline activators (NaOH, KOH, sodium and potassium silicate solutions).

Monitoring of freezing patterns within 3D collagen-hydroxyapatite scaffolds using infrared thermography.

The importance of cryopreservation in tissue engineering is unceasingly increasing. Preparation, cryopreservation, and storage of tissue-engineered constructs (TECs) at an on-site location offer a convenient way for their clinical application and commercialization. Partial freezing initiated at high sub-zero temperatures using ice-nucleating agents (INAs) has recently been applied in organ cryopreservation.

Characterization data of reference materials used for phase II of the priority program DFG SPP 2005 "Opus Fluidum Futurum - Rheology of reactive, multiscale, multiphase construction materials".

A thorough characterization of base materials is the prerequisite for further research. In this paper, the characterization data of the reference materials (CEM I 42.5 R, limestone powder, calcined clay and a mixture of these three components) used in the second funding phase of the priority program 2005 of the German Research Foundation (DFG SPP 2005) are presented under the aspects of chemical and mineralogical composition as well as physical and chemical properties.

Compressive Fatigue Investigation on High-Strength and Ultra-High-Strength Concrete within the SPP 2020.

The influence of the compressive strength of concrete on fatigue resistance has not been investigated thoroughly and contradictory results can be found in the literature. To date, the focus of concrete fatigue research has been on the determination of the numbers of cycles to failure. Concerning the fatigue behaviour of high-strength concrete (HPC) and, especially, ultra-high-strength concrete (UHPC), which is described by damage indicators such as strain and stiffness development, little knowledge is available, as well as with respect to the underlying damage mechanisms.

Influence of the composition of high-strength concrete and mortar on the compressive fatigue behaviour.

The results of compressive fatigue investigations on four high-strength concretes and their corresponding mortars are presented. The influences of coarse aggregates generally, the substitution of basalt coarse aggregate by granite, the addition of silica fume and the variation of the water to cement () ratio are investigated systematically. The numbers of cycles to failure, the developments of strain, stiffness, dissipated energy and acoustic emission hits are focused on in the analyses.

Influence of Moisture Content and Wet Environment on the Fatigue Behaviour of High-Strength Concrete.

The influence of a wet environment on the fatigue behaviour of high-strength concrete has become more important in recent years with the expansion of offshore wind energy systems. According to the few investigations documented in the literature, the fatigue resistance of specimens submerged in water is significantly lower compared to that of specimens in dry conditions. However, it is still not clear how the wet environment and the moisture content in concrete influence its fatigue behaviour and which damage mechanisms are involved in the deterioration process.

Compressive Fatigue Behaviour of High-Strength Concrete and Mortar: Experimental Investigations and Computational Modelling.

A high-strength concrete and mortar subjected to compressive fatigue loading were comparatively investigated using experimental and computational techniques. The focus of the investigations was on the influence of the coarse aggregate in high-strength concrete. Accordingly, the fatigue behaviour was analysed experimentally using the macroscopic damage indicators strain, stiffness and acoustic emission hits.

Fatigue-Induced Damage in High-Strength Concrete Microstructure.

A high-strength concrete subjected to compressive fatigue loading with two maximum stress levels was investigated and the behaviour was evaluated using the macroscopic damage indicators, strain and acoustic emission hits (AE-hits), combined with microstructural analyses utilising light microscopy and scanning electron microscopy (SEM). A clustering technique using Gaussian mixture modelling combined with a posterior probability of 0.80 was firstly applied to the AE-hits caused by compressive fatigue loading, leading to two clusters depending on the maximum stress level.

Modified Carboxymethylcellulose-Based Scaffolds as New Potential Ecofriendly Superplasticizers with a Retardant Effect for Mortar: From the Synthesis to the Application.

This article is focused on the research and development of new cellulose ether derivatives as innovative superplasticizers for mortar systems. Several synthetic strategies have been pursued to obtain new compounds to study their properties on cementitious systems as new bio-based additives. The new water-soluble admixtures were synthesized using a complex carboxymethylcellulose-based backbone that was first hydrolyzed and then sulfo-ethylated in the presence of sodium vinyl sulphonate.

Influence of Low-Pressure Treatment on the Morphological and Compositional Stability of Microscopic Ettringite.

The impact of low-pressure treatment on the crystal structure, morphology, and chemical composition of ettringite, due to their major importance with respect to processability (i.a., drying conditions) and to the analysis of ettringite-containing samples, is examined utilizing X-ray diffraction, thermogravimetric analysis, Raman spectroscopy, and environmental scanning electron microscopy.

Formation of Geopolymers Using Sodium Silicate Solution and Aluminum Orthophosphate.

This paper reports the formation and structure of fast setting geopolymers activated by using three sodium silicate solutions with different modules (1.6, 2.0 and 2.