One-Step Patterning of Organic Semiconductors on Gold Electrodes via Capillary-Bridge Manipulation.

Patterning organic semiconductors directly on Au electrodes possesses the advantages of eliminating metal atomic penetration effect, compatibility with fine lithography processes, and feasibility of work function modification on electrodes, and it is therefore of value in the commercial manufacturability application of optoelectronic devices with low cost, large scale, and high efficiency. Solution processing, is relatively inexpensive and is scalable to large areas. Nonetheless, conventional solution processing approaches have trade-offs among controllable morphology, regular alignment, precise position, and ordered molecular packing arising from the uncontrollable dewetting kinetics.

Movement posture and injury pattern of pelvis-lumbar spine of seated human impacted by the vertical high loads: a finite element analysis.

The injury conditions of the sitting position occupant inside the military equipment are highly related to the vertical impact environments. In this study, a detailed three-dimensional finite element (FE) model of pelvis-lumbar spine of seated human with nonlinear material property and strain failure criterion was developed and validated. A series of sinusoidal accelerations with a constant peak speed of 8 m/s and frequencies ranging from 10 Hz to 90 Hz were loaded on the FE model to investigate the injury conditions under different high loading rates.

Ultra-High Temperature Molten Oxide Electrochemistry.

Recently, the ultra-high temperature electrochemistry (UTE, about >1000 °C) has emerged, which represents an exploration to extend the temperature limit of human technology in electrochemical engineering. UTE has far-reaching impact on revolutionary low-carbon metal extraction and the in situ production of oxygen for deep-space exploration. It is hence of urgency to systematically summarize the development of UTE.

An electrochemically stable homogeneous glassy electrolyte formed at room temperature for all-solid-state sodium batteries.

All-solid-state sodium batteries (ASSSBs) are promising candidates for grid-scale energy storage. However, there are no commercialized ASSSBs yet, in part due to the lack of a low-cost, simple-to-fabricate solid electrolyte (SE) with electrochemical stability towards Na metal. In this work, we report a family of oxysulfide glass SEs (NaPSO, where 0 < x ≤ 0.

Locust-Inspired Direction-Dependent Transport Based on a Magnetic-Responsive Asymmetric-Microplate-Arrayed Surface.

Inspired by the highly efficient jumping mechanism of locusts, a magnetic-responsive asymmetric-microplate-arrayed surface is designed. Elastic energy can be stored in the microplate and rapidly released by loading and removing a magnetic field. Similar to the bouncing behavior of the locust, objects deposited on the surface of the microplate-arrayed surface will bounce suddenly.

An in situ micro-indentation apparatus for investigating mechanical parameters of thermal barrier coatings under temperature gradient.

Premature failure of thermal barrier coatings (TBCs) under a temperature gradient is an overriding concern in many applications, and their mechanical parameters are essential to failure analysis. In this study, an in situ micro-indentation apparatus, including a heating module, cooling module, and micro-indentation module, was developed to study the mechanical parameters of TBCs with a temperature gradient. The upper surface of the TBC was heated by radiation to simulate high-temperature service conditions, and the bottom surface was gas-cooled.

Understanding Enhanced Ionic Conductivity in Composite Solid-State Electrolyte in a Wide Frequency Range of 10 -10 Hz.

The ionic conductivity of composite solid-state electrolytes (SSEs) can be tuned by introducing inorganic fillers, of which the mechanism remains elusive. Herein, ion conductivity of composite SSEs is characterized in an unprecedentedly wide frequency range of 10 -10  Hz by combining chronoamperometry, electrochemical impedance spectrum, and dielectric spectrum. Using this method, it is unraveled that how the volume fraction v and surface fluorine content x of TiO fillers tune the ionic conductivity of composite SSEs.

Controllable preparation of an ice cream-shaped hollow sphere array.

Hollow microspheres with high specific surface area are widely used in thermal insulation, drug delivery and sustained release, catalysis and optical absorption. Eutectic gallium-indium (EGaIn) undergoes phase transformation and oxidation when heated in aqueous solution, which can provide a crystal seed and preferential growth environment for nanomaterials. Therefore, it is very promising to further study the application of liquid metal in functional and structural nanomaterials.

Investigation on Flaw Evolution of Additively Manufactured AlO Ceramic by In Situ X-ray Computed Tomography.

The additive manufacturing process may create flaws inside ceramic materials. The flaws have a significant influence on the macroscopic mechanical behavior of ceramic materials. In order to reveal the influence of flaws on the mechanical behavior of additively manufactured ceramic, flaw evolution under mechanical loads was studied by in situ X-ray computed tomography (XCT) in this work.

Electrocatalysis for Continuous Multi-Step Reactions in Quasi-Solid-State Electrolytes Towards High-Energy and Long-Life Aluminum-Sulfur Batteries.

Aluminum-sulfur (Al-S) batteries of ultrahigh energy-to-price ratios are a promising energy storage technology, while they suffer from a large voltage gap and short lifespan. Herein, we propose an electrocatalyst-boosting quasi-solid-state Al-S battery, which involves a sulfur-anchored cobalt/nitrogen co-doped graphene (S@CoNG) positive electrode and an ionic-liquid-impregnated metal-organic framework (IL@MOF) electrolyte. The Co-N sites in CoNG continuously catalyze the breaking of Al-Cl and S-S bonds and accelerate the sulfur conversion, endowing the Al-S battery with a shortened voltage gap of 0.

Ultrasonic reflection characteristics of Lithium-ion battery based on Legendre orthogonal polynomial method.

Mechanical properties such as density and Young's modulus of lithium-ion battery electrodes are related to the state of charge (SOC). Characterizing the battery SOC by means of ultrasonic non-destructive testing can obtain the relationship between wave propagation information and the SOC. During the battery charging process, the Young's modulus and density of the internal electrode material will change, which will affect the propagation of ultrasonic waves in the battery.

Simple but Efficient Method To Transport Droplets on Arbitrarily Controllable Paths.

The flexible manipulation of droplets manifests a wide spectrum of applications, such as micro-flow control, drug-targeted therapy, and microelectromechanical system heat dissipation. How to realize the efficient control of droplets has become a problem of concern. In this paper, a simple method that can realize the transport of droplets along any controllable path is proposed.

Laser-Induced Graphene Based Flexible Electronic Devices.

Since it was reported in 2014, laser-induced graphene (LIG) has received growing attention for its fast speed, non-mask, and low-cost customizable preparation, and has shown its potential in the fields of wearable electronics and biological sensors that require high flexibility and versatility. Laser-induced graphene has been successfully prepared on various substrates with contents from various carbon sources, e.g.

A 4D x-ray computer microtomography for high-temperature electrochemistry.

High-temperature electrochemistry is widely used in many fields. However, real-time observations and an in-depth understanding of the inside evolution of this system from an experimental perspective remain limited because of harsh reaction conditions and multiphysics fields. Here, we tackled this challenge with a high-temperature electrolysis facility developed in-house.

Stable Quasi-Solid-State Aluminum Batteries.

Nonaqueous rechargeable aluminum batteries (RABs) of low cost and high safety are promising for next-generation energy storage. With the presence of ionic liquid (IL) electrolytes, their high moisture sensitivity and poor stability would lead to critical issues in liquid RABs, including undesirable gas production, irreversible activity loss, and an unstable electrode interface, undermining the operation stability. To address such issues, herein, a stable quasi-solid-state electrolyte is developed via encapsulating a small amount of an IL into a metal-organic framework, which not only protects the IL from moisture, but creates sufficient ionic transport network between the active materials and the electrolyte.

Wafer-scale integration of stretchable semiconducting polymer microstructures via capillary gradient.

Organic semiconducting polymers have opened a new paradigm for soft electronics due to their intrinsic flexibility and solution processibility. However, the contradiction between the mechanical stretchability and electronic performances restricts the implementation of high-mobility polymers with rigid molecular backbone in deformable devices. Here, we report the realization of high mobility and stretchability on curvilinear polymer microstructures fabricated by capillary-gradient assembly method.

Recent Progress in Active Mechanical Metamaterials and Construction Principles.

Active mechanical metamaterials (AMMs) (or smart mechanical metamaterials) that combine the configurations of mechanical metamaterials and the active control of stimuli-responsive materials have been widely investigated in recent decades. The elaborate artificial microstructures of mechanical metamaterials and the stimulus response characteristics of smart materials both contribute to AMMs, making them achieve excellent properties beyond the conventional metamaterials. The micro and macro structures of the AMMs are designed based on structural construction principles such as, phase transition, strain mismatch, and mechanical instability.

Quantificational 4D Visualization of Industrial Electrodeposition.

Electrodeposition is a fundamental technology in modern society and has been widely used in metal plating and extraction, etc. However, extreme reaction conditions, including wide operation temperature ranges and corrosive media (molten salt/oxide systems as a particular example), inhibit direct in situ observation of the electrodeposition process. To visualize the electrode kinetics in such "black box," X-ray tomography is employed to monitor the electrochemical processes and three-dimensional (3D) evolution of morphology.

Heterostructured CoS/CuCoS@N-doped carbon hollow sphere for potassium-ion batteries.

Potassium ions batteries (PIBs) have been regarded as a promising choice for electrical energy storage technology due to the wide distribution of potassium resources. However, developing low-cost and robust earth-rich anode materials is still a major challenge for the practical and scalable usage of PIBs. Herein, for the first time, we developed nitrogen doped carbon coating CoS/CuCoS heterostructure (CoS/CuCoS@NCs) hollow spheres and evaluated as anode for PIBs.

Liquid Crystal Elastomer Metamaterials with Giant Biaxial Thermal Shrinkage for Enhancing Skin Regeneration.

Liquid crystal elastomers (LCEs) are a class of soft active materials of increasing interest, because of their excellent actuation and optical performances. While LCEs show biomimetic mechanical properties (e.g.

Plastic deformation and strengthening mechanism of FCC/HCP nano-laminated dual-phase CoCrFeMnNi high entropy alloy.

FCC-structured CoCrFeMnNi high entropy alloy (HEA) has attracted abroad interests for years because of its excellent mechanical properties, except for strength. Recent experiments have reported a kind of nano-laminated dual-phase (NLDP) FCC/HCP structure that can strengthen the HEA. However, it is still unknown why the HEA can be strengthened by this kind of NLDP structure.

One-level microstructure-arrayed hydrophobic surface with low surface adhesion and strong anti-wetting function.

To achieve both a low surface adhesion function and a high anti-wetting function, it is generally necessary to introduce multi-level micro-nano-structures on a surface. However, this will bring the difficulty of preparation technology, and the functions will fail due to the fact that the nanostructures can easily be damaged. In this research, the surface adhesion and anti-wetting properties of several typically one-level microstructure-arrayed hydrophobic surfaces are analyzed with the dynamics theory, including a square pillar-arrayed three-dimensional microstructure, a conical table-arrayed microstructure, and square frustum-arrayed microstructure.

Mechanical properties and clamping behaviors of snow crab claw.

The high-performing biomimetic behaviors of crustaceans are the optimal results of long-time wise adaption to their living environment. One outstanding prototype is crab claw, which has the combining advantages of lightweight and high strength. To promote relevant engineering applications, it is imperative to explore its mechanical behaviors and structural characteristics.