The Effect of Hydrothermal, Microwave, and Mechanochemical Treatments of Tin Phosphate on Sorption of Some Cations.

The samples of precipitated tin (IV) phosphate, modified using hydrothermal, microwave, and mechanochemical procedures, were studied in the process of Cs(I), Sr(II), and U(VI) ion sorption. The initial and modified samples were investigated before and after sorption using XRD, XRF, FTIR, and nitrogen adsorption-desorption. It was found that the modification procedures transformed the micro-mesoporous structure of the initial sample into a meso-macroporous structure.

Adsorption of Ag (I) Ions at the Zirconium Phosphate/KNO Aqueous Solution Interface.

The paper presented the mechanical (MChT), microwave (MWT), and hydrothermal (HTT) methods of zirconium phosphate samples modification in order to improve its adsorption affinity for the Ag (I) ions. The FTIR studies proved that the modification of both gel and xerogel samples with the ultrasonic microwaves causes an increase in the concentration of phosphate groups on the surface of MWT-modified zirconium phosphate: the isoelectric point pHiep = 2.2-2.