The effect of carbonic anhydrase on foraminiferal Mg/Ca.

Marine biogenic calcium carbonate production plays a role in the exchange of CO between ocean and atmosphere. The effect of increased CO on calcification and on the resulting chemistry of shells and skeletons, however, is only partly understood. Foraminifera are among the main marine CaCO producers and the controls on element partitioning and isotope fractionation is the subject of many recent investigations.

Genetic redundancy in the naphthalene-degradation pathway of Cycloclasticus pugetii strain PS-1 enables response to varying substrate concentrations.

Polycyclic aromatic hydrocarbon (PAH) contamination in marine environments range from low-diffusive inputs to high loads. The influence of PAH concentration on the expression of functional genes [e.g.

Reusable and inductively regenerable magnetic activated carbon for removal of organic micropollutants from secondary wastewater effluents.

This work introduces a new sustainable alternative of powdered activated carbon (PAC) - magnetically harvestable and reusable after regeneration via inductive heating - for the adsorptive removal of organic micropollutants (OMP) from secondary wastewater effluents. For this purpose, two commercial PACs - lignite "L" (1187 m/g) and coconut "C"-based (1524 m/g) - were modified with magnetic iron oxide following two different synthesis approaches: infiltration ("infiltr") and surface deposition ("depos") route. The resulting magnetic powdered activated carbons (mPAC) and their precursor PACs were fully characterized before application.

Simultaneously decreasing arsenic and cadmium in rice by soil sulfate and limestone amendment under intermittent flooding.

Water management in paddy soils can effectively reduce the soil-to-rice grain transfer of either As or Cd, but not of both elements simultaneously due to the higher mobility of As under reducing and Cd under oxidizing soil conditions. Limestone amendment, the common form of liming, is well known for decreasing Cd accumulation in rice grown on acidic soils. Sulfate amendment was suggested to effectively decrease As accumulation in rice, especially under intermittent soil flooding.

A modified integrated physical advanced primary treatment to enhance particulate organic carbon removal in municipal wastewater treatment plants.

In the pursuit of a treatment approach that is both cost-effective and environmental-friendly, the applicability of microscreen (MS) techniques coupled with a primary sedimentation tank (PST) as a physical advanced primary treatment (APT) to enhance the removal of particulate organic carbon (POC) from municipal wastewater was investigated. A pilot unit, including a modified MS, adjustable to different meshes (including 20 and 15 μm) was operated continuously downstream to the PST at the Büsnau wastewater treatment plant in Stuttgart, Germany, and monitored for more than half a year. A strategy involving time-dependent backwashing and recirculation of MS permeate was employed to remove as much POC as possible from primarily treated wastewater, thereby extending the application of the MS.

Valorization of organic carbon in primary sludge via semi-continuous dark fermentation: First step to establish a wastewater biorefinery.

In this study, lab-scale, bench-scale, and pilot-scale experiments were carried out to optimize short-chain fatty acids production from primary sludge. Batch tests showed the requirement of short retention times and semi-continuous operation mode showed a plateau of maximum daily productivity at 36-hours hydraulic retention time with minimal methanation. Optimization from pH 5 to pH 10 at 36 h-hydraulic retention time under long-term semi-continuous operating mode revealed that production of short-chain fatty acids was pH dependent and highest yields could be achieved at pH 7 by establishing optimum redox conditions for fermentation.

An integrated physical-chemical system for concurrent carbon, nitrogen, and phosphorus removal in municipal wastewater treatment plants.

A substantial quantity of suspended solids (SS) present in municipal wastewater leads to the swift depletion of the ion exchange (IE) capacity of natural zeolites like Clinoptilolite (CIO). This limitation has become the primary factor contributing to the limited adoption of the IE technique within municipal wastewater treatment plants (WWTPs). However, an extensive lab-scale and pilot-scale study conducted over approximately one year has made it possible to efficiently apply the IE system using CIO (main grain size of 0.

Draft genome sequence of furan-degrading strain FUR100.

FUR100 was isolated from a mixture of soil and activated sludge. It can use furan as a sole source of carbon and energy. Its draft genome sequence may provide insight into the genetics of furan catabolism.

Comparison of 17β-estradiol, bisphenol-A and caffeine concentration levels before and after the water treatment plant.

This article compares the concentration levels of 17β-estradiol (E2), bisphenol-A (BPA) and caffeine (CAF) in the Sinos River, Brazil, which is a source of drinking water and the presence of contaminants after the conventional treatment in a municipal water treatment plant (WTP). A total of nine sampling campaigns were carried out, with sample collection in the Sinos River, upstream and downstream of the WTP, in addition to a drinking water sample (DW). The samples were extracted with solid phase extraction (SPE) and the concentration by liquid chromatography coupled to mass spectrometry (LC-MS).

Substrate-independent expression of key functional genes in strain PS-1 limits their use as markers for PAH biodegradation.

Microbial degradation of petroleum hydrocarbons is a crucial process for the clean-up of oil-contaminated environments. spp. are well-known polycyclic aromatic hydrocarbon (PAH) degraders that possess PAH-degradation marker genes including , , and .

Evaluating the sustainability of demand oriented biogas supply programs under different flexible hierarchies: A suggested approach based on the triple bottom line principle.

In this paper, a decision-making approach based on the triple bottom line concept is presented for evaluating the sustainability of demand-oriented biogas supply (DOBS) programs with regard to their environmental, economic, and social impacts. For the assessment, an indicator system was developed, whose main parameters were quantified by integrating emergy analysis, economic benefit assessment, and a proposed social risk accounting method. The Charnes-Cooper-Wei-Huang (CCWH) model with constrained cone was adopted to calculate the comprehensive sustainability via the synthesis of the economic, environmental, and social indicators, in which eight scenarios were set according to the flexibility hierarchy of biogas supplied for load demand, biogas production mode, and feeding substrates.

The 2-methylpropene degradation pathway in Mycobacteriaceae family strains.

Mycolicibacterium gadium IBE100 and Mycobacterium paragordonae IBE200 are aerobic, chemoorganoheterotrophic bacteria isolated from activated sludge from a wastewater treatment plant. They use 2-methylpropene (isobutene, 2-MP) as the sole source of carbon and energy. Here, we postulate a degradation pathway of 2-methylpropene derived from whole genome sequencing, differential expression analysis and peptide-mass fingerprinting.

Dosage concentration and pulsing frequency affect the degradation efficiency in simulated bacterial polycyclic aromatic hydrocarbon-degrading cultures.

A major source of anthropogenic polycyclic aromatic hydrocarbon (PAH) inputs into marine environments are diffuse emissions which result in low PAH concentrations in the ocean water, posing a potential threat for the affected ecosystems. However, the remediation of low-dosage PAH contaminations through microbial processes remains largely unknown. Here, we developed a process-based numerical model to simulate batch cultures receiving repeated low-dosage naphthalene pulses compared to the conventionally used one-time high-dosage.

Systematizing Microbial Bioplastic Production for Developing Sustainable Bioeconomy: Metabolic Nexus Modeling, Economic and Environmental Technologies Assessment.

The excessive usage of non-renewable resources to produce plastic commodities has incongruously influenced the environment's health. Especially in the times of COVID-19, the need for plastic-based health products has increased predominantly. Given the rise in global warming and greenhouse gas emissions, the lifecycle of plastic has been established to contribute to it significantly.

Mechanistic modeling indicates rapid glyphosate dissipation and sorption-driven persistence of its metabolite AMPA in soil.

Residual concentrations of glyphosate and its main transformation product aminomethylphosphonic acid (AMPA) are often observed in soils. The factors controlling their biodegradation are currently not well understood. We analyzed sorption-limited biodegradation of glyphosate and AMPA in soil with a set of microcosm experiments.

Recovery of dyes and salts from highly concentrated (dye and salt) mixed water using nano-filtration ceramic membranes.

In this study, a higher concentration of (reactive dyestuff and salt) mixed water was used to verify the feasibility of separation by membrane techniques. The commercial nano filtration ceramic membrane (MWCO 200 Da) has been used in cross flow mode for separation of dyes and salts from highly concentrated mixed water solution. NF ceramic membrane presents good permeability (pure water flux 54.

Model-based identification and testing of appropriate strategies to minimize NO emissions from biofilm deammonification.

Based on a one-year pilot plant operation of a two-step biofilm nitritation-anammox pilot plant, NO mitigation strategies were identified by applying a newly developed biofilm modeling approach. Due to adapted plant operation, the NO emission could be diminished by 75% (8.8% → 2.

Recovery of Ammonium Sulfate Solution by Regeneration of Loaded Clinoptilolite.

The zeolite clinoptilolite (CLI) is known to be a very good ion exchanger, as it consists of a three-dimensional structure formed of AlO and SiO tetrahedral, which are connected by a common oxygen atom. The micropores formed by this structure (with free diameters in the range of 0.40 nm and 0.

Insightful Advancement and Opportunities for Microbial Bioplastic Production.

Impetuous urbanization and population growth are driving increased demand for plastics to formulate impeccable industrial and biomedical commodities. The everlasting nature and excruciating waste management of petroleum-based plastics have catered to numerous challenges for the environment. However, just implementing various end-of-life management techniques for assimilation and recycling plastics is not a comprehensive remedy; instead, the extensive reliance on finite resources needs to be reduced for sustainable production and plastic product utilization.

Assessing data in the informal e-waste sector: The Agbogbloshie Scrapyard.

The Old-Fadama-Scrapyard, better known as Agbogbloshie, is located in Accra, Ghana. Over the last 20 years, the area has developed into a large scrapyard, where the informal sector processes mainly electronic waste (e-waste) and scrap metals. However, unsafe treatment methods, such as the open burning of cables and foams, and the spilling of hazardous liquids onto the ground, cause environmental pollution and create health risks by releasing persistent organic pollutants (POPs) and heavy metals.

Development of a Heavy Metal Sensing Boat for Automatic Analysis in Natural Waters Utilizing Anodic Stripping Voltammetry.

Determination of the levels of heavy metal ions would support assessment of sources and pathways of water pollution. However, traditional spatial assessment by manual sampling and off-site detection in the laboratory is expensive and time-consuming and requires trained personnel. Aiming to fill the gap between on-site automatic approaches and laboratory techniques, we developed an autonomous sensing boat for on-site heavy metal detection using square-wave anodic stripping voltammetry.

Performance evaluation and siting index of the stabilization ponds based on environmental parameters: a case study in Iran.

Stabilization ponds are open pools that remove total suspended solids, organic matters, microbial and pathogenic agents using physical, chemical, and biological processes. If the stabilization ponds are not well designed, they can produce odors, breed many insects, increase suspended solids concentration in the effluent and pollute groundwater. Consideration of environmental factors is critical for operation and maintenance.

Modern Carbon-Based Materials for Adsorptive Removal of Organic and Inorganic Pollutants from Water and Wastewater.

Currently, a serious threat for living organisms and human life in particular, is water contamination with persistent organic and inorganic pollutants. To date, several techniques have been adopted to remove/treat organics and toxic contaminants. Adsorption is one of the most effective and economical methods for this purpose.

The coupled socio-ecohydrological evolution of river systems: Towards an integrative perspective of river systems in the 21st century.

River systems have undergone a massive transformation since the Anthropocene. The natural properties of river systems have been drastically altered and reshaped, limiting the use of management frameworks, their scientific knowledge base and their ability to provide adequate solutions for current problems and those of the future, such as climate change, biodiversity crisis and increased demands for water resources. To address these challenges, a socioecologically driven research agenda for river systems that complements current approaches is needed and proposed.