Dibenzyl isophthalates as versatile hosts in room temperature phosphorescence host-guest systems.

We report a series of dibenzyl isophthalates (DBIs) as novel hosts for room-temperature phosphorescence (RTP) host-guest systems, achieving RTP quantum yields (QY) of up to 77% or lifetimes of up to 21.0 s with the guest coronene- . Furthermore, a 4,4'-Br substituted DBI was used to form host-guest RTP systems with 15 different aromatic guest molecules, to tune the phosphorescence emission color from blue to red and to demonstrate the versatility of the host.