Atomic Force Microscopy Study of the Long-Term Effect of the Glycerol Flow, Stopped in a Coiled Heat Exchanger, on Horseradish Peroxidase.

Glycerol is employed as a functional component of heat-transfer fluids, which are of use in both bioreactors and various biosensor devices. At the same time, flowing glycerol was reported to cause considerable triboelectric effects. Herein, by using atomic force microscopy (AFM), we have revealed the long-term effect of glycerol flow, stopped in a ground-shielded coiled heat exchanger, on horseradish peroxidase (HRP) adsorption on mica.

Exogenous GABA supplementation to facilitate Cr (III) tolerance and lipid biosynthesis in Chlorella sorokiniana.

Microalgae possess the prospective to be efficiently involved in bioremediation and biodiesel generation. However, conditions of stress often restrict their growth and diminish different metabolic processes. The current study evaluates the potential of GABA to improve the growth of the microalga Chlorella sorokiniana under Cr (III) stress through the exogenous administration of GABA.

Silver-Assisted Hydrogen Evolution from Aluminum Oxidation in Saline Media.

A swarf of aluminum alloy with high corrosion resistance and ductility was successfully converted into fine hydro reactive powders via ball milling with silver powder and either lithium chloride or gallium. The latter substances significantly intensified particle size reduction, while silver formed 'cathodic' sites (Ag, AgAl), promoting Al corrosion in aqueous saline solutions with hydrogen generation. The diffraction patterns, microphotographs, and elemental analysis results demonstrated partial aluminum oxidation in the samples and their contamination with tungsten carbide from milling balls.

Algae: A promising and sustainable protein-rich food ingredient for bakery and dairy products.

The consumer demand for protein rich foods urges the exploration for novel products of natural origin. Algae can be considered as a gold mine of different bioactive compounds, among which protein is distributed in significant amounts i.e.

Survival of microorganisms during two-year exposure in outer space near the ISS.

Results of an experiment named "Test" on survival and variability of microorganisms in open space near the International Space Station are presented. It was found after two-years exposure, spore-forming bacteria of the species Bacillus subtilis, fungi of the species Aureobasidium pullulans and archaea of the species Methanosarcina mazei S-6, deposited on cotton wool, are able to survive, and their numbers decreased equally, regardless of whether the microorganisms belong to different taxonomic groups. The main factors for the long-term survival could be the result of their dehydration and partial lyophilization in the vacuum of near-Earth space.

Metal Scrap to Hydrogen: Manufacture of Hydroreactive Solid Shapes via Combination of Ball Milling, Cold Pressing, and Spark Plasma Sintering.

Two sorts of tablets were manufactured from ball-milled powder (aluminum scrap and copper) by cold pressing and spark plasma sintering. Their microstructure, phase, and elemental compositions were investigated via scanning electron microscopy, X-ray diffraction analysis, and energy-dispersive X-ray spectroscopy. New phases, AlCu and MgCuAl, were detected in the samples.

Effect of porosity on rapid dynamic compaction of nickel nanopowder.

The shock-loading behavior of nanomaterials requires careful investigation because these complex systems are widely used in environments subjected to impulsive loads. Planar plate impact experiments are conducted to study shock compaction waves in 94% porous nickel powder containing spherical ∼55 nm particles in the pressure and strain rate ranges of 0.1-0.

Synergistic interaction between hydrocolloids and kinnow peel biowaste for the development of edible fillers using response surface methodology.

Rapidly rising societal awareness about the planet sustainability through developing environmentally friendly and biodegradable alternatives to current impact of plastics waste represents an emerging need for establishing a circular bioeconomy of cleaner, safer, greener, and sustainable future. Until now, no investigation has been done on edible tableware made from leftover fruit peels. Presently, Kinnow mandarin is the most commercially farmed citrus fruit commodity, with the highest production, productivity, and popularity among all horticulture crops worldwide, generating vast quantity of peels ending up as putrefying biowaste that impacts ecosystem health.

Revision of the oxygen reduction reaction on N-doped graphenes by grand-canonical DFT.

Nitrogen-doped graphenes were among the first promising metal-free carbon-based catalysts for the oxygen reduction reaction (ORR). However, data on the most efficient catalytic centers and their catalytic mechanisms are still under debate. In this work, we study the associative mechanism of the ORR in an alkaline medium on graphene containing various types of nitrogen doping.

Effects of Light Intensity on the Growth and Biochemical Composition in Various Microalgae Grown at High CO Concentrations.

In modern energy, various technologies for absorbing carbon dioxide from the atmosphere are being considered, including photosynthetic microalgae. An important task is to obtain maximum productivity at high concentrations of CO in gas-air mixtures. In this regard, the aim of the investigation is to study the effect of light intensity on the biomass growth and biochemical composition of five different microalgae strains: , , , , and .

Ultracold plasma expansion in quadrupole magnetic field.

We present simulation results of ultracold Sr plasma expansion in a quadrupole magnetic field by means of molecular dynamics. An analysis of plasma evolution influenced by a magnetic field is given. Plasma confinement time behavior under variation of magnetic field strength is estimated.

Exchange-correlation bound states of the triplet soft-sphere fermions by path-integral Monte Carlo simulations.

Path-integral Monte Carlo simulations in the Wigner approach to quantum mechanics has been applied to calculate momentum and spin-resolved radial distribution functions of the strongly correlated soft-sphere quantum fermions. The obtained spin-resolved radial distribution functions demonstrate arising triplet clusters of fermions, that is the consequence of the interference of exchange and interparticle interactions. The semiclassical analysis in the framework of the Bohr-Sommerfeld quantization condition, applied to the potential of the mean force corresponding to the same-spin radial distribution functions, allows to detect exchange-correlation bound states in triplet clusters and to estimate corresponding averaged energy levels.

Correcting charge distribution in reduced Li-molecule pair for computational screening of battery solvents.

Li-molecule pair is a widely used model for the simulation of reduction in Li-ion batteries. We demonstrate that this model provides incorrect results for some solvents. When an electron is added to the Li-molecule pair, it may go to the lithium-ion and neutralize it.

Numerical optimization of hydrothermal liquefaction process for the production of bio-oil and bio-char from Citrus maxima peel waste and product characterization.

This research study aims to potential utilization of Citrus maxima peel waste and optimize the hydrothermal liquefaction process for the production of bio-oil (BO) and bio-char (BC). The effect of several HTL processing variables on BO yield (%) and BC yield (%), including temperature, retention period, and slurry concentration, has been examined using central composite design (CCD) (a three-level three-factor design). The optimized values of HTL process variables were found to be 240 °C (temperature), 52 min (retention time), and 7% (slurry concentration) and the corresponding responses were 5.

Development of yeast and microalgae consortium biofilm growth system for biofuel production.

Background: The current study aimed to develop a laboratory-scale biofilm photobioreactor system for biofuel production.

Scope & Approach: During the investigation, Jute was discovered to be the best, cheap, hairy, open-pored supporting material for biofilm formation. Microalgae & yeast consortium was used in this study for biofilm formation.

Enhancing the bio-prospective of microalgae by different light systems and photoperiods.

Microalgae are a source of highly valuable bioactive metabolites and a high-potential feedstock for environmentally friendly and sustainable biofuel production. Recent research has shown that microalgae benefit the environment using less water than conventional crops while increasing oxygen production and lowering CO emissions. Microalgae are an excellent source of value-added compounds, such as proteins, pigments, lipids, and polysaccharides, as well as a high-potential feedstock for environmentally friendly and sustainable biofuel production.

Bio-oil and biochar production from Ageratum conyzoides using triple-stage hydrothermal liquefaction and utilization of biochar in removal of multiple heavy metals from water.

Production of low-cost biomass and its utilization for producing cost effective and eco-friendly bioenergy as well as for removing heavy metals from water can be explored as an approach to meet the sustainable development goals. In light of the above-mentioned study, hydrothermal liquefaction (HTL) of Billy goat weed (B; Ageratum conyzoides) was carried out to produce bio-oil. In addition, the residual biochar from the HTL process was activated to obtain Act-BC and was further modified to produce MnO-loaded biochar (Act-BC@MnO-25%).

Experimental and Theoretical Studies of Hydrogen Storage in LaNiAlFe Hydride Bed.

In this article, the experimental measurements of the absorption/desorption P-C-T isotherms of hydrogen in the LaNiFeAl alloy at different temperatures and constant hydrogen pressure have been studied using a numerical model. The mathematics equations of this model contain parameters, such as the two terms, n and n representing the numbers of hydrogen atoms per site; N and N are the receptor sites' densities, and the energetic parameters are P and P. All these parameters are derived by numerically adjusting the experimental data.

Interaction of Nitrite Ions with Hydrated Portlandite Surfaces: Atomistic Computer Simulation Study.

The nitrite admixtures in cement and concrete are used as corrosion inhibitors for steel reinforcement and also as anti-freezing agents. The characterization of the protective properties should account for the decrease in the concentration of free NO ions in the pores of cement concretes due to their adsorption. Here we applied the classical molecular dynamics computer simulation approach to quantitatively study the molecular scale mechanisms of nitrite adsorption from NaNO aqueous solution on a portlandite surface.

A phyco-nanobionics biohybrid system for increased carotenoid accumulation in UUIND6.

Recent advancements in "phyco-nanobionics" have sparked considerable interest in the ability of microalgae to synthesize high-value natural bioactive compounds such as carotenoid pigments, which have been highlighted as an emergent and vital bioactive compound from both industrial and scientific perspectives. Such bioactive compounds are often synthesized by either altering the biogenetic processes existing in living microorganisms or using synthetic techniques derived from petroleum-based chemical sources. A bio-hybrid light-driven cell factory system was established herein by using harmful macroalgal bloom extract (HMBE) and efficient light-harvesting silver nanoparticles (AgNPs) to synthesize HMBE-AgNPs and integrating the synthesized HMBE-AgNPs in various concentrations (1, 2.

Effects of Bi-Sn-Pb Alloy and Ball-Milling Duration on the Reactivity of Magnesium-Aluminum Waste-Based Materials for Hydrogen Production.

In the present study, composite materials were elaborated of mixed scrap of Mg-based casting alloys and low melting point Bi-Sn-Pb alloy by high energy ball milling, and their reactivity in NaCl solution with hydrogen release was tested. The impacts of the additive content and ball milling duration on their microstructure and hydrogen generation performance were investigated. Scanning electron microscopy (SEM) analysis revealed significant microstructural transformations of the particles during milling, and X-ray diffraction analysis (XRD) proved the formation of new intermetallic phases MgBi, MgSn, and MgPb.

Evaluation of the mechanisms underlying altered fatty acid biosynthesis in heterotrophic microalgal strain Chlorella sorokiniana during biodegradation of phenol and p-nitrophenol.

Phenolic compounds have become a severe environmental concern due to water contamination, affecting the sustainability of the ecosystem. The microalgae enzymes have enticed for the efficient involvement in the biodegradation of phenolics compound in metabolic processes. In this investigation, the oleaginous microalgae Chlorella sorokiniana was cultured heterotrophically under the influence of phenol and p-nitrophenol.

Enhanced Hydrogen Generation from Magnesium-Aluminum Scrap Ball Milled with Low Melting Point Solder Alloy.

In this investigation, composite materials were manufactured of mixed scrap of Mg-based alloys and low melting point Sn-Pb eutectic by high energy ball milling, and their hydrogen generation performance was tested in NaCl solution. The effects of the ball milling duration and additive content on their microstructure and reactivity were investigated. Scanning electron microscopy (SEM) analysis indicated notable structural transformations of the particles during ball milling, and X-ray diffraction analysis (XRD) proved the formation of new intermetallic phases MgSn and MgPb, which were aimed to augment galvanic corrosion of the base metal.

Stopped Flow of Glycerol Induces the Enhancement of Adsorption and Aggregation of HRP on Mica.

Glycerol is a usable component of heat-transfer fluids, and is thus suitable for the use in microchannel-based heat exchangers in biosensors and microelectronic devices. The flow of a fluid can lead to the generation of electromagnetic fields, which can affect enzymes. Herein, by means of atomic force microscopy (AFM) and spectrophotometry, a long-term effect of stopped flow of glycerol through a coiled heat exchanger on horseradish peroxidase (HRP) has been revealed.

Heavy metal tolerance in microalgae: Detoxification mechanisms and applications.

The proficiency of microalgae to resist heavy metals has potential to be beneficial in resolving various environmental challenges. Global situations such as the need for cost-effective and ecological ways of remediation of contaminated water and for the development of bioenergy sources could employ microalgae. In a medium with the presence of heavy metals, microalgae utilize different mechanisms to uptake the metal and further detoxify it.