Atmospheric scattering model and dark channel prior constraint network for environmental monitoring under hazy conditions.

Environmental monitoring systems based on remote sensing technology have a wider monitoring range and longer timeliness, which makes them widely used in the detection and management of pollution sources. However, haze weather conditions degrade image quality and reduce the precision of environmental monitoring systems. To address this problem, this research proposes a remote sensing image dehazing method based on the atmospheric scattering model and a dark channel prior constrained network.

Regional PM prediction with hybrid directed graph neural networks and Spatio-temporal fusion of meteorological factors.

Traditional statistical prediction methods on PM often focus on a single temporal or spatial dimension, with limited consideration for regional transport interactions among adjacent cities. To address this limitation, we propose a hybrid directed graph neural network method based on deep learning, which utilizes domain features to quantify the influence of neighboring cities and construct a directed graph. The model comprises a historical feature extraction module and a future transmission prediction module, and each module integrates a Graph Neural Network (GNN) and a Long Short-Term Memory Network (LSTM) for spatiotemporal encoding.

High thermal conductive and photothermal phase change material microcapsules via cellulose nanocrystal stabilized Pickering emulsion for solar harvesting and thermal energy storage.

Phase change materials (PCMs) are promising for thermal energy storage due to their high latent enthalpy and constant phase change temperature. However, organic PCMs suffer from leaking, low thermal conductivity, and flammability. Herein, high thermal conductivity, photothermal and flame-proof docosane microcapsules with melamine-formaldehyde (MF) and polypyrrole (PPy) (C-CMFP) were reported with cellulose nanocrystal (CNC) stabilized Pickering emulsion droplets as templates through in-situ polymerization.

Fabry-Perot Effect Suppression in Gas Cells Used in THz Absorption Spectrometers. Experimental Verification.

A standard measuring gas cell used in absorption spectrometers is a cylinder enclosed by two transparent windows. The Fabry-Perot effects caused by multiple reflections of terahertz waves between these windows produce significant variations in the transmitted radiation intensity. Therefore, the Fabry-Perot effects should be taken into account to correctly measure absorption spectra in Bouguer law-based absorption spectroscopy.

Fault Tolerant Spectral/Spatial Optical Code Division Multiple Access Passive Optical Network.

High-capacity communication networks are built to provide high throughput and low latency to accommodate the growing demand for bandwidth. However, the provision of these features is subject to a robust underlying network, which can provide high capacity with maximum reliability in terms of the system's connection availability. This work optimizes an existing 2D spectral-spatial optical code division multiple access (OCDMA) passive optical network (PON) to maximize connection availability while maintaining desirable communication capacity and capital expenditure.

Polarization and reflectance are linked to climate, size and mechanistic constraints in a group of scarab beetles.

Beetles exhibit an extraordinary diversity of brilliant and colourful appearances and optical effects invisible to humans. Their underlying mechanisms have received some attention, but we know little about the ecological variables driving their evolution. Here we investigated environmental correlates of reflectivity and circular polarization in a group of optically diverse beetles (Scarabaeidae-Rutelinae).

Self-healing and transparent ionic conductive PVA/pullulan/borax hydrogels with multi-sensing capabilities for wearable sensors.

Conductive hydrogels as wearable sensors have been used for numerous applications in human motion detection, personal healthcare monitoring and other diverse scenarios. However, it remains a challenge to integrate self-healing ability, multiple sensing capabilities, and transparency in one single unit. In this work, multifunctional polyvinyl alcohol (PVA)/Pullulan/Borax conductive hydrogels were fabricated by introducing borate ester bonds and hydrogen bonds.

Optimization of band structure by facet engineering to enhance photocatalytic/photothermal synergistic therapy of cobalt sulfide nanosheets.

With the rapid development of optics and nanotechnology, optical therapy is recognized as a potential strategy to combat bacterial drug resistance. Unfortunately, the limitation of band structure on the therapeutic effect of photocatalytic nano-antimicrobial materials has become a major challenge in the development of optical therapy. Here, CoS and CoS-T200 were prepared by facet engineering design with major exposed facets (311) and (222), respectively.

Towards improved spectroscopic applications in multi-gas environments: CO spectral line parameter measurement and analysis.

The ν + 2ν + ν band of CO is dominated by weak absorption lines near 2.0 uμm, which has potential application in planetary atmosphere, astrophysical, and hydrocarbon fuel combustion investigations. High-quality spectral line parameters are the foundation of spectroscopic technology.

Resolving the Loss of Intermediate-Size Speech Aerosols in Funnel-Guided Particle Counting Measurement.

Modeling of airborne virus transmission and protection against it requires knowledge of the amount of biofluid emitted into the atmosphere and its viral load. Whereas viral concentrations in biofluids are readily measured by quantitative PCR, the total volume of fluids aerosolized during speaking, as measured by different researchers using different technologies, differs by several orders of magnitude. We compared collection methods in which the aerosols first enter into a low humidity chamber either by direct injection or via commonly used funnel and tubing arrangements, followed by standard optical particle sizer measurement.

Improved ion detection sensitivity in mass spectrometry imaging using tapping-mode scanning probe electrospray ionization to visualize localized lipids in mouse testes.

Mass spectrometry imaging (MSI) is a promising analytical method to visualize the distribution of lipids in biological tissues. To clarify the relationship between cellular distribution and lipid types in a tissue, it is crucial to achieve both an improvement in ion detection sensitivity and a reduction in the ionization area. We report methods for improving the efficiency of ion transfer to a mass spectrometer and miniaturizing the extraction area of a sample for tapping-mode scanning probe electrospray ionization (t-SPESI), atmospheric pressure sampling, and ionization methods.

An investigative review of the expanded capabilities of thermal/optical techniques for measuring carbonaceous aerosols and beyond.

Carbonaceous aerosols primarily comprise organic carbon (OC) and black carbon (BC). Thermal-optical analysis (TOA) is the most commonly used method for separating carbonaceous aerosols into OC and EC (BC is referred to as elemental carbon EC, in this method). Advances in hardware design and algorithms have expanded the capabilities of TOA beyond just distinguishing OC and EC.

Demographic, morphological and coat factors in dogs after exercise at a fast course ability test (FCAT) trial.

Domestic dogs are a widely diverse species of endothermic mammals that show a positive correlation between body mass and whole-animal metabolic rate, but a negative correlation between body mass and lifespan, making them an interesting system for determining thermoregulatory patterns in relation to body mass, body morphology, and age within a single mammalian species. Though previous work has found differences in thermoregulation across seasons and with training in dogs of different sizes, we now seek to determine (1) whether sampling event-related temperature differences remained when dogs exercised intensely and acutely outdoors and (2) whether thermal differences were also expressed in short-term burst exercise in athletic dogs compared to long-term exercise in non-athletic dogs, as previously found. Here, we measured tympanic membrane temperature (T) as a correlate of core or internal body temperature (T).

4T1 Cell Membrane-Coated Pdots with NIR-II Absorption and Fluorescence Properties for Targeted Phototheranostics of Breast Tumors.

Designing highly biocompatible organic semiconducting conjugated polymer dots (Pdots) with bright fluorescence and superior absorption properties in the second near-infrared window (NIR-II: 1000-1700 nm) remains a huge challenge for tumor phototheranostics. In this study, we constructed 4T1 cell membrane-coated -PBTQ4F Pdots (CPdots) with enhanced NIR-II photoacoustic (PA) and fluorescence (FL) imaging capability for NIR-II photothermal therapy (PTT) of breast tumors. Our findings demonstrated that CPdots could specifically target breast tumors, leading to enhanced tumor accumulation after systemic administration in living mice.

Gelation and post-gelation mechanism of methylcellulose in an aqueous medium: H NMR and dynamic compressive rheological studies.

Methylcellulose (MC) has become crucial in 3D bioprinting in the last decade. Researchers investigated MC aqueous solutions blended with biopolymers at room temperature, focusing on rheological studies. Even at low concentrations, the gel state of MC, which provides structural strength through hydrophilic and hydrophobic associations, was explored for injection-based 3D printability.

A pressure-jump EPR system to monitor millisecond conformational exchange rates of spin-labeled proteins.

Site-directed spin labeling electron paramagnetic resonance (SDSL-EPR) using nitroxide spin labels is a well-established technology for mapping site-specific secondary and tertiary structure and for monitoring conformational changes in proteins of any degree of complexity, including membrane proteins, with high sensitivity. SDSL-EPR also provides information on protein dynamics in the timescale of ps-μs using continuous wave lineshape analysis and spin lattice relaxation time methods. However, the functionally important time domain of μs-ms, corresponding to large-scale protein motions, is inaccessible to those methods.

Synthesis and Characterizations of Dibenzo-Fused Perioctacene.

Dibenzoperioctacene (DBPO) with extended zigzag edges was synthesized and unambiguously characterized by a combination of nuclear magnetic resonance (NMR), mass spectrometry, and single-crystal X-ray diffraction analysis. Variable-temperature (VT) NMR analysis indicated the closed-shell character of DBPO, yet the bond lengths in the single-crystal structure of DBPO aligned more closely with those of open-shell teranthene than closed-shell bisanthene. Spin-unrestricted density functional theory (DFT) calculations using various methods supported that ground state of DBPO might be on the borderline between closed- and open-shell singlet states, with a large singlet-triplet energy gap (ΔE), consistent with the VT NMR and bond-length analyses.