Can neotectonic faults influence soil air radon levels in the Upper Rhine Graben? An exploratory machine learning assessment.

Radon (Rn) is a naturally occurring radioactive gas that poses a significant lung cancer risk. Subsurface fault zones can act as pathways for fluid and gas migration, potentially amplifying Rn accumulation. This study investigates the impact of fault zones on Rn concentrations within a 25 km area in the Northern Upper Rhine Graben, Germany - a region with available detailed geophysical exploration data and active neotectonic faulting.

On the structural evolution of nanoporous optically transparent CuO photocathodes upon calcination for photoelectrochemical applications.

Copper oxides are promising photocathode materials for solar hydrogen production due to their narrow optical band gap energy allowing broad visible light absorption. However, they suffer from severe photocorrosion upon illumination, mainly due to copper reduction. Nanostructuring has been proven to enhance the photoresponse of CuO photocathodes; however, there is a lack of precise structural control on the nanoscale upon sol-gel synthesis and calcination for achieving optically transparent CuO thin film photoabsorbers.

Cryosphere and land cover influence on stream water quality in Central Asia's glacierized catchments.

This work helps address recent calls for systematic water quality assessment in Central Asia and considers how nutrient and salinity sources, and transport, affect water quality along the continuum from the cryosphere to the lowland plains. Spatial and, for the first time, temporal variations in stream water pH, temperature, electrical conductivity, and nitrate and phosphate concentrations are presented for four catchments (485-13,500 km), all with glaciers and major urban areas. The catchments studied were: Kaskelen (Kazakhstan), Ala-Archa (Kyrgyzstan), Chirchik (Uzbekistan) and the Kofarnihon (Tajikistan).

Crystal structures of two new high-pressure oxynitrides with composition SnGeNO, from single-crystal electron diffraction.

SnGeNO was synthesized at high pressure (16 and 20 GPa) and high temperature (1200 and 1500°C) in a large-volume press. Powder X-ray diffraction experiments using synchrotron radiation indicate that the derived samples are mixtures of known and unknown phases. However, the powder X-ray diffraction patterns are not sufficient for structural characterization.

The comprehensive evaluation of nitrate origin and transformation pathways in the oxic alluvial aquifer in Serbia.

Accurate pollution source identification is essential for establishing adequate water management strategies, particularly in groundwater with slow flow and prolonged recharge process allowing long-term pollution retention. An integrated study based on hydrogeochemical, dual isotopic (δN and δO), and microbiological approaches (DN, IRB, and SRB BART tests) along with the statistical data processing was conducted to determine nitrate origin and fate in oxic alluvial groundwater source Ključ in Serbia. The findings from a comprehensive investigation, encompassing 20 groundwater sampling locations during the period 2010-2019, delineated three distinct zones - the hinterland (anthropogenic impact area-untreated sewage inflow), the middle zone (area of mixed influence from fertilizer application, accompanied by a mitigated anthropogenic impact), and the zone of riparian denitrification.

Do contaminants compromise the use of recycled nutrients in organic agriculture? A review and synthesis of current knowledge on contaminant concentrations, fate in the environment and risk assessment.

Use of nutrients recycled from societal waste streams in agriculture is part of the circular economy, and in line with organic farming principles. Nevertheless, diverse contaminants in waste streams create doubts among organic farmers about potential risks for soil health. Here, we gather the current knowledge on contaminant levels in waste streams and recycled nutrient sources, and discuss associated risks.

Numerical investigation of the effect of fluid pressurization rate on laboratory-scale injection-induced fault slip.

The effect of normal stress variations on fault frictional strength has been extensively characterized in laboratory experiments and modelling studies based on a rate-and-state-dependent fault friction formalism. However, the role of pore pressure changes during injection-induced fault reactivation and associated frictional phenomena is still not well understood. We apply rate-and-state friction (RSF) theory in finite element models to investigate the effect of fluid pressurization rate on fault (re)activation and on the resulting frictional slip characteristics at the laboratory scale.

Jasmonate signaling controls negative and positive effectors of salt stress tolerance in rice.

Plant responses to salt exposure involve large reconfigurations of hormonal pathways that orchestrate physiological changes towards tolerance. Jasmonate (JA) hormones are essential to withstand biotic and abiotic assaults, but their roles in salt tolerance remain unclear. Here we describe the dynamics of JA metabolism and signaling in root and leaf tissue of rice, a plant species that is highly exposed and sensitive to salt.

Mesoporous CuFe O Photoanodes for Solar Water Oxidation: Impact of Surface Morphology on the Photoelectrochemical Properties.

Metal oxide-based photoelectrodes for solar water splitting often utilize nanostructures to increase the solid-liquid interface area. This reduces charge transport distances and increases the photocurrent for materials with short minority charge carrier diffusion lengths. While the merits of nanostructuring are well established, the effect of surface order on the photocurrent and carrier recombination has not yet received much attention in the literature.

Sol-Gel-Derived Ordered Mesoporous High Entropy Spinel Ferrites and Assessment of Their Photoelectrochemical and Electrocatalytic Water Splitting Performance.

The novel material class of high entropy oxides with their unique and unexpected physicochemical properties is a candidate for energy applications. Herein, it is reported for the first time about the physico- and (photo-) electrochemical properties of ordered mesoporous (CoNiCuZnMg)Fe O thin films synthesized by a soft-templating and dip-coating approach. The A-site high entropy ferrites (HEF) are composed of periodically ordered mesopores building a highly accessible inorganic nanoarchitecture with large specific surface areas.

Fibre optic distributed acoustic sensing of volcanic events.

Understanding physical processes prior to and during volcanic eruptions has improved significantly in recent years. However, uncertainties about subsurface structures distorting observed signals and undetected processes within the volcano prevent volcanologists to infer subtle triggering mechanisms of volcanic phenomena. Here, we demonstrate that distributed acoustic sensing (DAS) with optical fibres allows us to identify volcanic events remotely and image hidden near-surface volcanic structural features.

Dynamics of pathogens and fecal indicators during riverbank filtration in times of high and low river levels.

Riverbank filtration is an established and quantitatively important approach to mine high-quality raw water for drinking water production. Bacterial fecal indicators are routinely used to monitor hygienic raw water quality, however, their applicability in viral contamination has been questioned repeatedly. Additionally, there are concerns that the increasing frequency and intensity of meteorological and hydrological events, i.

Soil from a Hexachlorocyclohexane Contaminated Field Site Inoculates Wheat in a Pot Experiment to Facilitate the Microbial Transformation of β-Hexachlorocyclohexane Examined by Compound-Specific Isotope Analysis.

β-Hexachlorocyclohexane (β-HCH) is a remnant from former HCH pesticide production. Its removal from the environment gained attention in the last few years since it is the most stable HCH isomer. However, knowledge about the transformation of β-HCH in soil-plant systems is still limited.

Fermentation, methanotrophy and methanogenesis influence sedimentary Fe and As dynamics in As-affected aquifers in Vietnam.

High arsenic (As) concentrations in groundwater are a worldwide problem threatening the health of millions of people. Microbial processes are central in the (trans)formation of the As-bearing ferric and ferrous minerals, and thus regulate dissolved As levels in many aquifers. Mineralogy, microbiology and dissolved As levels can vary sharply within aquifers, making high-resolution measurements particularly valuable in understanding the linkages between them.

Microbial transformation of biogenic and abiogenic Fe minerals followed by in-situ incubations in an As-contaminated vs. non-contaminated aquifer.

Fe(III) minerals play a crucial role for arsenic (As) mobility in aquifers as they usually represent the main As-bearing phases. Microbial reductive dissolution of As-bearing Fe(III) minerals is responsible for the release of As and the resulting groundwater contamination in many sites worldwide. So far, in most studies mainly abiogenic iron minerals have been considered.

Is thermal use of groundwater a pollution?

Thermal use of the shallow subsurface and its aquifers (< 400 m) is steadily increasing. Currently, more than 2800 aquifer thermal energy storage (ATES) systems are operating worldwide alongside more than 1.2 million ground source heat pump (GSHP) systems in Europe alone.

Quantifying biodegradation rate constants of o-xylene by combining compound-specific isotope analysis and groundwater dating.

The objective of this study is to estimate hydraulic conductivities and biodegradation rate constants in a coal-tar contaminated aquifer by compound-specific isotope analysis (CSIA) and tracer-based (H-He) groundwater dating (TGD). In two observation wells downgradient from the contaminant source in situ biodegradation of o-xylene, toluene and naphthalene under sulfate-reducing redox conditions could be demonstrated using CSIA. Median biodegradation rate constants for o-xylene ranging between 0.

Spatial and temporal evolution of groundwater arsenic contamination in the Red River delta, Vietnam: Interplay of mobilisation and retardation processes.

Geogenic arsenic (As) contamination of groundwater poses a major threat to global health, particularly in Asia. To mitigate this exposure, groundwater is increasingly extracted from low-As Pleistocene aquifers. This, however, disturbs groundwater flow and potentially draws high-As groundwater into low-As aquifers.

Continental outflow of anthropogenic aerosols over Arabian Sea and Indian Ocean during wintertime: ICARB-2018 campaign.

Chemical characterisation of atmospheric aerosols over Arabian Sea (AS) and Indian Ocean (IO) have been carried out during the winter period (January to February 2018) as part of the Integrated Campaign for Aerosols, gases and Radiation Budget (ICARB-2018). Mass concentrations of organic carbon (OC), elemental carbon (EC), water soluble and insoluble OC (WSOC, WIOC), primary and secondary OC (POC, SOC), water-soluble inorganic ions and trace metals have been estimated with a view to identify and quantify the major anthropogenic pollutants affecting the oceanic environments. Aerosol mass loading was found to exhibit strong spatial heterogeneity (varying from 13 to 84 μg m), significantly modulated by the origin of air-mass trajectories.

Comparison of operator- and computer-controlled scanning electron microscopy of particles from different atmospheric aerosol types.

Individual aerosol particles from an urban background site in Mainz (Germany), a traffic hotspot site in Essen (Germany), the free troposphere in the Swiss Alps (high altitude research station Jungfraujoch), a rural background/marine site on Cyprus (Cyprus Atmospheric Observatory) and a rural background site in the forested area of Odenwald (Germany) were characterised with two different scanning electron microscopy techniques, operator controlled (opSEM) and computer controlled (ccSEM). For all samples, about 500 particles were investigated by opSEM, and between 1103 and 6940 particles by ccSEM. Large systematic differences (in some cases a factor up to ~ 20) in the abundance of the various particle groups are observed in the results of the two techniques.

Dynamic strain determination using fibre-optic cables allows imaging of seismological and structural features.

Natural hazard prediction and efficient crust exploration require dense seismic observations both in time and space. Seismological techniques provide ground-motion data, whose accuracy depends on sensor characteristics and spatial distribution. Here we demonstrate that dynamic strain determination is possible with conventional fibre-optic cables deployed for telecommunication.

Intensification of ice nucleation observed in ocean ship emissions.

Shipping contributes primary and secondary emission products to the atmospheric aerosol burden that have implications for climate, clouds, and air quality from regional to global scales. In this study we exam the potential impact of ship emissions with regards to ice nucleating particles. Particles that nucleate ice are known to directly affect precipitation and cloud microphysical properties.

Using synoptic tracer surveys to assess runoff sources in an Andean headwater catchment in central Chile.

Headwater catchments in the Andes provide critical sources of water for downstream areas with large agricultural communities dependent upon irrigation. Data from such remote headwater catchments are sparse, and there is limited understanding of their hydrological function to guide sustainable water management. Here, we present the findings of repeat synoptic tracer surveys as rapid appraisal tools to understand dominant hydrological flow paths in the semi-arid Rio Grande basin, a 572-km headwater tributary of the 11,696-km Limarí basin in central Chile.

Identifying anthropogenic anomalies in air, surface and groundwater temperatures in Germany.

Human activity directly influences ambient air, surface and groundwater temperatures. The most prominent phenomenon is the urban heat island effect, which has been investigated particularly in large and densely populated cities. This study explores the anthropogenic impact on the thermal regime not only in selected urban areas, but on a countrywide scale for mean annual temperature datasets in Germany in three different compartments: measured surface air temperature, measured groundwater temperature, and satellite-derived land surface temperature.