Novel LCA-centric mix design approach for alkali-activated EAF slag with hybrid optimization techniques.

This study presents an innovative life cycle assessment (LCA)-centric approach for optimizing the mix design of alkali-activated materials (AAMs) as sustainable alternatives to ordinary portland cement (OPC). The AAMs are developed using electric arc furnace slag (EAFS) and fly ash as precursors. The environmental performance is evaluated using the ReCiPe midpoint methodology, considering both mass and economic allocation methods.

Selective leaching of rare earths, base metals and precious metals from used smartphones.

Discarded smartphones represent a valuable source of rare earths (REE), base metals and precious metals. This study focussed on the optimisation of three-stage selective leaching conditions for REE, copper and precious metals (Au and Ag), respectively, contained in printed circuit boards (PCBs) found in end-of-life smartphones. The effects of several leaching conditions, such as sulphuric acid and thiourea concentrations, were investigated using a statistical approach based on a design of experiments using Box-Behnken methodology.

Mass balance and economic study of a treatment chain for nickel, cobalt and rare earth elements recovery from Ni-MH batteries.

The aim of this project is to develop and evaluate the economic performance of a complete process for recovering nickel, cobalt, and rare earths (REEs) from nickel metal hydride (Ni-MH) battery waste. The main elements contained in the battery powder are Ni (523 g/kg), La (58 g/kg), Co (39 g/kg), Zn (21 g/kg), Nd (19 g/kg), Sm (19 g/kg) and Ce (14 g/kg). Metal leaching was carried out with 2 M sulfuric acid, solubilising 100% of Ni, 93% of Co and 94% of REEs.

Non-pathogenic microbiome associated to aquatic plants and anthropogenic impacts on this interaction.

The microbiota associated with aquatic plants plays a crucial role in promoting plant growth and development. The structure of the plant microbiome is shaped by intricate interactions among hosts, microbes, and environmental factors. Consequently, anthropogenic pressures that disrupt these interactions can indirectly impact the ecosystem services provided by aquatic plants, such as CO fixation, provision of food resources, shelter to animals, nutrient cycling, and water purification.

Comparison of the accumulation and effects of copper pyrithione and copper sulphate on rainbow trout larvae.

Copper pyrithione (CuPT) is used as a co-biocide in new antifouling paints but its toxicity remains little known. To compare the toxicity of copper-based compounds, rainbow trout (Oncorhynchus mykiss) larvae were exposed for 8-day to CuPT and CuSO at equivalent copper concentrations. CuPT exposure led to the greatest accumulation of Cu in larvae.

Optimization of metals and rare earth elements leaching from spent Ni-MH batteries by response surface methodology.

The rechargeable battery market has almost doubled in 15 years. Regardless of the type of batteries, their limited lifespan means that sooner or later they will constitute a mass of waste whose management is problematic as their content is high in elements and metals of high economic interest, but also toxic to the environment. This project is to optimize the solubilization conditions for rare earth elements (REEs) and other metals from waste nickel-metal hydride (Ni-MH) batteries.

Otolith-inferred patterns of marine migration frequency in Nunavik Arctic charr.

Alternative migratory tactics in salmonids reflect the large observed interindividual variation in spatial behaviour which may range from strict freshwater residency to uninterrupted anadromy. In Salvelinus, sea migrations are performed during the ice-free period as freshwater overwintering is thought to be obligatory due to physiological constraints. As a result, individuals can either migrate the next spring or remain in freshwater, as anadromy is generally considered facultative.

Future temperature-related excess mortality under climate change and population aging scenarios in Canada.

Objective: Climate change is expected to increase global temperatures. How temperature-related mortality risk will change is not completely understood, and how future demographic changes will affect temperature-related mortality needs to be clarified. We evaluate temperature-related mortality across Canada until 2099, accounting for age groups and scenarios of population growth.

Microplastic pollution and associated health hazards: Impact of COVID-19 pandemic.

The COVID-19 pandemic led to an increase in plastic used for medical purposes such as personal protective equipment and packaging materials. A very low share of plastics is recycled while the majority is sent to landfills. This plastic may degrade over time to form microplastics which may pollute land, air, and water sources.

Life Cycle Assessment of Microbial 2,3-Butanediol Production from Brewer's Spent Grain Modeled on Pinch Technology.

Microbial production of 2,3-butanediol (BDO) has received considerable attention as a promising alternate to fossil-derived BDO. In our previous work, BDO concentration >100 g/L was accumulated using brewer's spent grain (BSG) via microbial routes which was followed by techno-economic analysis of the bioprocess. In the present work, a life cycle assessment (LCA) was conducted for BDO production from the fermentation of BSG to identify the associated environmental impacts.

Persulfate activated with calcium peroxide to remediate RAFT soil contaminated with diesel in Arctic northern villages: on-site pilot scale study.

A pilot field study was conducted in a Canadian northern village (NV) to assess the remediation efficiency of sodium persulphate (SPS) alkali activated with calcium peroxide (CP) to degrade diesel from Arctic raft soil. A minimum temperature increase in the subsurface due to overall process reactions was required. The projected context of application was imperative to preserve the integrity of the remaining permafrost.

A Rapid Targeted Gene Inactivation Approach in Sulfolobus islandicus.

Homologous recombination-based gene targeting is a powerful and classic reverse genetics approach to precisely elucidate in vivo gene functions in the organisms across all three domains of life. Gene function studies in Archaea, particularly for those flourishing in inhospitable natural environments that are anaerobic, usually hot, and acidic, have been a great challenge; however, this situation was recently overturned with the increasing availability of genetic manipulation systems in several cultivable archaeal species. In the present chapter, we describe a detailed procedure to rapidly generate gene disruption mutants in the hyperthermophilic crenarchaeon Sulfolobus islandicus via a recently developed Microhomology-Mediated Gene Inactivation (MMGI) approach.

Rebuilding fish biomass for the world's marine ecoregions under climate change.

Rebuilding overexploited marine populations is an important step to achieve the United Nations' Sustainable Development Goal 14-Life Below Water. Mitigating major human pressures is required to achieve rebuilding goals. Climate change is one such key pressure, impacting fish and invertebrate populations by changing their biomass and biogeography.

Thermo-chemo-sonic pretreatment of lignocellulosic waste: Evaluating anaerobic biodegradability and environmental impacts.

In the present study, yard waste was pretreated by thermo-chemo-sonic pretreatment prior to anaerobic digestion to improve its anaerobic biodegradability. First, the pretreatment conditions were optimized using Box-Behnken design based response surface methodology for the maximum organic matter solubilisation. Then, the possible mechanism of delignification by thermo-chemo-sonic pretreatment was discussed.

A comparative life cycle assessment of different pyrolysis-pretreatment pathways of wood biomass for levoglucosan production.

In order to identify the most environmental-friendly pretreatment for pyrolsis of wood residue to levoglucosan (LG), for the first time a comparative life cycle assessment (LCA) was carried out for hot water treatment (HWT), torrefaction, acid pretreatment (AP) and salt pretreatment (SP) pathways. Since LG production can facilitate both resource recovery (RR) and wood residue handling (WRH), two different functional units (FUs), i.e.

Physical process to sort construction and demolition waste (C&DW) fines components using process water.

Modern societies are generating considerable volume of Construction and Demolition Wastes (C&DW) annually. Most recycling facilities offers viable sorting and recycling options for the coarser particles of the different materials found in those wastes. However, usual dry mechanical sorting and human sorting are not efficient on C&DW fines particles (C&DF, <10 mm) representing the third of the C&DW produced and being composed of similar materials.

Critical insights into psychrophilic anaerobic digestion: Novel strategies for improving biogas production.

Anaerobic digestion (AD) under psychrophilic temperature has only recently garnered deserved attention. In major parts of Europe, USA, Canada and Australia, climatic conditions are more suited for psychrophilic (<20 ℃) rather than mesophilic (35 - 37 ℃) and thermophilic (55 - 60 ℃) AD. Low temperature has adverse effects on important cellular processes which may render the cell biology inactive.

Immobilization of nitrifying bacteria on composite based on polymers and eggshells for nitrate production.

Nitrification is a key step in biological nitrogen transformation which depends on the performance of specialized microorganisms. Generally, nitrifying bacteria present a low growth rate and performance which can be improved when immobilized as a biofilm. The development of new materials suitable for the immobilization of nitrifying microorganisms is very important in nitrification and wastewater treatment.

Optimized indium solubilization from LCD panels using HSO leaching.

Spent liquid crystal displays (LCDs) are a secondary source of precious/strategic metals, including indium (In). The present study involved optimizing the solubilization of this strategic element from samples of indium tin oxide (ITO) glass prepared from LCD screens of computer monitors and laptop screens. The influence of operating conditions on In solubilization, as well as optimum conditions for sulfuric acid leaching were defined by a Box-Behnken-type experimental design methodology.

Seasonal variation of total mercury and condition indices of Arctic charr (Salvelinus alpinus) in Northern Québec, Canada.

The winter ecology of anadromous Arctic charr, an important fish species for Indigenous populations, has remained poorly detailed in the literature beyond descriptions of seasonal fasting and resulting declines in condition. However, prolonged periods of reduced feeding can have significant consequences for other variables, such as tissue contaminant levels. To more thoroughly detail seasonal changes, biological information (fork length, total weight, age, sex, somatic condition), stable isotopes (δ13C, % carbon, δ15N, % nitrogen), dorsal muscle % lipid, caloric densities, and total mercury (THg) concentrations were assessed in anadromous Arctic charr collected from Deception Bay, Canada, during the summer and over-wintering periods.

Techno-economic assessment of an hydrometallurgical process to simultaneously remove As, Cr, Cu, PCP and PCDD/F from contaminated soil.

Industrial activities lead to the contamination of large amounts of soils polluted by both inorganic and organic compounds, which are difficult to treat due to different chemical properties. The efficiency of a decontamination process developed to simultaneously remove mixed contamination of industrial soils was evaluated at the pilot-scale, as well as operating costs associated to that process to define the best remediation approach. The results showed that the treatment of the coarse fractions (>0.

Inclusion of water temperature in a fuzzy logic Atlantic salmon (Salmo salar) parr habitat model.

As water temperature is projected to increase in the next decades and its rise is clearly identified as a threat for cold water fish species, it is necessary to adapt and optimize the tools allowing to assess the quantity and quality of habitats with the inclusion of temperature. In this paper, a fuzzy logic habitat model was improved by adding water temperature as a key determinant of juvenile Atlantic salmon parr habitat quality. First, salmon experts were consulted to gather their knowledge of salmon parr habitat, then the model was validated with juvenile salmon electrofishing data collected on the Sainte-Marguerite, Matapedia and Petite-Cascapedia rivers (Québec, Canada).

Prediction of physical separation of metals from soils contaminated with municipal solid waste ashes and metallurgical residues.

Environmental legislation is forcing industrialized countries to rehabilitate contaminated lands. Expensive solutions are available to treat soils contaminated by metals (e.g.

Microbial connectivity and sorting in a High Arctic watershed.

Aquatic ecosystems in the High Arctic are facing unprecedented changes as a result of global warming effects on the cryosphere. Snow pack is a central feature of northern landscapes, but the snow microbiome and its microbial connectivity to adjacent and downstream habitats have been little explored. To evaluate these aspects, we sampled along a hydrologic continuum at Ward Hunt Lake (latitude 83°N) in the Canadian High Arctic, from snow banks, water tracks in the permafrost catchment, the upper and lower strata of the lake, and the lake outlet and its coastal marine mixing zone.